• Journal of the Korean institute of surface engineering
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• v.55 no.1
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• pp.24-31
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• 2022

This study investigated the effect of pre-treatment on the PEO film formation of AZ91 Mg alloy. The pre-treatment was conducted for 10 min at room temperature in 0.5 M oxalic acid (C₂H₂O₄) solution containing various ammonium fluoride (NH₄F) concentrations. The pre-treated AZ91 Mg specimens were anodized at 100 mA/cm² of 300 Hz AC for 2 min in 0.1 M NaOH + 0.4 M Na₂SiO₃ solution. When AZ91 Mg alloy was pretreated in 0.5 M oxalic acid with NH₄F concentration less than 0.3 M, continuous dissolution of the AZ91 Mg alloy occurred together with the formation of black smuts and arc initiation time for PEO film formation was very late. It was noticed that corrosion rate of the AZ91 Mg alloy became faster if small amount of NH₄F concentration, 0.1 M, is added. The fast corrosion is attributable to fast formation of porous fluoride together with porous oxides in the reaction products. On the other hand, when AZ91 Mg alloy was pretreated in 0.5 M oxalic acid with sufficient NH₄F more than 0.3 M, a thin and dense protective film was formed on the AZ91 Mg alloy surface which resulted in faster initiation of arcs and formation of PEO film.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.5 no.2
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• pp.1-6
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• 2009

Nuclear power plants (NPP) using Alloy 600 (Ni 75wt%, Cr 15wt%, Fe 10wt%) as a heat exchanger tube of the steam generator (SG) have experienced various corrosion problems by ageing such as pitting, intergranular attack (IGA) and stress corrosion cracking (SCC). In spite of much effort to reduce the material degradations, SCC is still one of important problems to overcome. Especially lead is known to be one of the most deleterious species in the secondary system that cause SCC of the alloy. Even Alloy 690 (Ni 60wt%, Cr 30wt%, Fe 10wt%) as an alternative of Alloy 600 because of outstanding superiority to SCC is also susceptible to leaded environment. An oxide on SG tubing materials such as Alloy 600 and Alloy 690 is formed and modified expanding to complex sludge throughout hideout return (HOR) of various impurities including Pb. Oxide formation and breakdown is requisite for SCC initiation and propagation. Therefore it is expected that an oxide property such as a passivity of an oxide formed on steam generator tubing materials is deeply related to PbSCC and an inhibitor to hinder oxide modification by lead efficiently can be found. In the present work, the SCC susceptibility obtained by using a slow strain rate test (SSRT) in aqueous solutions with and without lead was discussed in view of the oxide property. The oxides formed on Alloy 600 and Alloy 690 in aqueous solutions with and without lead were examined by using a transmission electron microscopy (TEM), an energy dispersive x-ray spectroscopy (EDXS), an x-ray photoelectron spectroscopy (XPS) and an electrochemical impedance spectroscopy (EIS).

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.549-552
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• 2008

Corrosion of reinforcing steel is prohibited under normal condition by the alkalinity of the pore water in the concrete. But the probability of steel corrosion becomes higher when the chloride ions are introduced into the concrete. Steel corrosion is decisive factor for the determination of service life of the marine concrete structures because chloride ions are abundant in the sea. In this paper, chloride penetration analysis for the rectangular pier in the marine environment is performed considering the diffusion movement of chlorides. Result reveals that the chloride concentration in the corner bar is higher than that of in the side bar with rectangular pier. Also the time to the specified accumulation of chloride in the corner bar is much shorter than that in the side bar. Because the corrosion initiation time of corner bar is half as much as that of side bar, service life for the rectangular pier in marine environment should be determined with respect to the coner bar.

• Corrosion Science and Technology
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• v.3 no.5
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• pp.198-208
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• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.1
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• pp.8-17
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• 2003

Fracture behaviors of pipes with local wall thinning are very important for the integrity of nuclear Power Plant. In Pipes of energy Plants, sometimes, the local wall thinning may result from severe erosion-corrosion (E/C) damage. However, the effects of local wall thinning on strength and fracture behaviors of piping system were not well studied. In this paper, the monotonic bending tests were performed of full-scale carbon steel pipes with local wall thinning. A monotonic bending load was applied to straight pipe specimens by four-point loading at ambient temperature without internal pressure. From the tests, fracture behaviors and fracture strength of locally thinned pipe were manifested systematically. The observed failure modes were divided into four types; ovalization. crack initiation/growth after ovalization, local buckling and crack initiation/growth after local buckling. Also, the strength and the allowable limit of piping system with local wall thinning were evaluated.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.11a
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• pp.242-246
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• 2004

Effects of circumferentially local wall thinning on the fracture behavior of pipes were investigated by monotonic four-point bending. Local wall thinning was machined on the pipes in order to simulate erosion/corrosion metal loss. The configurations of the eroded area included an eroded ratio of d/t= 0.2, 0.5, 0.6, and 0.8, and an eroded length of I = 10 mm, 25 mm, and 120 mm. Fracture type could be classified into ovalization, local buckling, and crack initiation depending on the eroded length and eroded ratio. Three-dimensional elasto-plastic analyses were also carried out using the finite element method, which is able to accurately simulate fracture behaviors excepting failure due to cracking. It was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the eroded area.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.585-588
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• 2008

To predict the service life of reinforced concrete structures exposed to chloride environment, quantitative measures of material properties such as the critical chloride content for corrosion in concrete and the diffusion coefficient of chloride ions of concrete and the surface chloride content of the concrete are essential. However, it should be noted that they are influenced by several factors such as concrete mix proportions, cement type, and environmental conditions, etc. Thus, the purpose of this research is to estimate more actually the critical chloride content for corrosion of the reinforcing steel in concrete by field exposure experiment. For this purpose, the prism concrete test specimens were made for water-cement(W/C) ratios of 31%, 42%, 50%, and 70%, and then the field exposure experiment for them were conducted at Youngduk of the east coast for about 3 years. During the test, corrosion monitoring by half cell potential method was carried out to detect the time to initiation of corrosion for test specimens and its chloride content was evaluated by breaking the concrete test specimens when corrosion of the reinforcing steel in concrete was perceived. It was observed from the test results that the critical chloride content for corrosion of reinforcing steel in concrete would be dependent on W/C ratio and almost irrespective of concrete cover.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1A
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• pp.75-89
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• 2006

This paper presents a practical and realistic Life-Cycle Cost (LCC) optimum design methodology of steel bridges considering time effect of bridge reliability under environmental stressors such as corrosion and heavy truck traffics. The LCC functions considered in the LCC optimization consist of initial cost, expected life-cycle maintenance cost and expected life-cycle rehabilitation costs including repair/replacement costs, loss of contents or fatality and injury losses, road user costs, and indirect socio-economic losses. For the assessment of the life-cycle rehabilitation costs, the annual probability of failure which depends upon the prior and updated load and resistance histories should be accounted for. For the purpose, Nowak live load model and a modified corrosion propagation model considering corrosion initiation, corrosion rate, and repainting effect are adopted in this study. The proposed methodology is applied to the LCC optimum design problem of an actual steel box girder bridge with 3 continuous spans (40 m+50 m+40 m=130 m), and various sensitivity analyses of types of steel, local corrosion environments, average daily traffic volume, and discount rates are performed to investigate the effects of various design parameters and conditions on the LCC-effectiveness. From the numerical investigation, it has been observed that local corrosion environments and the number of truck traffics significantly influence the LCC-effective optimum design of steel bridges, and thus realized that these conditions should be considered as crucial parameters for the optimum LCC-effective design.

• Journal of Ocean Engineering and Technology
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• v.21 no.2 s.75
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• pp.50-59
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• 2007

Steam generator tubes are degraded from wear, stress corrosion cracking, rupture and fatigue and so on. Therefore, the failure assessment of steam generator tube is very important for the integrity of energy plants. In the steam generator tubes, sometimes, the local wall thinning may result from severe degradations such as erosion-corrosion damage and wear due to vibration. In this paper, the elasto-plastic analysis was performed by FE code ANSYS on steam generator tubes with wall thinning. Also, the four-point bending tests were performed on the wall thinned specimens, and then it was compared with the analysis results. We evaluated the failure mode, fracture strength and fracture behavior from the experiment and FE analysis. Also, it was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the thinned area from FE analysis.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.83-84
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• 2008

The primary water stress corrosion cracking (PWSCC) of dissimilar metal weld based on Alloy 82/182 is one of major issues in material degradation of nuclear components. It is well known that the crack initiation and growth due to PWSCC is influenced by material's susceptibility to PWSCC and distribution of welding residual stress. Therefore, modeling the welding residual stress is of interest in understanding crack formation and growth in dissimilar metal weld. Currently in Korea, a numerical round robin study is undertaken to provide guidance on the welding residual stress analysis of dissimilar metal weld. As a part of this effort, the present paper investigates distribution of welding resisual stress of a ferritic low alloy steel nozzle with dissimilar metal weld using Alloy 82/182. Two-dimensional thermo-mechanical finite element analyses are carried out to simulate multi-pass welding process on the basis of the detailed design and fabrication data. The present results are compared with those from other participants, and more works incorporating physical measurements are going to be performed to quantify the uncertainties relating to modelling assumptions.