• Corrosion Science and Technology
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• 제3권4호
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• pp.148-153
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• 2004

Magnesium thin flims were prepared on cold-rolled steel substrates by RF magnetron sputtering technique. The influence of argon gas pressure and substrate bias voltage on their crystal orientation and morphology of the coated films were investigated by scanning electron microscopy (SEM) and X-ray diffraction, respectively. And the effect of crystal orientation and morphology of magnesium films on corrosion behaviors was estimated by measuring anodic polarization curves in deaerated 3%NaCl solution. From the experimental results, all the sputtered magnesium films showed obviously good corrosion resistance to compare with 99.99% magnesium target of the sputter-evaporation metal. Finally it was shown that the Corrosion-resistance of magnesium films can be improved greatly by controlling the crystal orientation and morphology with effective use of the plasma sputtering technique.

• ETRI Journal
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• 제21권3호
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• pp.16-21
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• 1999

After etching Al-Cu alloy films using SiCl4/Cl_2/He/CHF3 mixed gas plasma, the corrosion phenomenon at the grain boundary of the etched surface and a passivation layer on the etched surface with an SF6 plasma treatment subsequent to the etching were studied. In Al-Cu alloy system, corrosion occurs rapidly on the etched surface by residual chlorine atoms, and it occurs dominantly at the grain boundaries rather than the crystalline surfaces. To prevent corrosion, the SF6 gas plasma treatment subsequent to etching was carried out. The passivation layer is composed of fluorine-related compounds on the etched Al-Cu surface after the SF6 treatment, and it suppresses effectively corrosion on the surface as the SF6 treatment pressure increases. Corrosion could be suppressed successfully with the SF6 treatment at a total pressure of 300 mTorr. To investigate the reason why corrosion could be suppressed with the SF6 treatment, behaviors of chlorine and fluorine were studied by various analysis techniques. It was also found that the residual chlorine incorporated at the grain boundary of the etched surface accelerated corrosion and could not be removed after the SF6 plasma treatment.

• 한국해양공학회지
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• 제22권5호
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• pp.100-105
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• 2008

A106 Carbon Steel has recently been used as the material for pipes, nozzles, and tank shells in nuclear power plants. Its corrosion resistance gives the steel many advantages for use in structures under high temperature and high pressure. This steel is also expected to be used as a structural material in the shipbuilding industry for applications involving severe conditions, such as high temperature and pressure. In this study, the mechanical properties of A106 carbon steel were evaluated in regard to its corrosion times. The tensile and yielding strengths decreased as the corrosion time increased. In particular, the tensile strength was influenced by corrosion. In addition, an acoustic emission (AE) technique was used to clarify the microscopic damage to specimens that had undergone corrosion for a certain period. It was found that AE parameters, such as events, energy, duration time, and amplitude were useful for evaluating the degree of damage and remaining life of the corroded specimen. Various properties of the waveform and frequency range were also seen, based on the degree of damage to the specimen from the corrosion time.

• 한국압력기기공학회 논문집
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• 제10권1호
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• pp.96-99
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• 2014

The aim of the study was to evaluate the water treatment of pressurized water reactor secondary side by the mixed amine of ammonia and ethanolamine, from the standpoint of corrosion control, as compared with all volatile treatment of ammonia. The pressurized water reactor systems have switched a secondary side pH control agent to minimize the corrosion in the moisture separator/reheater and feedwater heater systems and the transport of corrosion products into steam generator. As results of field test, pH was increased in the steam generator and the wet steam area of moisture separator/reheater and the concentration of Fe were decreased by more than 50% as compared with water treatment of ammonia.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.1041-1044
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• 2001

This study was performed to evaluate the effect of non-uniform corrosion distribution on the analysis of concrete cover failure. A series of experiments have been undertaken to measure the corrosion rate of reinforcement according to the concentration of chloride ion so as to suggest a relationship between the reinforcement corrosion rate and chloride ion density. The corrosion induced pressure depending on the density of chloride ion has been derived. And nonlinear analysis assuming nonlinear corrosion distribution for cover cracking was achieved and compared with other experimental results to verify the accuracy of the model. Analysis was also performed for various parameters to compare their effects.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.900-907
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• 2000

The three-dimensional turbulent flow in curved pipes susceptible to flow-accelerated corrosion has been analyzed numerically to predict the pressure and shear stress distributions on the inner surface of the pipes. The analysis employs the body-fitted non-orthogonal curvilinear coordinate system and a standard $ {\kappa}-{\varepsilon}$ turbulence model with wall function method. The finite volume method is used to discretize the governing equations. The convection term is approximated by a high-resolution and bounded discretization scheme. The cell-centered, non-staggered grid arrangement is adopted and the resulting checkerboard pressure oscillation is prevented by the application of a modified version of momentum interpolation scheme. The SIMPLE algorithm is employed for the pressure and velocity coupling. The numerical calculations have been performed for two curved pipes with different bend angles and curvature radii, and discussions have been made on the distributions of the primary and secondary flow velocities, pressure and shear stress on the inner surface of the pipe to examine applicability of the present analysis method. As the result it is seen that the method is effective to predict the susceptible systems or their local areas where the fluid velocity or local turbulence is so high that the structural integrity can be threatened by wall thinning degradation due to flow-accelerated corrosion.

• Tribology and Lubricants
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• 제30권2호
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• pp.99-107
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• 2014

Fretting corrosion tests are conducted with a constant displacement amplitude using silver-plated brass coupons to investigate the effect of contact pressure on fretting corrosion. Three behaviors are identified based on the change in electric resistance and friction coefficient during the fretting test period, and the identified behaviors are dependent on the magnitude of the applied load. The failure cycle ($N_f$) with an electric resistance of 0.1 D cannot be achieved due to the adhesion behavior of the metal and metal contact under the higher applied load of 0.45 N. This suggests that an average contact pressure higher than 159 MPa for the silver-coated connector is desirable to gain an almost infinite lifetime. The relationship between the electric contact resistance (R) and the average contact pressure (p) can be written as $p=106.2{\times}{\Omega}^{-1.5}$.

• Nuclear Engineering and Technology
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• 제54권12호
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• pp.4481-4490
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• 2022

In this study, a new rupture disk corrosion test (RDCT) method was developed for real-time detection of stress corrosion cracking (SCC) initiation of Alloy 600 in a primary water environment of pressurized water reactors. In the RDCT method, one side of a disk specimen was exposed to a simulated primary water at high temperature and pressure while the other side was maintained at ambient pressure, inducing a dome-shaped deformation and tensile stress on the specimen. When SCC occurs in the primary water environment, it leads to the specimen rupture or water leakage through the specimen, which can be detected in real-time using a pressure gauge. The tensile stress applied to the disk specimen was calculated using a finite element analysis. The tensile stress was calculated to increase as the specimen thickness decreased. The SCC initiation time of the specimen was evaluated by the RDCT method, from which result it was found that the crack initiation time decreased with the decrease of specimen thickness owing to the increase of applied stress. After the SCC initiation test, many cracks were observed on the specimen surface in an intergranular fracture mode, which is a typical characteristic of SCC in the primary water environment.

• Advances in concrete construction
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• 제7권4호
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• pp.203-210
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• 2019

Concrete structures in marine environment are susceptible to chloride attack, where chloride diffusion results in the corrosion of steel bar and further lead to the cracking of concrete cover. This process causes structural deterioration and affects the response of concrete structures to different forms of loading. This paper presents the use of ABAQUS Finite Element Software in simulating the processes involved in concrete's structural degradation from chloride diffusion to steel corrosion and concrete cover cracking. Fick's law was used for the chloride diffusion, while the mass loss from steel corrosion was obtained using Faraday's law. Pressure generated by steel corrosion product at the concrete-steel interface was modeled by applying uniform radial displacements, while concrete smeared cracking alongside the Extended Finite Element Method (XFEM) was used for concrete cover cracking simulation. Results show that, chloride concentration decreases with penetration depth, but increases with exposure time at the concrete-steel interface. Cracks initiate and propagate in the concrete cover as pressure caused by the steel corrosion product increases. Furthermore, the crack width increases with the exposure time on the surface of the concrete.

• 동력기계공학회지
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• 제18권5호
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• pp.80-87
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• 2014

The pipelines are apt to erosion or corrosion because of the high-speed flow of water and steam with high temperatures or high pressures. This study was carried out a finite element analysis (FEA) and an experimental for the fracture behavior of T-joint pipes with local wall thinning under internal pressure. Local wall thinning was machined on the pipes in order to simulate erosion and corrosion of the metal. The configurations of the eroded area included an eroded ratio of d/t=0.80~0.963 and an eroded length of l=25 mm, 50 mm, and 102 mm. Three-dimensional elastic-plastic analyses were also carried out using FEA, which accurately simulates failure behaviors. In regards to the relationship between pressure and eroded, the criterion that indicates what can be used safely under operating pressure and design pressure were obtained from FEA. The FEA results were in relatively good agreement with that of the experiment.