• Title/Summary/Keyword: corrosion ratio

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The Optimization of Continuous Casting Process for Production of Copper Clad Steel Wire (동피복 복합선재 제조를 위한 연속주조공정의 최적화)

  • Cho, Hoon;Kim, Dae-Geun;Hwang, Duck-Young;Jo, Hyung-Ho;Kim, Yun-Kyu;Kim, Young-Jig
    • Journal of Korea Foundry Society
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    • v.25 no.6
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    • pp.259-264
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    • 2005
  • The copper clad steel wire is used extensively as lead wires of electronic components such as capacitors, diodes and glass sealing lamp because the wire combines the strength and low thermal expansion characteristic of Fe-Ni steel with the conductivity and corrosion resistance of copper. In order to fabricate the copper clad steel wire, several processes including electro-plating, tubecladding extrusion process and dip forming process have been introduced and applied. The electroplating process for the production of copper clad steel wire shows poor productivity and induces environmental load generation such as electroplating solution. The dip forming process is suitable to mass production of copper clad steel such as trolley wire. and need expensive manufacturing facilities. The present paper describes the improvement of the conventional continuous casting process to fabricate copper clad steel wire, which its core metal is low thermal expansion Fe-Ni alloy and its sheath material is copper. In particular, the formation of intermetallic compound at interface between core and sheath was investigated in order to introduce optimum continuous casting process parameter for fabrication of copper clad steel wire with higher electrical conductivity. The mechanical strength of copper clad steel wire was also investigated through wiredrawing process with of 95% in total reduction ratio.

The Effect of Citric Acid on Copper Chemical Mechanical Polishing (구연산이 Copper Chemical Mechanical Polishing에 미치는 영향)

  • Jung, Won-Duck;Park, Boum-Young;Lee, Hyun-Seop;Lee, Sang-Jic;Chang, One-Moon;Park, Sung-Min;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.565-566
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    • 2006
  • Slurry used in metal chemical mechanical polishing normally consists of an oxidizer, a complexing agent, a corrosion inhibitor and an abrasive. This paper investigates effects of citric acid as a complexing agent for Cu CMP with $H_2O_2$ as an oxidizer. In order to study chemical effects of a citric acid, x-ray photoelectron spectroscopy were performed on Cu sample after Cu etching test. XPS results reveal that CuO, $Cu(OH)_2$ layer decrease but Cu/$Cu_2O$ layer increase on Cu sample surface. To investigate nanomechanical properties of Cu sample surface, nanoindentation was performed on Cu sample. Results of nanoindentation indicate wear resistance of Cu Surface decrease. According to decrease of wear resistance on Cu surface, removal rate increases from $285\;{\AA}/min$ to $8645\;{\AA}/min$ in Cu CMP.

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Defects Evaluation at Lap Joint Friction Stir Welding by Lock-in Ultrasound Infrared Thermography (위상잠금 초음파 적외선열화상에 의한 겹치기 마찰교반용접부의 결함 평가)

  • Choi, Man-Yong;Park, Hee-Sang;Park, Jeong-Hak;Kang, Ki-Soo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.104-109
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    • 2010
  • Lap joint friction stir welding(LFSW) is an relatively new solid state joining process. A6061-T6 aluminium alloy has gathered wide acceptance in the fabrication of light weight structures requiring a high strength to weight ratio and good corrosion resistance. Test methods used in this paper, lock-in thermography, a phase difference between the defect area and the healthy area indicates the qualitative location and size of the defect. In this paper, the defects detected from the thermal image of mechanical properties for weld were evaluated and compared by the lock-in infrared thermography technique.

Feasibility Study on Diagnosis of Material Damage Using Bulk Wave Mixing Technique (체적파 혼합기법을 이용한 재료 손상 진단 적용 가능성 연구)

  • Choi, Jeongseok;Cho, Younho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.1
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    • pp.53-59
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    • 2016
  • Ultrasonic nonlinear evaluation is generally utilized for detection of not only defects but also microdamage such as corrosion and plastic deformation. Nonlinearity is determined by the amplitude ratio of primary wave second harmonic wave, and the results of its comparison are used for evaluation. Owing to the experimental features, the experimental nonlinearity result contains system nonlinearity and material nonlinearity. System nonlinearity is that which is unwanted by the user; hence, it acts as an error and interrupts analysis. In this study, a bulk wave mixing technique is implemented in order to minimize the system nonlinearity and obtain the reliable analysis results. The biggest advantage of this technique is that experimental nonlinearity contains less system nonlinearity than that for the conventional nonlinear ultrasonic technique. Theoretical and experimental verifications are performed in this study. By comparing the results of the bulk wave mixing technique with those of the conventional technique, the strengths, weaknesses, and application validity of the bulk wave mixing technique are determined.

TiN Surface-Alloying of Ti-6Al-4V Alloy by CO2 Laser (CO2 레이저에 의한 Ti-6Al-4V 합금(合金)의 TiN 표면합금화(表面合金化))

  • Park, S.D.;Lee, O.Y.;Song, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.32-43
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    • 1995
  • Ti-6Al-4V alloy are widely used in chemical and aircraft industries for their good corrosion resistance and high strength to weight ratio. Surface alloying of Ti alloy by $CO_2$ laser is able to produce few hundred micrometers thick TiN surface-alloyed layer with high hardness on the substrate very simplely by injecting reaction gas($N_2$) into a laser-generated melt pool and adjust the hardness to the specific requirements of the individual application by changing of laser processing parameters. This research has been investigated the effect of such parameters on TiN surface-alloying of Ti-6Al-4V alloy by $CO_2$ laser. The maximum hardness of TiN surface-alloyed zone waw obtained by injecting 100% $N_2$ gas and it was decreased as the amount of $N_2$ gas in Ar and $N_2$ gas mixture was decreased. As scanning speed was increased, the hardness and depth of TiN surface-alloyed zone was decreased at constant laser power. The surface hardness after double scanning laser treatment is higher than that of single scanning. At constant laser power, the surface roughness is increased after the surface alloying if laser scanning speed is decreased.

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Experimental and numerical investigation of strengthened deficient steel SHS columns under axial compressive loads

  • Shahraki, Mehdi;Sohrabi, Mohammad Reza;Azizyan, Gholam Reza;Narmashiri, Kambiz
    • Structural Engineering and Mechanics
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    • v.67 no.2
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    • pp.207-217
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    • 2018
  • In past years, numerous problems have vexed engineers with regard to buckling, corrosion, bending, and overloading in damaged steel structures. This article sets out to investigate the possible effects of carbon fiber reinforced polymer (CFRP) and steel plates for retrofitting deficient steel square hollow section (SHS) columns. The effects of axial loading, stiffness, axial displacement, the position and shape of deficient region on the length of steel SHS columns, and slenderness ratio are examined through a detailed parametric study. A total of 14 specimens was tested for failure under axial compression in a laboratory and simulated using finite element (FE) analysis based on a numerical approach. The results indicate that the application of CFRP sheets and steel plates also caused a reduction in stress in the damaged region and prevented or retarded local deformation around the deficiency. The findings showed that a deficiency leads to reduced load-carrying capacity of steel SHS columns and the retrofitting method is responsible for the increase in the load-bearing capacity of the steel columns. Finally, this research showed that the CFRP performed better than steel plates in compensating the axial force caused by the cross-section reduction due to the problems associated with the use of steel plates, such as in welding, increased weight, thermal stress around the welding location, and the possibility of creating another deficiency by welding.

A Study on the Characteristics of Low Temperature sintering Ceramic Siding Using Natural Minerals (천연광물을 활용한 저온소결 세라믹 사이딩의 특성에 관한 연구)

  • Kim, Soon-ho;Choi, Jeong-min
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.12
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    • pp.149-156
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    • 2019
  • Recently, skyscraper building and apartment fires, which were rapidly spread out from a low floor to a rooftop, have become a frequent occurrence in mass media. This fire problems have a fatal disadvantage that the exterior wall finish of the building emits toxic gas in case of fire by using dry bit method or organic insulating material. Therefore, in order to remedy these problems, many exterior wall finishing construction methods have been proposed, but the current trend is to use existing construction methods due to problems such as economy, weight, and durability. On the other hand, in countries such as Germany and Japan, ceramic sidings are used as exterior finishing material for buildings, which is environmentally friendly, excellent natural beauty, long life, easy maintenance and high-quality exterior materials. However, those ceramic sidings have still the problems such as manufacturing cost and weight problem because of boosting the sintering temperature up to 1,350℃ or more. Also, conventional CRC, MgO, FRP sidings which are composed of pulp, glass fiber and organic materials, have been reports of deformation due to ultraviolet rays, discoloration, corrosion and scattering, surface rupture, lifting and peeling. Therefore, in this study as an alternative to solve this problem, halosite nano kaolin produced in Sancheong in Korea and frit flux were used to satisfy the required properties as ceramic siding using low temperature sintering (below 1,000℃) and lightweight materials such as pearlite. This study aims to design the optimal formulation and process of materials and to study the characteristics of nano-coated ceramic siding material development and to present relevant basic data. The findings show that ceramic siding for nanocoated building materials is excellent as a natural ceramic siding building material. The fire resistance of natural minerals and nano particle refining technology satisfy the bending strength of 80kgf / cm2, the volume ratio of 2.0 and the absorption rate of less than 10.0%.

Microstructural Characteristics of Oxidation Resistant Cr-Si-Al alloys in Cast State and after High Temperature Heating (내산화성 Cr-Si-Al합금의 주조상태 및 고온가열 후의 미세조직 특성)

  • Kim, Jeong-Min;Kim, Chae-Young;Yang, Won-Chul;Park, Joon-Sik
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.156-161
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    • 2021
  • Cr-Si based alloys are not only excellent in corrosion resistance at high temperatures, but also have good wear resistance due to the formation of Cr3Si phase, therefore they are promising as metallic coating materials. Aluminum is often added to Cr-Si alloys to improve the oxidation resistance through which stable alumina surface film is formed. On the other hand, due to the addition of aluminum, various Al-containing phases may be formed and may negatively affect the heat resistance of the Cr-Si-Al alloys, so detailed investigation is required. In this study, two Cr-Si-Al alloys (high-Si & high-Al) were prepared in the form of cast ingots through a vacuum arc melting process and the microstructural changes after high temperature heating process were investigated. In the case of the cast high-Si alloy, a considerable amount of Cr3Si phase was formed, and its hardness was significantly higher than that of the cast high-Al alloy. Also, Al-rich phases (with the high Al/Cr ratio) were not found much compared to the high-Al alloy. Meanwhile, it was observed that the amount of the Al-rich phases reduced by the annealing heat treatment for both alloys. In the case of the high temperature heating at 1,400 ℃, no significant microstructural change was observed in the high Si alloy, but a little more coarse and segregated AlCr phases were found in the high Al alloy compared to the cast state.

Evaluation on De-Icing Salts Laden Environment of Road in Seoul (제설제에 노출된 서울시내 도로 시설물의 열화 환경 분석)

  • Yoon, In-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.1-9
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    • 2022
  • De -icing salts have been used commonly in areas where snow or ice is a seasonal safety hazard for roadway, however, the salts is one of main causes on serious deterioration of road infrastructures in crowded urban city like Seoul. In order to establish maintenance strategy of road infrastructures under de-icing salts laden environment, it is necessary to examine environmental characteristics and its response to the existing facilities. The purpose of this study is to evaluate the deterioration environment of road infrastructures. Additional purpose is to develop a design model and details for durability design of infrastructures under de-icing salts laden environment, considering mainly a build-up rate of surface chlorides. Concentration of external chloride solution and surface chloride content were calculated at the level of average de-icing salts for 5 years, ratio of auxiliary road of 17.5 to 30%, and effective exposure area to snow 50 to 80%. The chloride build-up rate was 0.073 ~ 0.077% / year and the maximum surface chloride content was calculated to be 2.2 ~ 2.31% by concrete wt. This study is expected to be used for establishing integrated strategy of road infrastructures, such as predicting chloride profiles or degree of chemical corrosion to exposure concrete.

Behaviour and design of stainless steel shear connectors in composite beams

  • Yifan Zhou;Brian Uy;Jia Wang;Dongxu Li;Xinpei Liu
    • Steel and Composite Structures
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    • v.46 no.2
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    • pp.175-193
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    • 2023
  • Stainless steel-concrete composite beam has become an attractive structural form for offshore bridges and iconic high-rise buildings, owing to the superior corrosion resistance and excellent ductility of stainless steel material. In a composite beam, stainless steel shear connectors play an important role by establishing the interconnection between stainless steel beam and concrete slab. To enable the best use of high strength stainless steel shear connectors in composite beams, high strength concrete is recommended. To date, the application of stainless steel shear connectors in composite beams is still very limited due to the lack of research and proper design recommendations. In this paper, a total of seven pushout specimens were tested to investigate the load-slip behaviour of stainless steel shear connectors. A thorough discussion has been made on the differences between stainless steel bolted connectors and welded studs, in terms of the failure modes, load-slip behaviour and ultimate shear resistance. In parallel with the experimental programme, a finite element model was developed in ABAQUS to simulate the behaviour of stainless steel shear connectors, with which the effects of shear connector strength, concrete strength and embedded connector height to diameter ratio (h/d) were evaluated. The obtained experimental and numerical results were analysed and compared with existing codes of practice, including AS/NZS 2327, EN 1994-1-1 and ANSI/AISC 360-16. The comparison results indicated that the current codes need to be improved for the design of high strength stainless steel shear connectors. On this basis, modified design approaches were proposed to predict the shear capacity of stainless steel bolted connectors and welded studs in the composite beams.