• 제목/요약/키워드: corrosive wear

검색결과 50건 처리시간 0.025초

대체냉매를 사용한 에어콘에서 합성오일과 건조제(M/S)의 영향 (Effects of Refrigerant Oils and Molecular Sieve on Air Conditioner using Alternative Refrigerant)

  • 좌성훈;홍정기;김창국;윤백;강석춘
    • 설비공학논문집
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    • 제8권4호
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    • pp.473-483
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    • 1996
  • To protect the ozone layer, R22 will be replaced with HFCs. R407C is a leading candidate as alternative refrigerant for air conditioner due to its similar thermodynamic characteristics with R22. In replacing R22 with R407C, the compatibility with lubricating oil is of major concern. Polyol ester (POE) oil among the synthetic oils is considered to be the best lubricant for use with R407C because of good electrical properties and miscibility. However, lubricating ability of mixture of R407C/POE oil is lower than that of R22/mineral oil due to the production of acid by hydrolysis which causes corrosive wear. Therefore, to minimize water content, it is needed to develop a molecular sieve desiccant which is compatible with R407C and ester oil. This paper discusses (1) the change of properties of POE oil when current molecular seive is used, (2) the effects of POE oils and additives on durability of compressor. Through compressor life test and bench wear test, it was found that inadequate use of POE oils and additives may promote the deteriation of molecular sieve, resulting in decrease of durability of compressor.

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BIOCOMPATIBISITY OF ION BEAM PROCESSED FILMS DEPOSITED ON SURGICAL TI-6AI-4V

  • Lee, I-S;Song and I-j Yu
    • 한국진공학회지
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    • 제6권S1호
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    • pp.16-22
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    • 1997
  • ion beam processing of materials for medical application has gained increasing interest in the last decade and the implantation of nitrogen into TI-6AI-4V to improve corrosive-wear performance is currently used for processing of total hip and knee joints. Oxides and nitrides of Ti, Zr, Al, Cr were deposited on TI-6AI-4V substrates by DC magnetron sputtering dual ion beam sputtering and ion beam assisted deposition. The cytotoxicity of these films were investigated by MTT method and showed comparable to untreated TI-6AI-4V Plasm-sprayed hydroxyapatite(HAp) coatings showed excellent cytotoxicity regardless of heat treatment. intermediate layer coatings of nitrides and oxides increased the bond strength of HAp to substrate by intrdducing chemical bond at interface. Heat treatment of HAp coatings also improved the chemical bond at interfaces and increased the bond strength of untreated TI-6AI-4V to 16.4 kg/$\textrm{cm}^2$ but still lower than 33.1 kg./$\textrm{cm}^2$ of ir oxide as a imtermediate layer caoting.

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온도에 따른 콘크리트 구조체 단면 보수용 폴리머 모르타르의 기초적 연구 (Fundamental Study of Polymer-modified Cement Mortar for Maintenance in Concrete Structure According to Ambient Temperature)

  • 서정필;김재원;이정구;최훈국;강철;김진만
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2007년도 춘계학술논문 발표대회
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    • pp.59-62
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    • 2007
  • Nowadays, polymer-cement mortars are widely used in construction field(floorings and pavements, water-proofings, adhesives, repair materials, deck coverings, anti-corrosive linings) Because of excellent performance such as high tensile and flexural strength, waterproofness, excellent adhesion, good durability, improved wear and chemical resistances. This article presents the results of experimental study that investigates the effect of ambient temperature on the strength properties of polymer-modified cement mortar. Results show that when increasing the polymer proportion in mortar on different ambient temperature, the compressive strength and flexural strength are decreased, and also alkali resistance is decreased.

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입환기관차의 노후도 평가 : 차체 및 대차 (Deterioration Analysis of a Shunting Locomotive: Carbody and Bogies)

  • 김정국;정종덕;편장식;장세기;홍용기;김원경
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2004년도 추계학술대회 논문집
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    • pp.269-276
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    • 2004
  • Deterioration analysis was performed on carbody and bogies of a shunting locomotive, which has been used for shunting works in steel making processes. In this investigation, various types of technical evaluation methods for the locomotive were employed to assess the current deterioration status. Corrosion test and nondestructive evaluation (NDE) techniques were employed to demonstrate the wear status of the carbody and bogie parts in the locomotive. Since the locomotive has been working under corrosive environment, the corrosion tests with x-ray analysis for exterior part of the locomotive were conducted to examine the evolution of corrosion reaction, and NDE techniques such as ultrasonic testing, magnetic particle testing, and x-ray radiography, were conducted on the carbody and bogies to inspect any possible inherent and/or in-service flaws. In this paper, the degree of deterioration in a shunting locomotive has been presented based on the analysis results.

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인공해양환경에서 플라즈마 아크 용사 공법이 적용된 Al 및 Zn 코팅의 부식 방지 성능 평가 (Anti Corrosive Performance of Al and Zn Coatings Deposited by Plasma Arc Thermal Spray Process in Artificial Ocean Water)

  • 잔낫;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 가을 학술논문 발표대회
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    • pp.52-53
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    • 2020
  • The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

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Corrosion Characteristics of Welding Zones Welded with 1.25Cr-0.5 Mo Filler Metal to Forged Steel for Piston Crown Material

  • Jeong, Jae-Hyun;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil;Moon, Kyung-Man
    • Corrosion Science and Technology
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    • 제14권2호
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    • pp.54-58
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    • 2015
  • A heavy oil of low quality has been mainly used in the diesel engine of the merchant ship as the oil price has been significantly jumped for several years. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, 1.25Cr-0.5Mo filler metal was welded with SMAW method in the forged steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. And, the corrosion resistance of the heat affected and weld metal zones was also increased than that of the base metal zone. Furthermore, it appeared that the corrosive products with red color and local corrosion like as a pitting corrosion were more frequently observed on the surface of the base metal zone compared to the heat affected and weld metal zones. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the 1.25Cr-0.5Mo electrode.

용사처리에 의한 자동차 브레이크용 마찰재료의 마찰성능개선에 관한 연구 (A study on the improvement of frictional performance of friction material for automobile brake by spray treatment)

  • 김윤해;배창원;손태관
    • Journal of Advanced Marine Engineering and Technology
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    • 제22권1호
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    • pp.67-76
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    • 1998
  • Friction materials for brake linings and clutches have severe performance requirements. The principal function of such frictional elements is to convert kinetic energy to heat, and then either to absorb or to dissipate heat. In order to achieve these objectives, the coefficient of friction must be as high as possible, independent of variations in operating conditions, and the necessary energy conversion must be accomplished with a minimum of wear on the contacting parts. In this study, Al powder, Al bronze powder and Mo powder used in general for automobile brake was sprayed on automobile brake disc to restrain rust and to maintain friction performance. Dynamo and corrosion tests have been carried out. It is concluded that the sprayed disc with Al bronze powder has the most improved frictional performance and anti-corrosive characteristics. The main results obtained can be summarized as follows; 1. From the corrosion current density test for gray cast iron and sprayed disc with powders of Al, Al bronze and Mo, it was cleared that the spray treatment with Al bronze powder showed the most superior anti-corrosive characteristics than other powders. 2. By anode polarization toward the noble direction from corrosion potential, corrosion current density with sprayed brake disc by Al-bronze powder was the lowest. 3. Mean frictional coefficients obtained from dynamo test are as follows : the sprayed disc with Al(99.99%) powder was 0.190 ; the sprayed disc with Al-bronze powder was 0.312 ; the sprayed disc with Mo powder was 0.257 ; the non-sprayed disc of gray cast iron was 0.331. In the case of the sprayed disc Al-bronze powder showed the most excellent frictional characteristics . 4. Amount of burnish quantity obtained from burnish test by dynamometer is as follows : the sprayed disc with Al-powder was 1.079 mm : the sprayed disc with Al-bronze powder was 0.155 mm : the sprayed disc with Mo powder was 0.253 mm : the non-sprayed disc of gray cast iron was 0.241 mm. Al-bronze powder also showed the most excellent burnish characteristics.

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Stellite bearings for liquid Zn-/Al-Systems with advanced chemical and physical properties by Mechanical Alloying and Standard-PM-Route

  • Zoz, H.;Benz, H.U.;Huettebraeucker, K.;Furken, L.;Ren, H.;Reichardt, R.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2000년도 춘계학술강연 및 발표대회 강연 및 발표논문 초록집
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    • pp.9-10
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    • 2000
  • An important business-field of world-wide steel-industry is the coating of thin metal-sheets with zinc, zinc-aluminum and aluminum based materials. These products mostly go into automotive industry. in particular for the car-body. into building and construction industry as well as household appliances. Due to mass-production, the processing is done in large continuously operating plants where the mostly cold-rolled metal-strip as the substrate is handled in coils up to 40 tons unwind before and rolled up again after passing the processing plant which includes cleaning, annealing, hot-dip galvanizing / aluminizing and chemical treatment. In the liquid Zn, Zn-AI, AI-Zn and AI-Si bathes a combined action of corrosion and wear under high temperature and high stress onto the transfer components (rolls) accounts for major economic losses. Most critical here are the bearing systems of these rolls operating in the liquid system. Rolls in liquid system can not be avoided as they are needed to transfer the steel-strip into and out of the crucible. Since several years, ceramic roller bearings are tested here [1.2], however, in particular due to uncontrollable Slag-impurities within the hot bath [3], slide bearings are still expected to be of a higher potential [4]. The today's state of the art is the application of slide bearings based on Stellite\ulcorneragainst Stellite which is in general a 50-60 wt% Co-matrix with incorporated Cr- and W-carbides and other composites. Indeed Stellite is used as the bearing-material as of it's chemical properties (does not go into solution), the physical properties in particular with poor lubricating properties are not satisfying at all. To increase the Sliding behavior in the bearing system, about 0.15-0.2 wt% of lead has been added into the hot-bath in the past. Due to environmental regulations. this had to be reduced dramatically_ This together with the heavily increasing production rates expressed by increased velocity of the substrate-steel-band up to 200 m/min and increased tractate power up to 10 tons in modern plants. leads to life times of the bearings of a few up to several days only. To improve this situation. the Mechanical Alloying (MA) TeChnique [5.6.7.8] is used to prOduce advanced Stellite-based bearing materials. A lubricating phase is introduced into Stellite-powder-material by MA, the composite-powder-particles are coated by High Energy Milling (HEM) in order to produce bearing-bushes of approximately 12 kg by Sintering, Liquid Phase Sintering (LPS) and Hot Isostatic Pressing (HIP). The chemical and physical behavior of samples as well as the bearing systems in the hot galvanizing / aluminizing plant are discussed. DependenCies like lubricant material and composite, LPS-binder and composite, particle shape and PM-route with respect to achievable density. (temperature--) shock-reSistibility and corrosive-wear behavior will be described. The materials are characterized by particle size analysis (laser diffraction), scanning electron microscopy and X-ray diffraction. corrosive-wear behavior is determined using a special cylinder-in-bush apparatus (CIBA) as well as field-test in real production condition. Part I of this work describes the initial testing phase where different sample materials are produced, characterized, consolidated and tested in the CIBA under a common AI-Zn-system. The results are discussed and the material-system for the large components to be produced for the field test in real production condition is decided. Outlook: Part II of this work will describe the field test in a hot-dip-galvanizing/aluminizing plant of the mechanically alloyed bearing bushes under aluminum-rich liquid metal. Alter testing, the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed. Part III of this project will describe a second initial testing phase where the won results of part 1+11 will be transferred to the AI-Si system. Part IV of this project will describe the field test in a hot-dip-aluminizing plant of the mechanically alloyed bearing bushes under aluminum liquid metal. After testing. the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed.

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Research on the Solution and Properties of Ni-P/n-$Al_2O_3$ Electroless Composite Plating

  • Huang, Yan-bin;Liu, Fei-fei;Zhang, Qi-yong;Ba, Guo-zhao;Liang, Zhi-jie
    • Corrosion Science and Technology
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    • 제6권5호
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    • pp.257-260
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    • 2007
  • In order to further improve the corrosion resistance and wear resistance of the Ni-P coatings of electroless plating, electroless Ni-P/n-$Al_2O_3$ composite deposits were prepared by adding some nano $Al_2O_3$ Particles in Ni-P plating bath. The bath composition and proproties were studied in this paper. The orthogonal test was applied in order to get the new composite solution, taking the initial stable potential as evaluation standard and considering the elements correlation at the same time. The processing parameters have been optimized by single factor experiment in which the depositing speed was chosen as the evaluation standard. The results showed that the process is stable and the composite Ni-P/n-$Al_2O_3$ deposits werebright and smooth, whose hardness and corrosion resistance are much better than simple Ni-P coatings. Furthermore the surface appearance and structure of the composite Ni-P/n-$Al_2O_3$ coating were investigated by SEM and XRD method. It was proved that the coating surface is typical cystiform cells and its structure is amorphous. All test results ofcomposite coating showed that all various physical coating properties had been improved by adding nano-particles. The hardness of optimal coating is more than 600HV and increases to 1000HV after heat-treating, and its hardness is 20~50% higher than Ni-P coating. The rust points appeared in 200 hour by immersing the coating into the 10%HCl solution and the corrosive speed is $3{\times}10^{-3}mg/(cm^2{\cdot}h)$which was obtained after 300 hour. In the same condition Ni-P coating is $5.6{\times}10^{-3}mg/(cm^2{\cdot}h)$. The salt spray resistance of the layers can exceed 600h with the thickness $20{\mu}m$.

건성마찰 소음에 대한 부식 영향도 실험연구 (An Experimental Investigation of the Effect of Corrosion on Dry Friction Noise)

  • 백종수;강재영
    • 대한기계학회논문집A
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    • 제39권12호
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    • pp.1251-1256
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    • 2015
  • 본 연구에서는 왕복운동 및 회전운동 마찰 실험장치를 이하여 부식금속의 마찰소음특성을 파악하였다. 그 결과 부식금속이 소음발생 시키고 마찰소음의 크기를 증가시키는 것을 확인하였다. 또한, 마찰소음에서 부식의 영향은 마찰표면의 변화로부터 기인하는 것을 관찰할 수 있다. 마찰이 지속적으로 발생될 때 부식금속 마찰계수의 음의 기울기가 증가하여 부식이 되지 않은 금속에 비해 상대적으로 빠르게 불안정해 질 수 있음을 확인하였다.