• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.375-381
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• 2017

Recently, due to the increasing of interest about the eco-friendly concrete, it is being increased to use concretes containing by-products of industry such as fly ash, ground granulated blast furnace slag, silica fume, and etc. Especially, these are well known for improving the resistance to reinforcement corrosion in concrete and decreasing chloride ion penetration. The purpose of this experimental research is to evaluate the resistance to corrosion of reinforcement and critical chloride content of high volume fly ash concrete(HVFAC) which is replaced with fly ash for approximately 50% cement content. For this purpose, corrosion monitoring of reinforcement by half cell potential method was carried out for the cylindrical test specimens that the upper of reinforcement in concrete was exposed to detect the time of corrosion initiation for reinforcement. It was observed from the test result that the the time of corrosion initiation for reinforcement of HVFAC by the accelerated corrosion tests increased 1.2~1.3 times than plain concrete and the critical chloride contents of plain concrete and HVFAC were found to range $0.80{\sim}1.20kg/m^3$, $0.89{\sim}1.60kg/m^3$, respectively.

• Journal of the Korean Society for Nondestructive Testing
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• v.33 no.5
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• pp.409-414
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• 2013

In this work, corrosion of 304 stainless steel was evaluated by using acoustic emission(AE) technique. AE measurement system was set for detecting acoustic signal during accelerated corrosion test of the specimen. AE signal started to be detected after the time of pitting corrosion initiation was evaluated by anodic polarization curve. Pitting corrosion damage was confirmed by optical microscopic observation of the surface morphology. AE cumulative counts and amplitude according to corrosion time could be divided into three stages. These trends were discussed in relation with changing pitting corrosion mechanism. Feasibilities of AE technique for evaluation of corrosion damage and mechanism were suggested.

• Corrosion Science and Technology
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• v.13 no.6
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• pp.214-223
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• 2014

Interest in the durability assessment and structural performance has increased according to an increase of concrete structures in salt damage environment recent years. Reliable way ensuring the most accelerated corrosion test is a method of performing the rebar corrosion monitoring as exposed directly to the marine test site exposure. However, long-term exposure test has a disadvantage because of a long period of time. Therefore, many studies on reinforced concrete in salt damage environments have been developed as alternatives to replace this. However, accelerated corrosion test is appropriate to evaluate the critical chlorine concentration in the short term, but only accelerated test method, is not easy to get correct answer. Accuracy of correlation acceleration test depends on the period of the degree of exposure environments. Therefore, in this study, depending on the concrete mix material, by the test was performed on the basis of the composite degradation of the salt damage, and investigate the difference of corrosion initiation time of the rebar, and indoor corrosion time of the structure, of the marine environment of the actual environments were inuestigated. The correlation coefficient was derived in the experiment. Long-term exposure test was actually conducted in consideration of the exposure conditions submerged zone, splash zone and tidal zone. The accelerated corrosion tests were carried out by immersion conditions, and by the combined deterioration due to the carbonation and accelerated corrosion due to wet and dry condition.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.7 no.1
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• pp.9-16
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• 2011

Primary water stress corrosion cracking (PWSCC) has been found in the weld region of the nuclear power plant. Welding can produce tensile residual stress. Tensile residual stress contributes to the initiation and growth of PWSCC. It is important to estimate weld residual stress accurately to predict or prevent the initiation and growth of PWSCC. This paper shows the results of finite element analysis and measurement experiment for weld residual stress. For the study, four kinds of specimen were fabricated with the materials used in the nuclear power plant. Residual stresses were measured by four kinds of methods of hole drilling, x-ray diffraction, instrumented indentation and sectioning. Through the study, numerical analysis and measurement results were compared and the characteristics of each measurement technique were observed.

• Computers and Concrete
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• v.13 no.2
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• pp.187-207
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• 2014

This paper mainly discusses the influence of the aggregate properties including grading, shape, content and distribution on the chloride diffusion coefficient, as well as the initiation time of steel corrosion from a probabilistic point of view. Towards this goal, a simulation method of random aggregate structure (RAS) based on elliptical particles and a procedure of finite element analysis (FEA) at meso-scale are firstly developed to perform the analysis. Next, the chloride diffusion coefficient ratio between concrete and cement paste $D_{app}/D_{cp}$ is chosen as the index to represent the effect of aggregates on the chloride diffusion process. Identification of the random distribution of this index demonstrates that it can be viewed as actually having a normal distribution. After that, the effect of aggregates on $D_{app}/D_{cp}$ is comprehensively studied, showing that the appropriate properties of aggregates should be decided by both of the average and the deviation of $D_{app}/D_{cp}$. Finally, a case study is conducted to demonstrate the application of this mesoscopic method in predicting the initiation time of steel corrosion in reinforced concrete (RC) structures. The mesoscopic probabilistic method developed in this paper can not only provide more reliable evidences on the proper grading and shape of aggregates, but also play an important role in the probability-based design method.

• Structural Engineering and Mechanics
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• v.61 no.6
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• pp.693-700
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• 2017

Concrete cover cracking due to the corrosion of steel reinforcing bars is one of the main causes of deterioration in Reinforced Concrete (RC) structures. The oxidation level of the bars causes varying levels of expansion. The rebar expansions could lead to through-thickness cracking of the concrete cover, where depending on the cracking characteristics, the service life of the structures would be affected. In this paper, the effect of geometrical and material parameters, i.e., concrete cover thickness, reinforcing bar diameter, and concrete tensile strength, on the required pressure for concrete cover cracking due to corrosion has been investigated through detailed numerical simulations. ABAQUS finite element software is employed as a modeling platform where the concrete cracking is simulated by means of eXtended Finite Element Method (XFEM). The accuracy of the numerical simulations is verified by comparing the numerical results with experimental data obtained from the literature. Using a previously proposed empirical equation and the numerical model, the time from corrosion initiation to the cover cracking is predicted and then compared to the respective experimental data. Finally, a parametric study is undertaken to determine the optimum ratio of the rebar diameter to the reinforcing bars spacing in order to avoid concrete cover delamination.

• Korean Journal of Materials Research
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• v.9 no.2
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• pp.217-225
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• 1999

The effect on the pitting corrosion resistance of laser welding and surface treatment developed as a repair method of stream generator tubing material that was a major component of primary system at nuclear power plant was observed. Some heat-treated Alloy 600 tubing materials used at domestic nuclear power plants were laser-surface observed. Some heat-treated Alloy 600 tubing materials used at domestic nuclear power plants were laser-surface melted and the microstructural characteristics were examined. The pitting corrosion resistance was examined through Ep(pitting potential) and degree of pit generation by means of the electrochemical tests and the immersion tests respectively. The pit formation characteristics were investigated through microstructural changes and the pit initiation site and pit morphology. The test results showed that the pitting corrosion resistances was increased in the order of the followings; sensitized Alloy 600, solution annealed alloy600, and laser surface melted Alloy 600. Pits were initiated preferably at Ti-containing inclusions and their surroundings in all tested specimens and it is believed that higher pitting resistance of laser-surface treated Alloy 600 was caused by fine, homogeneous distribution of non-soluble inclusions, the disappearance of grain boundary, and the formation of dense, stable oxide film. The major element of corrosion products filled in the pit was Cr. On the other hand, Fe was enriched in the deposit formed on the pit.

• Corrosion Science and Technology
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• v.10 no.4
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• pp.118-124
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• 2011

Alloy 600 (Ni 75 wt%, Cr 15 wt%, Fe 10 wt%) as a heat exchanger tube of the steam generator (SG) in nuclear power plants (NPP) has been degraded by various corrosion mechanism during the long-term operation. Especially lead (Pb) is known to be one of the most deleterious species in the secondary system causing outer diameter stress corrosion cracking (ODSCC). Oxide formation and breakdown is requisite for SCC initiation and propagation. Therefore it is expected that a property change of the oxide formed on SG tubing materials by lead addition into a solution is closely related to PbSCC. In the present work, the SCC susceptibility was assessed by using a slow strain rate test (SSRT) in caustic solutions with and without lead for Alloy 600 and Alloy 690 (Ni 60 wt%, Cr 30 wt%, Fe 10 wt%) used as an alternative of Alloy 600 because of outstanding superiority to SCC. The results were discussed in view of the oxide property formed on Alloy 600 and Alloy 690. The oxides formed on Alloy 600 and Alloy 690 in aqueous solutions with and without lead were examined by using a transmission electron microscopy (TEM), equipped with an energy dispersive x-ray spectroscopy (EDXS).

• Journal of the Korea institute for structural maintenance and inspection
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• v.4 no.1
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• pp.121-129
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• 2000

In general. service life of the sea-shore concrete structures is largely influenced by the corrosion of reinforcing steel due to the chloride contamination, and the penetration of chloride ions into concrete is governed by concrete condition state as a micro-structure. In this study, characteristics of chloride diffusion in concrete are analyzed in accordance with the mixing properties and durability of concrete, by considering the facts that micro-structure of concrete varies with the mixing properties and can indirectly be analyzed by using the durability test. In order to predict the service life of existing concrete structures, chloride diffusion equation for the concrete structures under various service conditions and the major parameters used in that equation are formulated as the mathematical models. Based on the results of chloride diffusion analysis in accordance with the mixing properties and durability of concrete and mathematical models formulated in this study, a prediction system is developed to predict the corrosion initiation of reinforcing steel in the sea-shore concrete structures.

• KIEAE Journal
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• v.10 no.3
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• pp.103-110
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• 2010

Carbonation is one of the major deterioration factors for concrete. So. lots of researchers have proposed the equations for determining carbonated depth and the initial time of steel corrosion due to carbonation to predict the service life of concrete structures. However, there are large gaps among the equations for predicting carbonation because each researcher has different considering factors to predict carbonation depth. So, in this study, we calculated the deviations of the proposed equations for carbonation, and we calculated each researcher different corrosion initiation time. However, it has a lot of deviation. Therefore, we evaluated the probability of steel corrosion considering each deviation using MCS, an analysis method based on probability theory. In the results, we have proposed much advanced information for determining service life of reinforced concrete structures due to carbonation.