• Title/Summary/Keyword: corrosion initiation

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Correlation between chloride-induced corrosion initiation and time to cover cracking in RC Structures

  • Hosseini, Seyed Abbas;Shabakhty, Naser;Mahini, Seyed Saeed
    • Structural Engineering and Mechanics
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    • v.56 no.2
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    • pp.257-273
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    • 2015
  • Numerical value of correlation between effective parameters in the strength of a structure is as important as its stochastic properties in determining the safety of the structure. In this article investigation is made about the variation of coefficient of correlation between effective parameters in corrosion initiation time of reinforcement and the time of concrete cover cracking in reinforced concrete (RC) structures. Presence of many parameters and also error in measurement of these parameters results in uncertainty in determination of corrosion initiation and the time to crack initiation. In this paper, assuming diffusion process as chloride ingress mechanism in RC structures and considering random properties of effective parameters in this model, correlation between input parameters and predicted time to corrosion is calculated using the Monte Carlo (MC) random sampling. Results show the linear correlation between corrosion initiation time and effective input parameters increases with increasing uncertainty in the input parameters. Diffusion coefficient, concrete cover, surface chloride concentration and threshold chloride concentration have the highest correlation coefficient respectively. Also the uncertainty in the concrete cover has the greatest impact on the coefficient of correlation of corrosion initiation time and the time of crack initiation due to the corrosion phenomenon.

Research for the Evaluation of Corrosion Fatigue Crack Initiation Life (해수환경중 부식피로균열 발생수명 평가에 관한 연구)

  • Kim, Won-Beom;Paik, Jeom-Kee;Yajima, Hiroshi
    • Journal of the Society of Naval Architects of Korea
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    • v.44 no.4
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    • pp.417-424
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    • 2007
  • With regard to corrosion fatigue crack initiation life (Nc), it has been treated ambiguously for the member which doesn't have stress concentration area. In this research, in order to clarify the corrosion fatigue crack initiation life (Nc), corrosion fatigue tests were carried out. Reasonable and universal corrosion fatigue crack initiation life (Nc) was defined and corrosion fatigue crack initiation/propagation model was suggested also. As the fatigue crack which emanates from the pit is usually small, accordingly it is treated as a small crack. In addition, the observation of the corrosion fatigue fracture surfaces using SEM was conducted. And the fracture mechanics analysis using an intrinsic crack model was conducted for the treatment of the small crack. Finally, the followings were obtained. When there is no clear stress concentration point which seems to fall into a corrosion fatigue crack initiation life, the significance of the definition and suggestion of the moment of the reasonable and universal corrosion fatigue crack initiation life (Nc), at which the fatigue crack propagation rate becomes faster than the corrosion pit growth rate so that the fatigue crack initiates from the pit and propagates in earnest, has been clarified.

Corrosion initiation time models in RC coastal structures based on reliability approach

  • Djeddi, Lamine;Amirat, Abdelaziz
    • Advances in concrete construction
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    • v.9 no.2
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    • pp.149-159
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    • 2020
  • The present work proposes new engineering models for determining corrosion initiation time in concrete reinforcing steels in marine environment. The models are based on Fick's second law that is commonly used for chloride diffusion. The latter is based on deterministic analyses involving the most influencing parameters such as distance of the concrete structure from the seaside, depth of steel concrete cover, ambient temperature, relative humidity and the water-cement ratio. However, a realistic corrosion initiation time cannot be estimated because of the uncertainties associated to the different parameters of the models. Therefore a reliability approach using FORM/SORM method has been applied to develop the proposed engineering models integrating a limit state function and a reliability index β. As a result, the corrosion initiation time is expressed by new exponential engineering models where the uncertainties are associated to the model parameters. The main emerging result is a realistic decision tool for corrosion planning inspection.

Evaluation of carbonation service life of slag blended concrete considering climate changes

  • Wang, Xiao-Yong;Luan, Yao
    • Computers and Concrete
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    • v.21 no.4
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    • pp.419-429
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    • 2018
  • Climate changes, such as increasing of $CO_2$ concentration and global warming, will impact on the carbonation service life of concrete structures. Moreover, slag blended concrete has a lower carbonation resistance than control concrete. This study presents a probabilistic numerical procedure for evaluating the impact of climate change on carbonation service life of slag blended concrete. This numerical procedure considers both corrosion initiation period and corrosion propagation period. First, in corrosion initiation period, by using an integrated hydration-carbonation model, the amount of carbonatable substances, porosity, and carbonation depth are calculated. The probability of corrosion initiation is determined through Monte Carlo method. Second, in corrosion propagation period, a probabilistic model is proposed to calculate the critical corrosion degree at surface cracking, the probability of surface cracking, and service life. Third, based on the service life in corrosion initiation period and corrosion propagation period, the whole service life is calculated. The analysis shows that for concrete structures with 50 years service life, after considering climate changes, the service life reduces about 7%.

Probabilistic time-dependent sensitivity analysis of HPC bridge deck exposed to chlorides

  • Ghosh, Pratanu;Konecny, Petr;Lehner, Petr;Tikalsky, Paul J.
    • Computers and Concrete
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    • v.19 no.3
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    • pp.305-313
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    • 2017
  • A robust finite element based reinforced concrete bridge deck corrosion initiation model is applied for time-dependent probabilistic sensitivity analysis. The model is focused on uncertainties in the governing parameters that include variation of high performance concrete (HPC) diffusion coefficients, concrete cover depth, surface chloride concentration, holidays in reinforcements, coatings and critical chloride threshold level in several steel reinforcements. The corrosion initiation risk is expressed in the form of probability over intended life span of the bridge deck. Conducted study shows the time-dependent sensitivity analysis to evaluate the significance of governing parameters on chloride ingress rate, various steel reinforcement protection and the corrosion initiation likelihood. Results from this probabilistic analysis provide better insight into the effect of input parameters variation on the estimate of the corrosion initiation risk for the design of concrete structures in harsh chloride environments.

Effects of Cement Alkalinity on the Time-to-Corrosion of Reinforcing Steel in Concrete under Chloride Exposure

  • Nam, Jingak;Hartt, William H.;Kim, Kijoon
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.245-250
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    • 2004
  • A series of classical G109 type concrete specimens was exposed to cyclic wet and dry ponding with 15 w/o NaCl solution for approximately five years. Mix design variables included 1) three cement alkalinities (EqA of 0.97, 0.52, and 0.36) and 2) three water-cement ratios (0.50, 0.41, and 0.37). To determine the corrosion initiation time, corrosion potential and macro-cell current between top and bottom bars were monitored. Subsequent to corrosion initiation, specimens were autopsied and visually inspected. Concrete powder samples were collected from top rebar trace and chloride concentration was measured. Also, time-to-corrosion, $T_i$, for specimens of the individual mix designs was represented using Weibull analysis. Time-to-corrosion was a distributed parameter; and because of this, corrosion initiation of four identical specimens for each mix varied, often over a relatively wide range. Specimens fabricated using the lowest water cement ratio and the highest alkalinity cement exhibited the longest time-to-corrosion initiation and the highest chloride threshold levels. Time-to-corrosion did not increase monotonically with cement alkalinity, however, presumably as a consequence of relatively high $Cl^-$ binding in the lower pore water pH range. The chloride threshold level, $Cl_{th}$, increased with increasing $T_i$ and, consequently, was greatest for the highest cement alkalinity specimens.

Study of Hot Salt Stress Corrosion Crack Initiation of Alloy IMI 834 by using DC Potential Drop Method

  • Pustode, Mangesh D.;Dewangan, Bhupendra;Raja, V.S.;Paulose, Neeta;Babu, Narendra
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.203-208
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    • 2016
  • DC potential drop technique was employed during the slow strain rate tests to study the hot salt stress corrosion crack (HSSCC) initiation at 300 and $400^{\circ}C$. Threshold stresses for HSSCC initiation were found to about 88 % of the yield strength at both temperatures, but the time from crack initiation to final failure (${\Delta}t_{scc}$) decreased significantly with temperature, which reflects larger tendency for brittle fracture and secondary cracking. The brittle fracture features consisted of transgranular cracking through the primary ${\alpha}$ grain and discontinuous faceted cracking through the transformed ${\beta}$ grains.

Characteristics of Corrosion Fatigue of High Strength Steel for Marine Weld Structure

  • Choi, Seong-Dae;Kubo, Takeo;Misawa, Hiroshi;Lee, Jong-Hyung;Song, Dug-Jung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.2 no.4
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    • pp.53-60
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    • 2003
  • Large sized marine structures are used under corrosion environment of seawater and applied by severe service loading such as an ocean current, a billow and a tempest. Marine structures are usually constructed by lots of thick wall steel pipes joining welded joints. The thickness of such as steel pipes is usually more than 40mm. The such as steels are called "Thermo-Mechanical Control Process steel (TMCP steel)" strengthened by a heat treatment in process of steel manufactures. The failure, especially crack initiation, of marine structures was starting at weld joints under service condition. Then they should be designed by basis of the fatigue strength under seawater corrosion environment of weld joints. To clarity the fatigue crack initiation behavior is important more than to clarify the crack propagation behavior on the strength design of marine structures, because it is very difficult to find out the crack initiation and propagation phenomena and then even if it will be able to find out, it is considered that the refit of the damaged parts of welded joints have a technical difficulty under the sea. Therefore, it is most important to clarify the corrosion fatigue crack initiation behavior under the seawater condition. But, there is one big difficulty to make a test for thick plate specimen, for example thicker than 40mm. Because, it is need large capacity loading apparatus to test such as thick plate specimen. In this research, the new configuration specimen for fatigue crack initiation tests was proposed. Using this new specimen, it is easy to carry out the fatigue clack initiation tests with relatively low cyclic loading and to observe a fatigue crack initiation behavior.

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Effect of Carbonation Threshold Depth on the Initiation Time of Corrosion at the Concrete Durability Design (콘크리트의 내구성 설계시 탄산화 임계깊이가 철근부식 개시시기에 미치는 영향에 관한 연구)

  • Yang, Jae-Won;Lee, Sang-Hyun;Song, Hun;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2010.05a
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    • pp.229-230
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    • 2010
  • The Carbonation, one of the main deterioration factors of concrete, reduces capacity of members with providing rebar corrosion environment. Consequently it suggested standards of all countries of world, carbonation depth prediction equation of respective researchers and time to rebar corrosion initiation. As a result of carbonation depth prediction equation calculation, difference of time to rebar corrosion initiation is 149 years and difference of carbonation depth prediction equation is 162 years when water cement ratio is 50%. So a study on rebar corrosion with carbonation depth will need existing reliable data and verifications by experiment.

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An Experimental Study on Measurement of Corrosion Initiation in Reinforced Concrete Exposed to Chloride Using EIS Method (EIS를 이용한 염해에 노출된 철근콘크리트의 부식개시 측정에 관한 실험적 연구)

  • Park, Dong-Jin;Park, Jang-Hyun;Lee, Kwang-Soo;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.61-62
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    • 2017
  • In this study, the initiation of steel corrosion was monitored due to chloride attack using embedded sensor. In general, Steel bars embedded in concrete are protected from corrosion by being forming a passive film on the surface. However, the passive film is destroyed by chemical erosion such as concrete carbonation and chloride penetration, and the rebar is exposed to the deteriorating factor and corrosion proceeds. In order to realize the initiation of steel corrosion, OCP and change of Impedance parameter were observed by using Half-cell and EIS method depending on cover depth. As result, 10mm cover showed the impedence increased in 6weeks.

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