• Journal of Electrochemical Science and Technology
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• v.11 no.4
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• pp.368-378
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• 2020

In the paper, corrosion behavior of T91 steel in different concentrations of NaHSO₃ solution was studied in combination with scanning electron microscope (SEM) and electrochemical measurements. The results showed that the steel exhibited active anodic dissolution characteristics in the solution, and NaHSO₃ concentration affected both cathodic and anodic behaviors. The steel surface was covered by intact corrosion products in the solutions, but the compactness and mechanical properties of the corrosion products degraded with the increase of NaHSO₃ concentration. In low-concentration NaHSO₃ solution the steel tended to undergo uniform corrosion with slight corrosion pits, but its corrosion mode gradually transited to localized corrosion as the NaHSO₃ concentration increased. The mechanical property degradation of the corrosion products caused by sulfur compounds and the pH decrease of the solution are the important factors to accelerating its corrosion process.

• Computers and Concrete
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• v.15 no.3
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• pp.411-436
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• 2015

In this work, a comprehensive approach to model the structural behaviour of Reinforced Concrete (RC) beams subjected to reinforcement corrosion is proposed. The coupled environmental - mechanical damage model developed by some of the authors is enhanced for considering the main effects of corrosion on concrete, on composite interaction between reinforcement bars and concrete and on steel reinforcement. This approach is adopted for reproducing a set of experimental tests on RC beams with different corrosion degrees. After the simulation of the sound beams, the main parameters involved in the relationships characterizing the effects of corrosion are calibrated and tested, referring to one degraded beam. Then, in order to validate the proposed approach and to assess its ability to predict the structural response of deteriorated elements, several corroded beams are analyzed. The numerical results show a good agreement with the experimental ones: in particular, the proposed model properly predicts the structural response in terms of both failure mode and load-deflection curves, with increasing corrosion level.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.1
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• pp.1-7
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• 2007

In this study, the influence of compressive residual stress and corrosive condition for corrosion fatigue crack was investigated, after immersing in 3.5%NaCl, $10%HNO_3+3%HF,\;6%FeCl_3$. The immersion period was performed for 90days. The fatigue characterization of a spring steel with processed shot peening were performed by considering the several corrosion environments in the range of stress ratio of 0.05 by means of opening mode displacement. By using the methods mentioned above, the following conclusions have been drawn: The fatigue life shows more improvement in the shot peened material than that in the un peened material. And the fatigue life shows improvement in ambient than in corrosion conditions. Threshold stress intensity factor range of the shot peened materials has higher than of the un peened materials. And the threshold stress intensity factor range was decreased in corrosion environments over ambient.

• Journal of Electrochemical Science and Technology
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• v.9 no.4
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• pp.260-275
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• 2018

The corrosion inhibition of cast iron in 1 M HCl by Phenanthroline (Phen) was investigated using potentiodynamic polarization (PDP) curves, electrochemical impedance spectroscopy (EIS), surface analysis and theoretical calculations. It is found that Phen exhibits high inhibition activity towards the corrosive action of HCl and its adsorption obeys the Langmuir adsorption isotherm model. The results showed that inhibition efficiency increases with Phen concentration up to a maximum value of 96% at 1.4 mM, and decreases slightly with the increase in temperature. The free adsorption energy value indicates that Phen adsorbs on cast iron surface in 1 M HCl via a simultaneous physisorption and chemisorption mechanism. Scanning electron microscopy (SEM) micrographs, atomic force microscopy (AFM) and FTIR analysis confirmed the formation of a protective film on cast iron surface, resulting in the improvement of its corrosion resistance in the studied aggressive solution. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of Phen molecules with their adsorption mode.

• Corrosion Science and Technology
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• v.20 no.2
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• pp.69-76
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• 2021

In this work, we have performed a corrosion failure analysis of a leaking tube connected to an upper header of a condensate pre-heater in a heat recovery steam generator. It was revealed that the leakage position in the tube was the location where the materials were easily vulnerable due to tensile residual stresses induced by the material manufacturing process and welding process. In addition to an imbalance in the module induced by temperature difference during operation of the pre-heater, the weight of the modules and thermal fatigue provoked a type of stress of tensile-tensile fatigue on the tube. Thus, the leakage position of the pre-heater was exposed to the tensile stress on the inner surface of the tube facing the gas, which rendered the unstable oxide layer susceptible to corrosion and the formation of pits on the water side. The cracks propagated along with the degraded microstructure in a transgranular cracking mode under fatigue loading and finally resulted in water leakage.

• Smart Structures and Systems
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• v.15 no.3
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• pp.787-806
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• 2015

Due to corrosion, a large number of belt conveyors support structure in industrial plants have deteriorated. Severe corrosion may result in collapse of the structures. Therefore, practical and effective structural assessment techniques are needed. In this paper, damage identification methods based on two specific local vibration modes, named periodic and isolated local vibration modes, are proposed. The identification methods utilize the facts that support structures have many identical members repeated along the belt conveyor and there exist some local modes within a small frequency range where vibrations of these identical members are much larger than those of the other members. When one of these identical members is damaged, this member no longer vibrates in those modes. Instead, the member vibrates alone in an isolated mode with a lower frequency. A damage identification method based on frequencies comparison of these vibration modes and another method based on amplitude comparison of the periodic local vibration mode are explained. These methods do not require the baseline measurement records of undamaged structure. The methods is capable of detecting multiple damages simultaneously. The applicability of the methods is experimentally validated with a laboratory model and a real belt-conveyor support structure.

• Journal of The Korean Society of Agricultural Engineers
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• v.46 no.1
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• pp.41-51
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• 2004

FRP re-bar in concrete structures could be used as a substitute of steel re-bars for that cases in which aggressive environment produce high steel corrosion, or lightweight is an important design factor, or transportation cost increase significantly with the weight of the materials. But FRP fibers have only linearly elastic stress-strain behavior; whereas, steel re-bar has linear elastic behavior up to the yield point followed by large plastic deformation and strain hardening. Thus, the current FRP re-bars are not suitable concrete reinforcement where a large amount of plastic deformation prior to collapse is required. The main objectives of this study in to evaluate the tensile behavior and the fracture mode of hybrid FRP re-bar. Fracture mode of hybrid FRP re-bar is unique. The only feature common to the failure of the hybrid FRP re-bars and the composite is the random fiber fracture and multilevel fracture of sleeve fibers, and the resin laceration behavior in both the sleeve and the core areas. Also, the result of the tensile and interlaminar shear stress test results of hybrid FRP re-bar can provide its excellent tensile strength-strain and interlaminar stress-strain behavior.

• Nuclear Engineering and Technology
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• v.24 no.1
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• pp.52-62
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• 1992

Radioactive nuclides deposited on out-of-core surface after the radiation in the core by the transport of corrosion products (CRUD) through the primary coolant system in PWR which is the major plant type in Korea, are leading sources of radiation exposure to plant maintenance personnel. Thus, the optimal chemistry operation method is required for the reduction of radiation exposure by the corrosion products. This study analysed the actual water chemistry operation data of four operating domestic PWRs. And in order to evaluate the coolant chemistry operation data, a computer code which can calculate the activity buildup in the various chemistry conditions of PWR coolant was employed. Through the analysis of comparison between the activity buildup of actual water chemistry operation mode and that of assumed Elevated Li operation mode calculated by the computer code, it was found that the out-of core radioactivity can be reduced by diminishing the deposition of corrosion products on the core in case that the Elevated Li operation mode is applied to the coolant chemistry operation of PWR. And the higher coolant pH operation was shown to have the advantage of the reduction of out-of-core activity buildup if the integrity of system structural materials and fuel cladding is guaranteed.

• International Journal of Naval Architecture and Ocean Engineering
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• v.7 no.3
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• pp.435-451
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• 2015

Evaluation of the performance of aging structures is essential in the oil and gas industry, where the inaccurate prediction of structural performance can have significantly hazardous consequences. The effects of structure failure due to the significant reduction in wall thickness, which determines the burst strength, make it very complicated for pipeline operators to maintain pipeline serviceability. In other words, the serviceability of gas pipelines and elbows needs to be predicted and assessed to ensure that the burst or collapse strength capacities of the structures remain less than the maximum allowable operation pressure. In this study, several positions of the corrosion in a subsea elbow made of API X42 steel were evaluated using both design formulas and numerical analysis. The most hazardous corrosion position of the aging elbow was then determined to assess its serviceability. The results of this study are applicable to the operational and elbow serviceability needs of subsea pipelines and can help predict more accurate replacement or repair times.

• Journal of Welding and Joining
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• v.33 no.4
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• pp.37-43
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• 2015

Characteristics of dissimilar metal welds between STS 316L and carbon steel ASTM A516 Gr.70 made with GTAW have been evaluated in terms of microstructure, ferrite content, chemical analysis, hardness and corrosion resistance. Three heat inputs of 9.00, 11.25, 13.00kJ/cm were employed to make joints of dissimilar metals with ER309 wire. Based on microstructural examination, the amount of vermicular type of ${\delta}$-ferrite was increased with increasing heat input due to the increase of Creq/Nieq in the second layer of welds. Based on the EDX analysis of weld metals, Cr and Ni content in the 2nd layer increased while those content in the first layer of welds decreased with heat inputs. Cellular solidification mode in the 1st layer and dendritic solidification mode in the 2nd layer due to different cooling rates were prevailed, respectively. Heat affected zone which formed hard microstructure showed higher hardness than the weld metal. The salt spray test of dissimilar metals weld joints showed that the carbon steel surfaces only corroded. The weight loss rate due to corrosion increased up to 100hours but it decreased above 100 hours. There was little difference in the weight loss caused by corrosion regardless of heat inputs.