• Title/Summary/Keyword: countercurrent

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Kinetic study of high-temperature removal of $H_2S$ by Ca-based sorbents (황화수소 제거를 위한 칼슘계 고온탈황제의 황화반응속도에 관한 연구)

  • 김영식;전지환
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1998.04a
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    • pp.144-153
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    • 1998
  • Sorbents of calcined limestone and oyster particles having a diameter of about 0.63mm were exposed to simulate fuel gases containing 5000ppmv H2S for temperatures ranging from 600 to 800C in a TGA. The reaction between CaO and H2S proceds via an unreacted shrinking core mechanism. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. The kinetics of the sorption of H2S by CaO is sensitive to the reaction temperature and particle size, and the reaction rate of oyster was faster than the calcined limestone.

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Characteristics of Bubble Mode in the Cylindrical Absorber for Heat Pump System (열펌프 시스템에서 원통형 흡수기 내 기포모드의 특성)

  • 이기봉;전병희;이재철;박찬진;김성현
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2000.11a
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    • pp.199-204
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    • 2000
  • 산업과 과학발달에 의해 더욱 물질적으로 풍요로워진 인류에게 에너지와 환경문제는 새로운 당면문제로 부각되고 있다. 특히 1992년 몬트리올 협정에서는 CFC 및 HCFC의 사용을 각각 1997과 2002년부터 전면 금지시키기로 하였고, 1997년에는 2008-2012년까지 전세계 온실가스 배출량을 5.2% 줄이는 것을 골자로 하는 교토 선언이 합의되었다. 이러한 상황을 타개하기 위한 많은 연구 중 흡수식 열펌프는 환경친화적인 자연냉매를 사용하는 열구동 시스템으로 다시 주목을 받고 있다. 특히 흡수식 열펌프의 구성요소 중 흡수에 의하여 고온의 열을 얻을 수 있는 흡수기에 효율적인 열·물질전달 모드를 적용함으로써 제품의 소형화와 에너지 손실 감소를 이루고 있다. 이에 본 연구에서는 새로운 흡수기 모드로 연구되고 있는 기포타입모드를 원통형 흡수기에 적용해 보고, 그 특성을 고찰해 보고자 하였다. 흡수기로 유입되는 ammonia gas와 용액을 cocurrnet 및 countercurrent로 흘려주었고, 높이에 따른 농도, 온도 및 압력을 측정·비교해 보았다.(중략)

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A Study on the Model of Sulfidation Kinetics Using Seashell Wastes (패각 폐기물을 이용한 황화반응 모델에 관한 연구)

  • Kim Young-Sik
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.395-401
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    • 2004
  • In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove $H_{2}S$. Unreacted core model ior desulfuriration rate prediction of sorbent was indicated. These were linear relationship between time and conversion. So co-current diffusion resistance was conducted reaction rate controlling step. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. Maximum desulfurization capacity was observed at 0.631 mm for lime, oyster and hard-shelled mussel. The kinetics of the sorption of $H_{2}S$ by CaO is sensitive to the reaction temperature and particle size at $800^{\circ}C$, and the reaction rate of oyster was faster than the calcined limestone at $700^{\circ}C$.

Performance Analysis of Moving Bed Heat Exchanger of Solid Particles in a Vertical Pipe (고체입자 이동층을 이용한 수직 전열관 열교환기의 성능해석)

  • Park, Sang-Il;Choe, Gyeong-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.9
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    • pp.2916-2923
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    • 1996
  • A numerical analysis of the moving bed heat exchanger of solid particles inside the vertical pipe was performed using finite difference method. Also, the theoretical solutions were obtained for comparison when the wall heat flux or the wall temperature was assumed constant. The comparison showed that their results agreed well each other. The moving bed heat exchanger was classified as countercurrent-flow, parallel-flow, and cross-flow types according to the gas flow direction. For each type, the thermal efficiency of heat exchanger was calculated as a function of non-dimensional parameters such as the characteristic length of heat exchanger, Biot number and the ratio of thermal capacities of gas and solid particles.

Dialysis in parallel-flow rectangular membrane modules with external reflux for improved performance

  • Yeh, Ho-Ming;Cheng, Tung-Wen;Chen, Kuan-Hung
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.159-169
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    • 2010
  • The effect of external recycle on the performance of dialysis in countercurrent-flow rectangular membrane modules was investigated both theoretically and experimentally. Theoretical analysis of mass transfer in parallel-flow device with and without recycle is analogous to heat transfer in parallel-flow heat exchangers. Experiments were carried out with the use of a microporous membrane to dialyze urea aqueous solution by pure water. In contrast to a device with recycle, improvement in mass transfer is achievable if parallel-flow dialysis is operated in a device of same size with recycle which provides the increase of fluid velocity, resulting in reduction of mass-transfer resistance, especially for rather low feed volume rate.

Variability of Mesoscale Eddies in the Pacific Ocean Simulated by an Eddy Resolving OGCM of $1/12^{\circ}$

  • Yim B.Y.;Noh Y.;You S.H.;Yoon J.H.;Qiu B.
    • 한국전산유체공학회:학술대회논문집
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    • 2006.05a
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    • pp.133-136
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    • 2006
  • The mesoscale eddy field in the North Pacific Ocean, simulated by a high resolution eddy-resolving OGCM ($1/12^{\circ}C$ horizontal resolution), was analyzed, and compared with satellite altimetry data of TOPEX/Poseidon. High levels of eddy kinetic energy (EKE) appear near the Kurosho, North Equatorial Current (NEC), and Subtropical Countercurrent (STCC) in the western part of the subropical gyre. In particlure, it was found that the EKE level of the STCC has a well-defined annual cycle, but no distinct annual cycle of the EKE exists in any other zonal current of the North Pacific Ocean.

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Local Mean Water Layer Thickness in Countercurrent Stratified Two -Phase Fllow (물-증기 역류 성층이상유동에서의 국부 평균 액체층 두께)

  • Kim, Hho-Jung;Kim, Kap
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.6
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    • pp.947-958
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    • 1986
  • 물-증기 역류 성층이상유동에서의 평균 액체층 두께가 여러가지 경사각과 종횡비에 따라 측정되었다. 난류유동에 있어서 전단응력분포의 선형화와 von Karman의 혼합길이 이론을 근거로 평균 액체층의 두께에 대한 관계식이 제시되었으며 실험결과와 잘 일치하였음을 보였다. 접촉면에서의 조파저항이 고려되지 않은 해석결과는, 수평 성층유동의 경우에, 평균 액체층 두께보다는 오히려 파곡까지의 액체층 두께를 예측하고 있는 것으로 나타났다. 또한 평균 액체층 두께에 대한 실험 상관관계식이 계산시 편의를 위해 쉽게 인지할 수 있는 매개변수들의 항들롤 제시되었다.

Separation of Organic Pollutants by Nondispersive Membrane-Solvent Extraction (비분산 막-용매추출에 의한 유기오염물의 분리)

  • 유홍진;한성록
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.2
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    • pp.174-185
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    • 2004
  • Organic pollutants (Phenol, 2-Chlorophenol, Nitrobenzene) were separated from wastewater by nondispersive membrane solvent extraction, using a microporous hydrophobic hollow fiber module. The system was operated countercurrently and cocurrently with the aqueous phase flowing through the fiber lumens and the solvent flowing through the shell side. The distribution coefficients of several solvents (MIBK, IPAc, Hexane) were examined and MIBK was selected as an extracting solvent. Separation efficiency of countercurrent flow method was better than that of cocurrent flow method. Also, the overall mass transfer coefficients were determined.

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PREDICTION OF A MUTUAL SEPARATION OF ACTINIDE AND RARE EARTH GROUPS IN A MULTISTAGE REDUCTIVE EXTRACTION SYSTEM

  • Yoo, Jae-Hyung;Lee, Han-Soo;Kim, Eung-Ho
    • Nuclear Engineering and Technology
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    • v.39 no.5
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    • pp.663-672
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    • 2007
  • The mutual separation behavior of actinides and rare earths in a countercurrent multistage reductive extraction system was predicted by computer calculation. The distribution information for actinides and rare earths in the reductive extraction systems of LiCl-KCl/Cd and LiCl-KCl/Bi was collected from literature and then it was used for the calculation of a multistage extraction. The results of the concentration profiles throughout the extraction cascade, recovery yields of various metal solutes, and separation factors between the actinides and rare earths were calculated. The effects of the major process parameters, such as reducing agent content in the metal phase, number of stages, and salt/metal flow ratio, etc., on the extraction behavior were also examined.

A Study on the Ethanol Concentration Characteristics of Commercial Membranes for Countercurrent Reverse Osmosis Process (향류식 역삼투공정에 의한 상용막의 에탄올 농축특성 연구)

  • 진병복;이광현;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.27-30
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    • 1991
  • 역삼투공정은 선택적 투과성을 가진 막을 이용하여 혼합용액으로부터 특정물질을 분리, 농축 또는 정제하기 위하여 널리 응용되는 분리막기술중의 하나이며, 연속공정이 용이하고 단순히 압력만을 가하는 물리적 조작이므로 원리 및 장치가 간단하여 해수 담수화, 폐수처리, 유용물질 회수, 초순수제조, 식품 및 의약품의 분리, 농축 등 여러 산업분야에서 응용되고 있다. 그러나 매우 큰 삼투압을 나타내는 용액의 농축을 위해서는 삼투압보다 큰 적용압력을 가해주어야 하나 사용된 막은 일정압력 이상에서는 수축되어 제기능을 발휘하지 못하게 되므로 일반적인 역삼투공정으로써는 큰 삼투압을 나타내는 용액의 농축에는 사용될 수 없다. 이는 용액의 삼투압이 씨스템에서 가해줄 수 있는 압력보다 커지기 때문으로, 이 삼투압차를 줄여줄 수 있다면 같은 압력에서도 더 큰 농축효과를 얻을 수 있다.

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