• Title/Summary/Keyword: counter material

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Effect of carrier collector on the Efficiency of DSSCs

  • Ramasamy, Easwaramoorthi;Lee, Won-Jae;Lee, Dong-Yun;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.633-634
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    • 2005
  • Transparent conducting glasses exhibit high ohmic losses that are apparent in the case of large size Dye Sensitized Solar Cells (DSSCs). In this study, we investigated the impact of current collectors over the efficiency of DSSCs. The Silver current collectors were prepared on both counter electrode and working electrode surface by screen printing method. For long term stability in electrolyte environment and also to avoid the charge recombination, current collectors are protected by sodium silicate overcoat layer. These current collectors were characterized for their microstructure parameters. Also current collector's stability in electrolyte environment has been investigated.

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Electrochemical Properties of Mixture Langmuir-Blogett Films of Fatty Acid containing Azobenzene and Phospholipid (아조벤젠기를 가진 지방산과 인지질 혼합 LB막의 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.920-923
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    • 2004
  • We have investgated on the monolayer LB film of BASH-DMPC mixture on an ITO for the photoisomerization by light irradiation. We measured electrochemical properties by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution at a variable concentration and monolayer LB films. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of 8A5H-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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Experimental Study on the Mold Life of Fine Blanking Using Thick Plate Materials (후판 소재를 적용한 파인 블랭킹 금형 수명에 관한 연구)

  • Park, D.H.;Hyun, K.H.
    • Transactions of Materials Processing
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    • v.30 no.3
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    • pp.149-156
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    • 2021
  • Fine blanking is a high-precision process combining principles of metal stamping and cold forming. Unlike conventional metal stamping, fine blanking uses a special triple action such as V-ring force, counter force, shearing force. This study performed the effect of pocket-shaped compression molding on the mold life of the fine blanking using the 7.4mm thick SM45C material. In order to determine the lifespan of the punch and die in the fine blanking molds, a trial mold was manufactured and various punch materials were selected to perform the mold life test. A study on the life of a fine blanking mold by applying a thick plate material was experimentally performed through a mold test.

Contamination measurement, Analysis & Control for Satellite (인공위성의 오염 측정, 분석 및 관리)

  • Lee, Sang-Hoon;Hong, Seok-Jong;Cho, Hyok-Jin;Seo, Hee-Jun;Moon, Guee-Won
    • Aerospace Engineering and Technology
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    • v.9 no.2
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    • pp.116-122
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    • 2010
  • It is necessary to be careful about contamination control to minimize the accumulation of the contamination material on satellite surface during the I&T phase. In the space environment which characterized by high vacuum, high and very low temperature, contamination material causes satellite to lose its own performance. Especially, contamination material can accumulate on critical surfaces such as lenses, mirrors, and sensors. KARI(Korea Aerospace Research Institute) conducts the clean room to control and minimize the contamination effect. This paper introduces the principle of contamination and the method of measure and analysis for the contamination.

Properties of Heavyweight Concrete for Radiation Shielding (방사선 차폐용 중량콘크리트의 기초 특성)

  • Yang, Seung-Kyu;Um, Tai-Sun;Lee, Jong-Ryul;Kim, Yong-Ho;Wu, Sang-Ik;Kim, Tae-Bong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.561-564
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    • 2008
  • Concrete is considered to be one of the excellent and versatile shielding material and is widely used for the radiation shielding material. Specially, heavyweight(or high density) concrete is used in counter weights of bascule and lift bridges, but it is generally used in radiation shielding structures and differ from normal weight concrete by having a higher density and special compositions to improve its attenuation properties. Thorough examination and evaluation of heavyweight aggregate sources are necessary to obtain material suitable for the type of shielding required. Therefore, this paper aims to study mechanical properties of heavyweight concrete by using normal cement, natural and heavyweight aggregate.

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Sliding Wear and Friction Properties of Composite Materials for Friction Bushing (Friction Bushing용 복합재료의 미끄럼 마찰마모특성에 관한 연구)

  • Lee Han-Young;Heo Dae-Hong;Kim Tae-Jun;Cho Yong-Jae;Cho Bum-Rae;Hur Man-Dae
    • Tribology and Lubricants
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    • v.22 no.1
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    • pp.1-7
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    • 2006
  • The sliding friction and wear properties of mineral fiber reinforced composite(MF) and glass fiber reinforced composites(GF) are investigated to clarify their field of use and the role of each fiber in friction material. Friction and wear test reveals that GF composite has better wear resistance even though with low friction coefficient, comparing with MF composite. Glass fiber strengthen effectively the matrix and may absorb friction energy to convert it into the fracture energy of them, as well as its lubricative role. However, mineral fiber in MF composite is too small to strengthen the matrix. Then MF composite are easily plowed and worn out by asperity on counter material. Friction coefficient of MF composite is higher friction coefficient than that of GF composite and varied widely with test.

Effect of Pasternak foundation: Structural modal identification for vibration of FG shell

  • Hussain, Muzamal;Selmi, Abdellatif
    • Advances in concrete construction
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    • v.9 no.6
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    • pp.569-576
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    • 2020
  • Employment of the wave propagation approach with the combination of Pasternak foundation equation gives birth to the shell frequency equation. Mathematically, the integral form of the Lagrange energy functional is converted into a set of three partial differential equations. A cylindrical shell is placed on the elastic foundation of Pasternak. For isotropic materials, the physical properties are same everywhere, whereas the laminated and functionally graded materials, they vary from point to point. Here the shell material has been taken as functionally graded material. The influence of the elastic foundation, wave number, length and height-to-radius ratios is investigated with different boundary conditions. The frequencies of length-to-radius and height-to-radius ratio are counter part of each other. The frequency first increases and gain maximum value in the midway of the shell length and then lowers down for the variations of wave number. It is found that due to inducting the elastic foundation of Pasternak, the frequencies increases. It is also exhibited that the effect of frequencies is investigated by varying the surfaces with stainless steel and nickel as a constituent material. MATLAB software is utilized for the vibration of functionally graded cylindrical shell with elastic foundation of Pasternak and the results are verified with the open literature.

Effects of Temperature on Tribological Properties of Polymer Material (온도 조건에 따른 폴리머 소재의 트라이볼로지 특성 연구)

  • Chi-Yoon An;Dae-Eun Kim
    • Tribology and Lubricants
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    • v.39 no.6
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    • pp.262-267
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    • 2023
  • Research to replace metal mechanical elements with polymer materials has recently accelerated. However, polymers exhibit less favorable mechanical properties than metal materials, and are often easily worn-out owing to frictional heat when their mechanical elements contact while in relative motion. Therefore, research on the polymer tribological properties is required to employ polymer materials in mechanical elements operating under harsh conditions. In this study, we examine the effect of mechanical part operating temperatures on the material friction and wear characteristics of polymer materials. We conduct ball-on-disk friction tests under dry conditions at various temperatures, using a metal ball with high hardness and a polymer as the counter surface. Each test is repeated at least three times to ensure the reliability of the test results. Before the friction test, we analyze the surface hardness and roughness of each polymer specimen; after the friction test, we use a three-dimensional confocal microscope to compare and analyze the polymer specimen wear characteristics. Based on this study, we systematically elucidate the polymer material tribological characteristics. This information should be useful for selecting and utilizing polymer materials at various temperatures.

Preparation of Silicon-Carbon Composite via Magnesiothermic Reduction Method and Its Application to the Anode Material for Lithium Ion Battery (마그네슘열환원법을 이용한 실리콘-탄소 복합재 제조 및 리튬이차전지 음극재로의 이용)

  • Kim, Eudem;Kwon, Soon Hyung;Kim, Myung-Soo;Jung, Ji Chul
    • Korean Journal of Materials Research
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    • v.24 no.5
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    • pp.243-248
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    • 2014
  • Silicon-carbon composite was prepared by the magnesiothermic reduction of mesoporous silica and subsequent impregnation with a carbon precursor. This was applied for use as an anode material for high-performance lithium-ion batteries. Well-ordered mesoporous silica(SBA-15) was employed as a starting material for the mesoporous silicon, and sucrose was used as a carbon source. It was found that complete removal of by-products ($Mg_2Si$ and $Mg_2SiO_4$) formed by side reactions of silica and magnesium during the magnesiothermic reduction, was a crucial factor for successful formation of mesoporous silicon. Successful formation of the silicon-carbon composite was well confirmed by appropriate characterization tools (e.g., $N_2$ adsorption-desorption, small-angle X-ray scattering, X-ray diffraction, and thermogravimetric analyses). A lithium-ion battery was fabricated using the prepared silicon-carbon composite as the anode, and lithium foil as the counter-electrode. Electrochemical analysis revealed that the silicon-carbon composite showed better cycling stability than graphite, when used as the anode in the lithium-ion battery. This improvement could be due to the fact that carbon efficiently suppressed the change in volume of the silicon material caused by the charge-discharge cycle. This indicates that silicon-carbon composite, prepared via the magnesiothermic reduction and impregnation methods, could be an efficient anode material for lithium ion batteries.

A Study on the Efficiency of Dye Sensitized Solar Cell Based on the Volume of Binder Addition (바인더 함량에 따른 염료감응 태양전지의 효율에 관한 연구)

  • Ki, Hyun-Chul;Jung, Haeng-Yun;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.12
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    • pp.878-881
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    • 2013
  • In this study, we have fabricated the dye sensitized solar cell (DSSC) composed by a transparent conductive oxide (TCO), a nanocrystalline semiconductor film usually $TiO_2$, a sensitizer adsorbed on the surface of the semiconductor, an electrolyte containing a redox mediator and a counter electrode. The $TiO_2$ nanopowder was prepared by sol-gel methode. The HCl (hydrochloric acid) and TBAOH (Tetrabutyl amonium hydroxide) was added for improving the catalyst and distributed properties of $TiO_2$ nanopowder. Ammonium hydroixde was added in order to control the morphology and size of $TiO_2$ nano crystal. A $TiO_2$ paste for working electrode was prepared with the addition of HPC (hydroxypropyl cellulos) used as a binder of which volume was controled as 1.3, 1.5, 1.7, and 2.0%. The measured I-V curves of assembled DSSC showed that the cell with 1.7% HPC binder had the best efficiency of 6.79%.