• Title/Summary/Keyword: corrosion prevention

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Recent Progress of Automotive Galvanized Steels in Korea

  • Lee, Suk-Kyu;Kim, Jong-Sang;Choo, Wung-Yong
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.254-258
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    • 2010
  • Due to the global warming and economic crisis, automakers are currently focusing on the development of high fuel-efficiency vehicles. To accord with these requirements, steelmakers have been trying to develop advanced high-strength steels with improved automotive-related properties. In addition, galvanizing technologies have been developed to improve coating properties for AHSS (Advanced High Strength Steel) such as pre-oxidation and pre-coating, as well as roll dent prevention. In this paper, newly developed products and technologies for automotive galvanized steel sheet are reviewed.

A Study on the Anti-corrosion Properties of Organic and Inorganic Inhibitor by Electrochemical Evaluation Method in Saturated Aqueous Solution of Calcium Hydroxide (포화 수산화칼슘 수용액 내에서의 무기계 및 유기계 방청제의 전기화학적 방식 특성평가)

  • Kim, Soo-Young;Ryu, Hwa-Sung;Kim, Sung-Kil;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.66-74
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    • 2013
  • In this study, corrosion potential ($E_{corr}$), corrosion rate, and polarization resistance were measured aimed at inorganic inhibitors (passive film type) and organic inhibitors (absorption type). The experiment was conducted using potentiostat for the variable molar ratio and chloride ion concentration of the components of inhibitors in an aqueous solution of saturated calcium hydroxide targeting corrosion. As a result, it was possible to ensure an anticorrosive performance of at least a 1.2 molar ratio of inorganic inhibitors. Also, the organic inhibitors ensured the prevention of the anticorrosive performance of at least about a 0.3 molar ratio. It also showed the tendency that between polarization resistance and corrosion rate, Ecorr and corrosion rate is inversely proportional to the linear. Conversely, the tendency between polarization resistance and Ecorr is proportional to the linear. Also, a distinct difference in organic and inorganic inhibitors' relationship to Ecorr, corrosion rate, and polarization resistance was not shown.

Study on Corrosion Problems in PEMFC Cooling System (PEMFC 냉각 시스템의 물부식 방지에 관한 연구)

  • Park, Kwang-Jin;Jeong, Jae-Hwa;Kim, Jung-Hyun;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.12
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    • pp.1188-1193
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    • 2007
  • This study focuses on the corrosion problems of STS316(stainless steel 316) tube for the cooling system of PEMFC (Proton Exchange Membrane Fuel Cell) operation. Deionized water which is highly corrosive is used especially for cooling agent of PEMFC to eliminate electrical conductivity, The tensile stress analysis was performed to check the change of mechanical strength of cooling line and pH of the water was monitored for the observation of extent of corrosion at simulated PEMFC operating condition. When STS316 tube was exposed to deionized water for 500 hours, substantial cracks were found on the surface and the pH of water was decreased from 6.8 to 5.8. For prevention of corrosion problems, the STS316 was coated by three kinds of fluororesin such as PTFE, FEP and ETFE. Among the coating materials, PTFE was the most protective in corrosive environment and was maintained the mechanical strength. To lower the cost, the same experimental analyses were carried out for iron tubes and the result will be discussed in detail.

Trend and Review of Corrosion Resistant Alloy (CRA) for Offshore Pipeline Engineering (내식합금 (CRA) 동향 및 해양 파이프라인 설계 적용에 대한 고찰)

  • Yu, Su-Young;Choi, Han-Suk;Lee, Seung-Keon;Kim, Do-Kyun
    • Journal of Ocean Engineering and Technology
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    • v.28 no.1
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    • pp.85-92
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    • 2014
  • Offshore fields are increasingly important for the development of offshore resources due to the growing energy needs. However, an offshore field for oil and gas production has difficult development conditions, e.g., high temperature, high pressure, sweet/sour compositions of fluids, etc. Corrosion is one of the biggest issues for offshore pipeline engineering. In this study, a Corrosion Resistant Alloy (CRA) pipe for corrosion prevention was investigated through its global demand and trends, and three types of CRA pipelines were introduced with detailed explanations. The usefulness of CRA was also evaluated in comparison to a carbon steel pipeline in terms of the structural strength, cost, and other factors. Offshore pipeline engineering, including mechanical design and verification of the results through an installation analysis based on numerical software, was performed for the carbon steel type and solid CRA type. The results obtained from this study will be useful data for CRA pipeline designers and researchers.

A Study on the Cavitation Corrosion of Gray Cast Iron Liner by Antifreeze (부동액에 따른 회주철 라이너의 캐비테이션 부식에 대한 연구)

  • Kim, Byeong-Ho;Kim, Byung-Hyun;Koo, Young-Ho;Seo, Jae-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.4
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    • pp.76-82
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    • 2017
  • The cylinder liner of a diesel engine is commonly made of gray cast iron. However, this cylinder liner can be damaged by the cavitation phenomenon in wet conditions. This cavitation has remained an unsolved problem until now. In this study, the cause of cavitation corrosion due to antifreeze solution was examined using a scanning electron microscope (SEM) and a 3D microscope. The necessary data to prevent the damage caused by cavitation erosion and the corrosion of gray cast iron cylinder liner was obtained. Analysis determined that the gray iron structure consists of an ${\alpha}-matrix$, flake graphite, and steadite. Cavitation erosion was initiated in the coarse flake graphite and propagated into the steadite with pitting. Under repetitive reaction conditions, the ${\alpha}-matrix$ was partially separated from the gray cast iron. This study is expected to be used as the basic data for the prevention of gray cast iron cavitation erosion and corrosion by controlling the graphite and steadite phases.

Crystal Structure Control of Calcareous Deposit Films Formed by Pulse Electrodeposition Process in Seawater and Their Properties (해수 중 펄스 전착 프로세스 의해 제작한 석회질 피막의 결정구조 제어 및 특성 평가)

  • Park, Jun-Mu;Lee, Seung-Hyo
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.103-110
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    • 2019
  • As an anti-corrosion method in seawater, cathodic protection is widely recognized as the most effective and technically appropriate corrosion prevention methodology for marine structures against harsh corrosive environment. When applying the cathodic protection in seawater, the surface of the metal facilities the formation of compounds of $CaCO_3$ and $Mg(OH)_2$. These mixed compounds are generally called 'calcareous deposits'. This layer functions as a barrier against the corrosive environment and functions to further inhibit the corrosion process and then leading to a decrease in current demand for cathodic protection. However, calcareous deposit films are partially formed on the surface of the cathode and there are some difficulties to maintain both a corrosion resistance for a long period of time and a strong adhesion between deposits and base metal. In this study, the pulse electrodeposition process was applied to improve adhesion and corrosion resistance of the calcareous deposit films, and to solve the problem of hydrogen embrittlement at high current density. The uniform and compact calcareous deposit films were prepared by pulse electrodeposition process, and their properties were characterized using various surface analytical techniques together with electrochemical methods.

A Study on the Application of Hydraulic Calculations considering the Corrosion Coefficient of Steel Piping for Fire Protection (소방용 강관배관 부식계수를 고려한 수리계산 적용방안에 관한 연구)

  • Mun, Chul-Hwan;Kang, Ho-Jung;Choi, Jae-Wook
    • Fire Science and Engineering
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    • v.34 no.4
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    • pp.69-77
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    • 2020
  • With the recent enlargement and complication of buildings, damage caused by the incidents of fires breaking out are escalating. Consequently, the use of sprinkler facilities is increasing among water-based fire extinguishing systems. Piping materials used in fire prevention systems include carbon steel (for general or pressure pipeline), CPVC, copper, and stainless-steel. Among these, the steel and CPVC pipes, which are commonly employed in fire prevention, were considered for testing the reliability of the water-based systems. This analysis was performed using the PIPENET software to perform hydraulic calculations in order to examine the flow and pressure at the terminal head when the corrosion coefficient was applied; this coefficient was applied considering the aging of pipes. Assuming a uniform pipe diameter in the steel pipes, the rated flow in the pump installed on the first floor of the basement was reduced by over 10% after 20 years had passed (C value of 90); moreover, the reduction in pressure and flow at its terminal head exceeded 30% and 16.5%, respectively. The results indicate that it is difficult to ensure the reliability of these fire prevention facilities. Furthermore, according to our estimation, considering 30 years had passed (C value of 80), the rated flow of the pump was reduced by over 15%, and the corresponding reduction in pressure and flow at its terminal head exceeded 42% and 24%, respectively.

Electrochemistry and Corrosion Characteristics of Polyaniline Dispersion Coating for Protection of Steels (강철보호를 위한 폴리아닐린 분산 코팅의 전기화학 및 부식특성)

  • Huh, Jae-Hoon;Oh, Eung-Ju;Cho, Jeong-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.6 no.2
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    • pp.113-118
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    • 2003
  • Processible polyaniline (PAM) dispersions consisting of polyaniline micro-particles, cyclohexanone, and a polymeric surfactant were prepared in a micro-milling machine with various mixing conditions. The electrochemical properties of the dispersion film coated on Pt electrode were investigated by cyclic voltammetry (CV). The electrochemistry of the PAM dispersion coatings was basically similar to a pure PAM coating based on the results of CV. The results of polarization measurements and open circuit potential measurements carried out in $3\;wt.\%$ NaCI solution showed increase in corrosion potential when the PANI dispersion coatings applied on steel surface. Variation of open circuit potential $(OCP,\;V_{OC})$ of the dispersion coating/steel electrodes was observed, which differed with milling conditions. The results demonstrated practical use of the conducting polymer dispersion as a coating material for corrosion prevention of steel.

Evaluation of the Corrosion Behavior of the Aluminum Cladding in the KMRR Fuel (KMRR 핵연료 알루미늄 피복재의 부식 거동 평가)

  • Lee, Chan-Bock;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.526-535
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    • 1994
  • For the evaluation of the corrosion behavior of the aluminum cladding in the KMRR(Korea Multipurpose Research Reactor) fuel, a modified Griess correlation was derived by introducing a heat flux factor derived from the comparison of the measured in-reactor corrosion data with the prediction of the Griess correlation. As a design criterion on the corrosion to maintain the KMRR fuel integrity, prevention of the oxide spallation was conservatively selected, which is conservatively assumed to occur when the temperature difference across the oxide layer exceeds 114$^{\circ}C$. A bounding power history of the KMRR fuel was determined by examining all the power histories of the KMRR fuel from cycle 1 to equilibrium cycle, and used to predict the maximum possible corrosion. Results of the corrosion prediction of the KMRR fuel with the bounding power history showed that the maximum local thickness of the oxide layer would be below 50$\mu$m and the design criterion on the oxide spallation would be satisfied with a factor of two margin. Therefore, it can be said that corrosion of the cladding will not impair the integrity of the KMRR fuel. Nevertheless, the applicability of the modified Griess correlation to the KMRR needs to be further verified through the KMRR fuel corrosion surveillance.

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