• 제목/요약/키워드: counter material

검색결과 260건 처리시간 0.028초

염료감응형 태양전지의 탄소나노튜브 상대전극의 광투과도와 전기화학적 특성이 에너지 변환 효율에 미치는 영향 (Effect of Electrochemical Properties and Optical Transmittance of Carbon Nanotubes Counter Electrodes on the Energy Conversion Efficiency of Dye-sensitized Solar Cells)

  • 한영문;황숙현;강명훈;김영주;김현국;김상효;배효준;최현광;전민현
    • 한국전기전자재료학회논문지
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    • 제24권4호
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    • pp.333-339
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    • 2011
  • In this work, electrochemical characteristics and optical transmittance of carbon nanotubes (CNTs) counter electrodes which had different amount of CNTs in CNTs slurries were analyzed. Two-step heat treatment processes were applied to achieve well-fabricated CNTs electrode. Three sets of CNTs electrodes and dye-sensitized solar cells (DSSCs) with CNTs counter electrodes were prepared. As the amount of CNTs increased, sheet resistance of CNTs electrode decreased. CNTs electrode with low sheet resistance had low electrochemical impedance and fast redox reaction. On the other hand, in case of CNTs counter electrode with low density of CNTs, performance of the dye-sensitized solar cell was improved due to its high optical transmittance. We found that the transmittance of CNTs counter electrode influence the performance of dye-sensitized solar cells.

철강재료위 coating된 PTFE 막층의 미끄럼 마찰마모특성 연구 (A Study of Sliding Friction and Wear Properties for PTFE Layer coated on Steel)

  • 이한영
    • Tribology and Lubricants
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    • 제24권2호
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    • pp.96-103
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    • 2008
  • PTFE is generally utilized as the form of composites with adding various fillers. The purpose of this paper lies on clarifying the friction and wear properties of the PTFE coating layer on steel. Especially, the effects of PTFE powder size for coating and surface roughness of the counter material on the properties are investigated. Sliding friction and wear tests are conducted at several sliding speeds by employing two types of PTFE coating layer using different powder sizes. One type of coating layer is composed of uniform fine powder, whereas the other type is made up of mixture powder of different sizes. As results, it is found that PTFE coating layer are effective to improve the wear resistance and to reduce the friction coefficient. It is clear that PTFE coating layers are abrasively removed by asperities of the counter material during sliding contact. However, PTFE coating layer with uniform fine powder shows somewhat better wear resistance than that with mixture powder of different sizes in low sliding speed region. It can be seen that the wear of the coating layer are drastically reduced because wear fragment from counter material are transferred to the coating layer. On the other hand, friction coefficient is shown not to be directly related with PTFE powder size in coating layer.

Platinum and carbon nano tube addition in carbon black counter electrode for dye-sensitized solar cells

  • Lee, Su Young;Kim, Sang Ho
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.229-230
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    • 2012
  • Platinum (Pt) has been commonly used as a counter electrode material in dye-sensitized solar cells, because it has high catalytic activity and electric conductivity as well as chemical inertness with iodide electrolyte. However, Pt is too expensive to be commercialized. Therefore, in the present study, carbon black counter electrode with Pt and carbon nano tube (CNT) was investigated. The power conversion efficiency with Pt added carbon black electrode was lower than hat of pure Pt electrode which was 6.47 %. By adding 3 wt% Pt to the carbon black counter electrode, the power conversion efficiency was maximized at 5.88 %. On them, additional adding of 1 wt % CNT, the power conversion efficiency (${\eta}$)wasincreasedupto6.21%. The reason of power conversion efficiency improvement with a proper amount of Pt and CNT was examined by comparing the impedance properties measured using EIS.

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레이저 표면개질된 SM45C강의 마멸거동 (Wear Behavior of Laser Modified SM45C Steel)

  • 배춘익;옥철호;박흥식;전태옥
    • Tribology and Lubricants
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    • 제16권1호
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    • pp.15-21
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    • 2000
  • Radiation of Nd-YAG laser changes and refines the surface microstructure of steels, which gives rise to enhancement of hardness and resulting wear resistance. In the present work, the effect of processing parameters during the surface modification with laser on the wear behavior of the SM45C steel was studied by means of wear testing. The counter material was alumina ceramics. The microstructure observation revealed the dependence of molten depth and width on the defocusing distance. The laser modification of steel surface give rise to improved wear resistance in the testing speed range of either <0.2 m/s or >0.9 m/s Material transfer from steel was wear observated the surface of counter material when testing speed was lower than 0.7 m/s.

U형 직교 대향류 플라스틱/종이 재질 간접증발소자 (U-type Cross-Counter Indirect Evaporative Cooler made of Plastic/Paper)

  • 김내현
    • 한국산학기술학회논문지
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    • 제17권11호
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    • pp.732-739
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    • 2016
  • 여름철이 무더운 대한민국에서는 냉방에 많은 전력을 소비한다. 이 경우 간접증발냉각을 동시에 적용하면 전기 사용을 줄일 수 있다. 본 연구에서는 플라스틱/종이 재질의 U형 직교대향류 간접증발소자를 개발하고 그 성능을 기존의 직교류소자와 비교하였다. 시료의 크기는 $500mm{\times}500mm{\times}1000mm$이었다. 직교대향류 소자의 간접증발효율은 직교류 소자의 간접증발효율보다 6~21% 크고 그 차이는 전방 풍속이 증가할수록 증가하였다. 이는 직교대향류 소자의 크기가 크고 (대향류의 2배) 직교 대향류의 유용도가 직교류의 유용도보다 크기 때문이다. 직교대향류 소자의 압력손실은 직교류 소자의 압력손실보다 2배 가량 컸다. 습채널의 압력손실도 건채널보다 51~66% 컸다. ${\epsilon}$-NTU 방식의 해석 모델은 실험 데이터를 ${\pm}10%$ 이내에서 예측하였다. 직교대향류 소자를 사용하였을 때 절약되는 전기에너지는 직교류 소자의 값보다 크고 그 차이는 풍속이 증가할수록 증가하였다. 하지만 직교대향류 소자의 크기가 직교류 소자에 비하여 2배 크므로 원가의 상승과 분무수 사용량의 증가가 예상된다.

LCD Color Filter용 Cy3 염료의 제조 및 특성 연구 (Preparation and Characterization of Cy3 Dye for LCD Color Filter)

  • 이상동;현동균;정연태
    • 한국전기전자재료학회논문지
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    • 제29권1호
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    • pp.35-39
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    • 2016
  • In this research, we focused on the improvement of cy3 dye's characteristics for LCD color filter. Solubility and thermal stability are main characteristics of dyes for LCD color filter. We performed experiment to change counter cation of cy3 dyes with alkoxy substituent for these purposes. These cy3 dyes (1b~5b) were prepared through the synthetic procedure of three steps. The synthesized new cy3 dyes were charaterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed purple color and maximum absorption wavelength (${\lambda}_{max}$) in the range of 578~590 nm in UV/Vis spectrum. We confirmed that solubility and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with alkoxy substituent have good solubility in organic solvents such as dichloromethane, methanol, and acetone. Especially, Cy3 dye with 4-nitrobenzyl counter cation (5b) gave excellent solubility characteristics.

회전방지장치와 지대주의 내육각구조가 임플란트로 전달되는 조임 회전력에 미치는 영향 (EFFECT OF A COUNTER-TORQUE DEVICE AND THE INTERNAL HEXAGON OF ABUTMENT ON THE TIGHTENING TORQUE TRANSMITTED TO THE IMPLANT)

  • 이상민;전영찬;정창모
    • 대한치과보철학회지
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    • 제41권2호
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    • pp.223-231
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    • 2003
  • Statement of problem : Little is known about the effect of a counter-torque device and the internal hexagon of abutment on the tightening torque transmitted to the implant. Purpose : The purpose of this study was to examine the effect of a counter-torque device and the internal hexagon of abutment on the tightening torque transmitted to the implant. Material and Methods : In this study, three types of abutment were used, (1) two-piece conical abutment with hexagon, (2) two-piece conical abutment without hexagon, and (3) one-piece conical abutment without hexagon. The experimental groups were divided into five groups according to the type of abutment and the usage of a counter-torque device. Group I : two-piece conical abutment with internal hexagon was tightened without the use of a counter-torque device. Group II : two-piece conical abutment without internal hexagon was tightened without the use of a counter-torque device. Group III : one-piece conical abutment without internal hexagon was tightened without the use of a counter-torque device. Group IV : two-piece conical abutment with internal hexagon was tightened with the use of a counter-torque device Group V : two-piece conical abutment without internal hexagon was tightened with the use of a counter-torque device. Abutments were tightened 20Ncm torque with the use of manual torque wrench and then torque values were measured by torque-gauge. After the measurement of torque values, all groups were loosened with the use of manual torque wrench and then detorque values were measured by torque-gauge. Results : The results were as follows. 1. There were no differences in torque values among three types of abutment. 2. Regardless of the existence of the internal hexagon of abutment, a counter-torque device decreased the tightening torque transmitted to the implant about 92% 3. In group III showed the highest detorque value, however there were no differences among group I, II, IV and V. Conclusion : Within the limitations of this study, it was concluded that the internal hexagon of abutment has no effect on the tightening torque transmitted to the implant and the detorque value of abutment screw. The use of a counter-torque device is essential to prevent microfracture on the implant-bone interface but has no effect on preload.

탄소나노튜브 상대전극을 이용한 염료감응형 태양전지 (Carbon nano-tube as the Counter electrode for Dye-sensitized Solar cell)

  • 구보근;이동윤;김현주;이원재;송재성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.691-694
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    • 2004
  • 염료감응형 태양전지는 다공질 $TiO_2$ 전극막, 광감응형 염료, 전해질, 상대전극으로 구성된, 전기화학적 원리를 응용한 신형태양전지이다. 염료감응형 태양전지의 상대전극으로 주로 Pt가 사용되고 있는데 본 연구에서는 탄소나노튜브를 사용하여 상대전극으로서의 가능성을 조사하였다. 제조된 탄소나노튜브 상대전극은 cyclic voltammetry와 Impedance spectroscopy을 이용하여 전기화학적 특성을 측정하였다. 또한 탄소 나노튜브 상대 전극이 태양전지의 효율 및 그 특성에 미치는 영향을 알아보기 위하여 단위 셀 태양전지를 제조하여 단파장 하에서의 광전특성을 측정하고, 이를 바탕으로 탄소나노튜브의 상대전극으로서의 가능성을 제시하였다.

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ZnO 압전변환기의 주파수특성에 관한 연구 (A Study on the frequency characteristic of ZnO Piezoelectric transducers)

  • 정규원;이종덕;정광천;박상만;송준태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.189-192
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    • 1996
  • In this paper ZnO Piezoelectric transducers were fabricated as follows, counter electrode (pt 99.9%) was deposited on the sapphire substrates by DC sputter method, and then piezoelectric layer (ZnO 99.999%) was deposited on the counter electrode according to the sputtering parameters, and then top electrode (pt 99.9%) was deposited on the piezoelectric layer by Electron Beam Gun Evaporator. Structural characteristic of deposited ZnO thin film was measured by XRD, SEM. Also, Frequency characteristic of ZnO transducer was analyzed theoretically and practically for input frequencies.

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전 고체형 일렉트로크로믹 소자 (All Solid State Electrochromic)

  • 채종우;조봉희;김영호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.295-298
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    • 1996
  • In this study, we have fabricated all solid state electrochromic devices using WO$_3$ film as the working electrode, V$_2$O$\_$5/ film as the counter electrode and PEO-LiClO$_4$-PC film as the solid electrolyte. The WO$_3$ thin films for working electrode and V$_2$O$\_$5/ thin films for counter electrode were deposited onto ITO glass by vacuum evaporation and were shown good electrochromic and state properties after 1x10$\^$5/ cycles. PEO-LiClO$_4$-PC polymer electrolyte can easily be formed into thin films, do not absorb in the visible region of the light. Therefore, such electrolyte have electrochromic properties suitable for large-scale all solid-state electrochromic devices. All solid-staeelectrochromic devices fabricated in this polymer electrolyte have optical modulation of 20%∼30% at 1.5 V.

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