• 제목/요약/키워드: corrosion-erosion environment

검색결과 58건 처리시간 0.025초

Investigation of Corrosion Fatigue Phenomena in Transient Zone and Preventive Coating and Blade Design against Fouling and Corrosive Environment for Mechanical Drive Turbines

  • Hata, Satoshi;Nagai, Naoyuki;Yasui, Toyoaki;Tsukamoto, Hiroshi
    • International Journal of Fluid Machinery and Systems
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    • 제1권1호
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    • pp.121-139
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    • 2008
  • For mechanical drive steam turbines, the investigation results of corrosion fatigue phenomena in the transient zone are introduced, including basic phenomena on expansion line and actual design and damage experience. These results were analyzed from the standpoint of stress intensity during the start of cracking. In order to resolve such problems, preventive coating and blade design methods against fouling and corrosive environments are developed. Detailed evaluation test results are given for coating performance using a unique test procedure simulating fouling phenomena and washing conditions. Finally, the results of the successful modification of internals and on-line washing results on site are introduced.

오스테나이트계 STS 304강의 해수 내 전기화학적 특성에 미치는 캐비테이션의 영향 (Effect of cavitation for electrochemical characteristics in seawater for austenitic 304 stainless steel)

  • 김성종;이승준;정상옥
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권5호
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    • pp.484-492
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    • 2013
  • 세계 각국은 산업 고도화에 따라 해수환경에 내식성, 내마모성을 갖는 재료에 대한 수요가 지속적으로 증가하고 있다. 특히 표면이 미려하고 내식성이 강한 스테인리스강은 선박, 해양 플랜트 및 조류발전 등 다양한 산업분야에 널리 사용되고 있다. 그러나 해양환경에서 $Cl^-$ 이온에 의한 부식 손상과 고속회전에 따라 캐비테이션 손상이 발생하기 쉽다. 따라서 이 연구에서는 해수 내 빠른 유속 환경에 사용되는 304 스테인리스강에 대해 캐비테이션 침식-부식실험을 실시하여 외부 조건이 스테인리스강의 내식성에 미치는 영향을 종합 분석하였다. 캐비테이션이 발생된 조건에서 워터캐비테이션 피닝효과에 의한 시험편 내에 압축잔류응력 형성으로 높은 경도를 나타냈으나, 물리적 충격으로 인한 산화피막 파괴로 동전위 분극 실험에서는 높은 전류밀도를 나타냈다. 따라서 해수 내 캐비테이션에 대한 저항성을 향상시키기 위해서는 전기화학적 특성뿐만 아니라 기계적 특성도 복합적으로 고려한 재료의 선택이 필요하다.

Corrosion and Materials Selection for Bitumen with Heavy Naphthenic Acid in Canadian Oil Sands

  • Eun, Thomas Jung-Chul
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.350-361
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    • 2008
  • Canada's oil sands contain one of the largest reserves of oil in the world. According to recent estimates, there are nearly 180 billion barrels of oil in the Canadian oil sands trapped in a complex mixture of sand, water and clay. More than 40 companies have been currently operating or developing oil sands facilities since the first production in 1967. The process of oil sands upgrading is similar with down stream refinery, but the corrosion environment in upgrading refinery is often more severe than in the refinery because of high chlorides, mineral contents, carbonic acid, heavy viscosity and fouling, higher naphthenic acid [$NA-R(CH_{2})nCOOH$], and greater sulfur contents. Naphthenic acid corrosion (NAC) which is one of the most critical corrosion issues in up & downstream refinery plants was observed for the first time in 1920's in refinery distillation processes of Rumania, Azerbaizan (Baku), Venezuela, and California. As a first API report, the 11th annual meeting stated sources and mechanism of NAC in early 1930's. API has been developing the risk base standards, such as API RP580, 571, and Publication 581 which are based on the worst NAC damage in the world since 2000. Nevertheless not only the NAC phenomena and control in Canadian sands oil process are not much widely known but also there are still no engineering guidances for the Canadian sands oil in API standards. This paper will give NAC phenomina and materials selection guidance against NA environment in Canadian oil sands upgrading processes.

Investigation on electrochemical performance of Al anode material for marine growth prevention system

  • Kim, Seong-Jong;Jang, Seok-Ki;Han, Min-Su;Lee, Seung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권8호
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    • pp.968-973
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    • 2014
  • Aluminum anode of marine growth prevention system for ship is installed in seachest or sea water strainer. The Al anode is connected to a control panel that feeds a current to the anode. The dissolved ions produced by the anode are transferred in sea water, spreads through the sea water pipe system and creates a protective film in the pipelines. Thereby, corrosion in pipeline system significantly is reduced. In application on condition as a steel ship, the big accident can be caused by the corrosion. Accordingly, in this research, we evaluated influence of applied current and flow velocity on electrochemical characteristics of Al anode for marine growth prevention system (MGPS). Based on the results of the erosion-cavitation experiments, cavitation rate increased greatly until 120 min. of the experimental time and decreased a little at the point of 180 min. where pit grew and merging occurred but showed a tendency of steadily increasing consumption rates. Based on the results of the Tafel analysis, compared to static states, corrosion current densities show a rapidly increasing tendency when flow occurred.

구리합금에 대한 WC-27NiCr 초고속화염용사 코팅층의 해수내 캐비테이션 특성 평가 (Evaluation of Cavitation Characteristics in Seawater on HVOF Spray Coated Layer with WC-27NiCr Material for Cu Alloy)

  • 한민수;김민성;장석기;김성종
    • Corrosion Science and Technology
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    • 제11권6호
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    • pp.263-269
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    • 2012
  • Copper alloys are commonly applied to ship's propellers, pumps and valves which are serviced in seawater due to their good castability and corrosion resistance. In the environment of high flow velocity, however, erosion damage predominates over corrosion damage. In particular, the cavitation in seawater environment accelerates surface damage to copper alloys, resulting in degradation of products and economic losses and also threatening safety. The surface was coated with WC-27NiCr by high velocity oxygen fuel(HVOF) spraying technique to attain durability and cavitation resistance of copper alloys under high velocity/pressure flow. The cavitation test was performed for the WC-27NiCr coating deposited by HVOF in seawater at the amplitude of $30{\mu}m$ with seawater temperature. The cavitation at $15^{\circ}C$ caused exfoliation of the coating layer in 17.5 hours while that of $25^{\circ}C$ caused the exfoliation in 12.5 hours. When the temperature of seawater was elevated to $25^{\circ}C$ from $15^{\circ}C$, more damage was induced by over 160%. Although WC-27NiCr has good durability, corrosion resistance and eletrochemical stability, the cavitation damage rate of the coating layer could remarkably increase at the elevated temperatures under cavitation environments.

ALBC3 합금의 수소과전압 현상을 이용한 캐비테이션과 전기화학적 특성 (Cavitation and Electrochemical Characteristics Using Hydrogen Overpotential Method for ALBC3 Alloy)

  • 박재철;이승준;김성종
    • 한국표면공학회지
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    • 제44권6호
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    • pp.277-283
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    • 2011
  • In this study, the cavitation test and electrochemical experiments were conducted for ALBC3(Cu-Al) alloy that has an excellent corrosion resistance and cavitation characteristic in sea water. Based on the ASTMG32 regulation, the cavitation test was performed with the cavitation and cavitation erosion tester using piezoelectric effect. The electrochemical characteristics are evaluated with potentiostatic experiments in activation polarization potential range. As a result, cavitation damage is increased proportionally to temperature and time at $30{\mu}m$ amplitude. It is appeared that acceleration period in weight loss presented over 6 hours under the cavitation environment in sea water. In addition, corrosion damages were observed at the potential range of -3.2~-1.4 V as the result of potensiostatic experiments during 12 hours in activation polarization potential range.

다중시기 영상자료를 이용한 금강하류의 하중도 퇴적환경 변화 (Sedimentary Environment Change in Mid-channel Bar of the Lower Geum River Using Multi-temporal Satellite Data)

  • 홍기병;장동호
    • 환경영향평가
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    • 제18권3호
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    • pp.171-183
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    • 2009
  • This study aims to analyze the sedimentary environment change in mid-channel bar of the lower Geum river basin after the construction of the estuary barrage using multi-temporal satellite data and GIS. The sedimentary environment changes were observed in mid-channel bar areas. The mid-channel bar F was found to have been newly formed for 10 years(1996-2006), whereas the mid-channel bar B located between mid-channel bar A and C has disappeared by erosion during the same periods. When examined by section, the areas of the mid-channel bar in the upper stream section from the Yipo's reference point generally increased due to the prevailing sedimentary environments, and those of the downstream section decreased where corrosive environments are dominant. In ternms of the centroid movement, the mid-channel bars grew up toward the downstream by switching erosion and accumulation, as sedimentation was prevailing in the downstream area of mid-channel bars and corrosion was dominant in the upper stream. Through grain size analysis, the study areas are divided into three sections according to the average grain size. In Section I, the mid-channel bars were formed as a result of sedimentary process of tides in the past. In Section II, the mid-channel bars were formed partly through the sedimentary process of rivers although the sedimentary process of tides is prevailing. In Section III, the mid-channel bars were formed mainly through the sedimentary process of rivers, even if it showed the sedimentary process of tides in the past.

워터캐비테이션피닝된 동합금의 전기화학적 특성평가 (Electrochmical Characteristics by Water Cavitation Peening of Cu Alloy)

  • 김성종;한민수;김민성
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권8호
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    • pp.1083-1090
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    • 2012
  • 동합금은 내식성이 우수하기 때문에 선박 프로펠러, 펌프 임펠러등 많은 주물재료로 사용되고 있다. 또한 해양구조물 및 대체에너지 산업의 급성장으로 수요가 증가하는 추세이다. 그러나 해수환경에 장시간 노출되어 고속 회전함에 따라 발생되는 침식 및 캐비테이션 손상 때문에 잦은 수리가 요구된다. 이러한 동합금의 내구성을 향상시키기 위해서 표면개질방법의 하나로 워터캐비테이션피닝 기술이 주목받고 있다. 이 기술은 열영향이 없고 환경친화적이며 주물재료에 특히 유용한 기술이다. 따라서 본 연구에서는 주물재료인 동합금을 증류수 중에서 워터캐비테이션피닝을 다양한 시간 변수로 실시하였고, 이후 이 재료를 해수중에서 전기화학적 방법을 통해 개질된 표면의 내식성을 평가하였다. 그 결과 재료의 내구성도 향상되며, 내식성도 우수하게 나타난 조건은 2분동안 워터캐비테이션피닝을 실시한 경우였다.

Ultrasonic Cavitation Behavior and its Degradation Mechanism of Epoxy Coatings in 3.5 % NaCl at 15 ℃

  • Jang, I.J.;Jeon, J.M.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • 제20권1호
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    • pp.26-36
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    • 2021
  • Pipes operating in the seawater environment faces cavitation degradation and corrosion of the metallic component, as well as a negative synergistic effect. Cavitation degradation shows the mechanism by which materials deteriorate by causing rapid change of pressure or high-frequency vibration in the solution, and introducing the formation and explosion of bubbles. In order to rate the cavitation resistance of materials, constant conditions have been used. However, while a dynamic cavitation condition can be generated in a real system, there has been little reported on the effect of ultrasonic amplitude on the cavitation resistance and mechanism of composites. In this work, 3 kinds of epoxy coatings were used, and the cavitation resistance of the epoxy coatings was evaluated in 3.5% NaCl at 15 ℃ using an indirect ultrasonic cavitation method. Eleven kinds of mechanical properties were obtained, namely compressive strength, flexural strength and modulus, tensile strength and elongation, Shore D hardness, water absorptivity, impact test, wear test for coating only and pull-off strength for epoxy coating/carbon steel or epoxy coating/rubber/carbon steel. The cavitation erosion mechanism of epoxy coatings was discussed on the basis of the mechanical properties and the effect of ultrasonic amplitude on the degradation of coatings.

선체 구조용 강재에 대한 Al과 Zn 아크용사코팅 층의 캐비테이션 손상 특성 (Cavitation Damage Characteristics of Al and Zn Arc Thermal Spray Coating Layers for Hull Structural Steel)

  • 박일초;김성종
    • 한국표면공학회지
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    • 제49권1호
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    • pp.32-39
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    • 2016
  • In this study, Al and Zn arc thermal spray coatings were carried out onto the substrate of SS400 steel to improve corrosion resistance and durability of hull structural steel for ship in marine environment. Therefore cavitation-erosion test was conducted to evaluate the durability of painted and thermal spray coated specimens. And then the damaged surface morphology and weight loss were obtained to compare with each other, respectively. As a result, the painted specimen was the poorest cavitation resistance characteristics because surface damage behavior appeared to be exfoliated in bulk shape during the cavitation experiment. And Zn thermal spray coating layer presented the significant surface damage depth due to relatively low surface hardness and local cavitation damage tendency. On the other hand, as a result of the weight loss analysis, the painting layer presented the poorest cavitation resistance and the Al thermal spray coating layer relatively showed the best results after cavitation experiment.