• Title/Summary/Keyword: corrosion rate, recycling

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Recycling of Safety Check Valves Contaminated with Radioactivity by Chemical Decontamination (化學除染에 의한 逆止밸브의 再使用)

  • 정종헌;최왕규;원휘준;심준보;오원진
    • Resources Recycling
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    • v.10 no.1
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    • pp.56-65
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    • 2001
  • Chemical decontamination techniques have been employed to reuse the high cost check valves contaminated with radioactivity and to reduce the radiation exposure during the inspection and maintenance work of safety injection system containing check valves. After chemical decontamination, an ultrasonic treatment was conducted to remove the fine solid particles retained in the crevices of check valves. The decontamination process conditions and the amount of chemical reagents were determined from the results of a pre-test, using the (list arm holder. The decontamination factors (DF), estimated from the activity in the solution, ranged from 14.5 to 18.5 corresponding to the activity removal of 93-95ft. The corrosion test data indicated that the general corrosion rate during a chemical decontamination-ultrasonic treatment process are low for type 304 S tainless steel, Inconel -600 and Stellite-6 materials $ (2.1\times10^{-2}$ $6.0\times10^{-2}$ and$ 1.7\times10^{-2}$ mil, respectively).

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Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Effect of Aluminum, Manganese, and Zirconium on the Content of Nickel in Molten Magnesium (마그네슘용탕의 니켈 함량에 미치는 알루미늄, 망간 및 지르코늄의 영향)

  • Jeong, Dae-Yeong;Moon, Young-Hoon;Moon, Byoung-Gi;Park, Won-Wook;Sohn, Keun-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.1
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    • pp.8-14
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    • 2015
  • Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.

Effects of recycling on the mechanical properties and the surface topography of Nickel-Titanium alloy wires (재생 과정이 니켈-티타늄 호선의 물리적 성질과 표면 거칠기에 미치는 영향)

  • Lee, Sung-Ho;Chang, Young-Il
    • The korean journal of orthodontics
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    • v.30 no.4 s.81
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    • pp.453-465
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    • 2000
  • The purpose of this study was to investigate the change of mechanical properties, surface topography and frictional force of various nickel titanium wires after recycling. Three types of nickel-titanium wires and one type of stainless steel wire were divided to three groups: as-received condition(T0:control group), treated in artificial saliva for four weeks(T1) and autoclaved after being treated in artificial saliva(T2). Some changes were observed for the selected mechanical properties in tensile test, surface topography by means of SEM and 3D profilogram, and frictional coefficient. The findings suggest that: 1. Nickel-titanium wires demonstrated no statistically significant differences in maximum tensile strength, elongation rate and modulus of elasticity, but stainless steel wire demonstrated statistically significant differences in maximum tensile strength, elongation rate and modulus of elasticity between the groups(p<0.05). 2. NiTi, Optimalloy, Stainless Steel wires demonstrated increased pitting and corrosion in SEM finding. 3. Recycled NiTi, Optimalloy and stainless steel wires demonstrated significantly greater surface roughness(Ra and Rq) through 3D profilogram when compared with the control wires(p<0.05), but Sentalloy didn't demonstrate significant difference. 4. Recycled NiTi, Optimalloy and stainless steel wires demonstrated significantly greater maximum frictional coefficient when compared with the control wires(p<0.05), but Sentalloy didn't demonstrate significant difference The changes of surface roughness and frictional coefficient in NiTi and Optimalloy had no clinical implication. Consequently recycled nickel titanium wires demonstrated no clinical problem in tensile properties, surface topography and frictional coefficient.

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