• Title/Summary/Keyword: counter material

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Effect of Electrochemical Properties and Optical Transmittance of Carbon Nanotubes Counter Electrodes on the Energy Conversion Efficiency of Dye-sensitized Solar Cells (염료감응형 태양전지의 탄소나노튜브 상대전극의 광투과도와 전기화학적 특성이 에너지 변환 효율에 미치는 영향)

  • Han, Young-Moon;Hwang, Sook-Hyun;Kang, Myung-Hoon;Kim, Young-Joo;Kim, Hyun-Kook;Kim, Sang-Hyo;Bae, Hyo-Jun;Choi, Hyon-Kwang;Jeon, Min-Hyon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.4
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    • pp.333-339
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    • 2011
  • In this work, electrochemical characteristics and optical transmittance of carbon nanotubes (CNTs) counter electrodes which had different amount of CNTs in CNTs slurries were analyzed. Two-step heat treatment processes were applied to achieve well-fabricated CNTs electrode. Three sets of CNTs electrodes and dye-sensitized solar cells (DSSCs) with CNTs counter electrodes were prepared. As the amount of CNTs increased, sheet resistance of CNTs electrode decreased. CNTs electrode with low sheet resistance had low electrochemical impedance and fast redox reaction. On the other hand, in case of CNTs counter electrode with low density of CNTs, performance of the dye-sensitized solar cell was improved due to its high optical transmittance. We found that the transmittance of CNTs counter electrode influence the performance of dye-sensitized solar cells.

A Study of Sliding Friction and Wear Properties for PTFE Layer coated on Steel (철강재료위 coating된 PTFE 막층의 미끄럼 마찰마모특성 연구)

  • Lee, Han-Young
    • Tribology and Lubricants
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    • v.24 no.2
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    • pp.96-103
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    • 2008
  • PTFE is generally utilized as the form of composites with adding various fillers. The purpose of this paper lies on clarifying the friction and wear properties of the PTFE coating layer on steel. Especially, the effects of PTFE powder size for coating and surface roughness of the counter material on the properties are investigated. Sliding friction and wear tests are conducted at several sliding speeds by employing two types of PTFE coating layer using different powder sizes. One type of coating layer is composed of uniform fine powder, whereas the other type is made up of mixture powder of different sizes. As results, it is found that PTFE coating layer are effective to improve the wear resistance and to reduce the friction coefficient. It is clear that PTFE coating layers are abrasively removed by asperities of the counter material during sliding contact. However, PTFE coating layer with uniform fine powder shows somewhat better wear resistance than that with mixture powder of different sizes in low sliding speed region. It can be seen that the wear of the coating layer are drastically reduced because wear fragment from counter material are transferred to the coating layer. On the other hand, friction coefficient is shown not to be directly related with PTFE powder size in coating layer.

Platinum and carbon nano tube addition in carbon black counter electrode for dye-sensitized solar cells

  • Lee, Su Young;Kim, Sang Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.229-230
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    • 2012
  • Platinum (Pt) has been commonly used as a counter electrode material in dye-sensitized solar cells, because it has high catalytic activity and electric conductivity as well as chemical inertness with iodide electrolyte. However, Pt is too expensive to be commercialized. Therefore, in the present study, carbon black counter electrode with Pt and carbon nano tube (CNT) was investigated. The power conversion efficiency with Pt added carbon black electrode was lower than hat of pure Pt electrode which was 6.47 %. By adding 3 wt% Pt to the carbon black counter electrode, the power conversion efficiency was maximized at 5.88 %. On them, additional adding of 1 wt % CNT, the power conversion efficiency (${\eta}$)wasincreasedupto6.21%. The reason of power conversion efficiency improvement with a proper amount of Pt and CNT was examined by comparing the impedance properties measured using EIS.

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Wear Behavior of Laser Modified SM45C Steel (레이저 표면개질된 SM45C강의 마멸거동)

  • 배춘익;옥철호;박흥식;전태옥
    • Tribology and Lubricants
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    • v.16 no.1
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    • pp.15-21
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    • 2000
  • Radiation of Nd-YAG laser changes and refines the surface microstructure of steels, which gives rise to enhancement of hardness and resulting wear resistance. In the present work, the effect of processing parameters during the surface modification with laser on the wear behavior of the SM45C steel was studied by means of wear testing. The counter material was alumina ceramics. The microstructure observation revealed the dependence of molten depth and width on the defocusing distance. The laser modification of steel surface give rise to improved wear resistance in the testing speed range of either <0.2 m/s or >0.9 m/s Material transfer from steel was wear observated the surface of counter material when testing speed was lower than 0.7 m/s.

U-type Cross-Counter Indirect Evaporative Cooler made of Plastic/Paper (U형 직교 대향류 플라스틱/종이 재질 간접증발소자)

  • Kim, Nea-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.11
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    • pp.732-739
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    • 2016
  • In Korea, the summer is hot and humid, and much electricity is consumed for air conditioning. Thus, the simultaneous usage of an indirect evaporative cooler and a common air conditioner could reduce the sensible heat and save electricity. This study developed a U-type cross-counter flow indirect evaporative cooler (IEC) made of plastic and paper. The efficiencies were compared with those of a cross-flow IEC. The specimen was $500mm{\times}500mm{\times}1000mm$. the results show that the indirect evaporation efficiencies of the cross-counter flow sample were 6-21% higher than those of the cross-flow sample. The pressure drops of the cross-counter sample were 51-66% higher. Thermal analysis based on the -NTU method predicted the experimental data within 10%. The electrical energy saved by the use of the cross-counter flow IEC was larger than that of the counter flow IEC, and the difference increases with the velocity. However, the the cross-counter IEC is two times larger than the cross-flow IEC, which may increase the material cost and water usage.

Preparation and Characterization of Cy3 Dye for LCD Color Filter (LCD Color Filter용 Cy3 염료의 제조 및 특성 연구)

  • Lee, Sang Dong;Hyun, Dong Kyoun;Jeong, Yeon Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.1
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    • pp.35-39
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    • 2016
  • In this research, we focused on the improvement of cy3 dye's characteristics for LCD color filter. Solubility and thermal stability are main characteristics of dyes for LCD color filter. We performed experiment to change counter cation of cy3 dyes with alkoxy substituent for these purposes. These cy3 dyes (1b~5b) were prepared through the synthetic procedure of three steps. The synthesized new cy3 dyes were charaterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed purple color and maximum absorption wavelength (${\lambda}_{max}$) in the range of 578~590 nm in UV/Vis spectrum. We confirmed that solubility and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with alkoxy substituent have good solubility in organic solvents such as dichloromethane, methanol, and acetone. Especially, Cy3 dye with 4-nitrobenzyl counter cation (5b) gave excellent solubility characteristics.

EFFECT OF A COUNTER-TORQUE DEVICE AND THE INTERNAL HEXAGON OF ABUTMENT ON THE TIGHTENING TORQUE TRANSMITTED TO THE IMPLANT (회전방지장치와 지대주의 내육각구조가 임플란트로 전달되는 조임 회전력에 미치는 영향)

  • Lee Sang-Min;Jeon Young-Chan;Jeong Chang-Mo
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.2
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    • pp.223-231
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    • 2003
  • Statement of problem : Little is known about the effect of a counter-torque device and the internal hexagon of abutment on the tightening torque transmitted to the implant. Purpose : The purpose of this study was to examine the effect of a counter-torque device and the internal hexagon of abutment on the tightening torque transmitted to the implant. Material and Methods : In this study, three types of abutment were used, (1) two-piece conical abutment with hexagon, (2) two-piece conical abutment without hexagon, and (3) one-piece conical abutment without hexagon. The experimental groups were divided into five groups according to the type of abutment and the usage of a counter-torque device. Group I : two-piece conical abutment with internal hexagon was tightened without the use of a counter-torque device. Group II : two-piece conical abutment without internal hexagon was tightened without the use of a counter-torque device. Group III : one-piece conical abutment without internal hexagon was tightened without the use of a counter-torque device. Group IV : two-piece conical abutment with internal hexagon was tightened with the use of a counter-torque device Group V : two-piece conical abutment without internal hexagon was tightened with the use of a counter-torque device. Abutments were tightened 20Ncm torque with the use of manual torque wrench and then torque values were measured by torque-gauge. After the measurement of torque values, all groups were loosened with the use of manual torque wrench and then detorque values were measured by torque-gauge. Results : The results were as follows. 1. There were no differences in torque values among three types of abutment. 2. Regardless of the existence of the internal hexagon of abutment, a counter-torque device decreased the tightening torque transmitted to the implant about 92% 3. In group III showed the highest detorque value, however there were no differences among group I, II, IV and V. Conclusion : Within the limitations of this study, it was concluded that the internal hexagon of abutment has no effect on the tightening torque transmitted to the implant and the detorque value of abutment screw. The use of a counter-torque device is essential to prevent microfracture on the implant-bone interface but has no effect on preload.

Carbon nano-tube as the Counter electrode for Dye-sensitized Solar cell (탄소나노튜브 상대전극을 이용한 염료감응형 태양전지)

  • Koo, Bo-Kun;Lee, Dong-Yoon;Kim, Hyun-Ju;Lee, Won-Jae;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.691-694
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    • 2004
  • 염료감응형 태양전지는 다공질 $TiO_2$ 전극막, 광감응형 염료, 전해질, 상대전극으로 구성된, 전기화학적 원리를 응용한 신형태양전지이다. 염료감응형 태양전지의 상대전극으로 주로 Pt가 사용되고 있는데 본 연구에서는 탄소나노튜브를 사용하여 상대전극으로서의 가능성을 조사하였다. 제조된 탄소나노튜브 상대전극은 cyclic voltammetry와 Impedance spectroscopy을 이용하여 전기화학적 특성을 측정하였다. 또한 탄소 나노튜브 상대 전극이 태양전지의 효율 및 그 특성에 미치는 영향을 알아보기 위하여 단위 셀 태양전지를 제조하여 단파장 하에서의 광전특성을 측정하고, 이를 바탕으로 탄소나노튜브의 상대전극으로서의 가능성을 제시하였다.

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A Study on the frequency characteristic of ZnO Piezoelectric transducers (ZnO 압전변환기의 주파수특성에 관한 연구)

  • 정규원;이종덕;정광천;박상만;송준태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.189-192
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    • 1996
  • In this paper ZnO Piezoelectric transducers were fabricated as follows, counter electrode (pt 99.9%) was deposited on the sapphire substrates by DC sputter method, and then piezoelectric layer (ZnO 99.999%) was deposited on the counter electrode according to the sputtering parameters, and then top electrode (pt 99.9%) was deposited on the piezoelectric layer by Electron Beam Gun Evaporator. Structural characteristic of deposited ZnO thin film was measured by XRD, SEM. Also, Frequency characteristic of ZnO transducer was analyzed theoretically and practically for input frequencies.

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All Solid State Electrochromic (전 고체형 일렉트로크로믹 소자)

  • 채종우;조봉희;김영호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.295-298
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    • 1996
  • In this study, we have fabricated all solid state electrochromic devices using WO$_3$ film as the working electrode, V$_2$O$\_$5/ film as the counter electrode and PEO-LiClO$_4$-PC film as the solid electrolyte. The WO$_3$ thin films for working electrode and V$_2$O$\_$5/ thin films for counter electrode were deposited onto ITO glass by vacuum evaporation and were shown good electrochromic and state properties after 1x10$\^$5/ cycles. PEO-LiClO$_4$-PC polymer electrolyte can easily be formed into thin films, do not absorb in the visible region of the light. Therefore, such electrolyte have electrochromic properties suitable for large-scale all solid-state electrochromic devices. All solid-staeelectrochromic devices fabricated in this polymer electrolyte have optical modulation of 20%∼30% at 1.5 V.

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