• Title/Summary/Keyword: corrosion effects

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Effects of GPS heat-treatment on microstructure of as-cast Co-Cr alloy (Co-Cr 주조합금의 미세구조에 미치는 GPS 열처리 효과)

  • Ryu, Jeong Ho;Lee, Ho Jun;Cho, Hyun Su;Paeng, Jong Min;Park, Jong Bum;Lee, Jung-Il
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.5
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    • pp.263-267
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    • 2017
  • The Co-Cr as-cast alloys are widely used in the manufacturing of orthopedic implants made with investment casting techniques because of its high strength, good corrosion resistance and excellent biocompatibility properties. Carbide precipitation at grain boundaries and interdendritic regions is the major strenthening mechanism in the as-cast condition. In this study, effects of GPS (Gas Pressured Sintering) heat-treatment on the microstructure and crystallinity of the as-cast Co-Cr alloy prepared by investment casting were investigated. It was confirmed that the content of metal carbide ($Cr_{23}C_6$) was increased in the grain boundary by using optical microscopy (OM), field-emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS).

Effects of Thermomechanical Processing on Changes of Microstructure and Mechanical Properties in Ti-10Ta-10Nb Alloy (가공 열처리에 따른 Ti-10Ta-10Nb합금의 미세조직 및 기계적 특성 변화)

  • Lee, Doh-Jae;Hwang, Ju-Young;Lee, Kyung-Ku;Yoon, Kye-Lim;Jun, Choong-Geug
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.2
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    • pp.91-98
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    • 2005
  • Both commercially pure titanium and Ti-6Al-4V alloy have been widely used as biomaterials because of their excellent biocompatibility, corrosion resistance and mechanical properties. However, in recent years, vanadium has been found to cause cytotoxic effects and adverse tissue reactions, while aluminium has been associated with potential neurological disorders. A newly designed ${\alpha}+{\beta}$ type Ti alloy, Ti-10Ta-10Nb alloy showed superior properties to CP Ti and Ti-6Al-4V alloy in the point of biomaterial, and elucidated the future uses as a biomaterial. Microstructural changes of Ti-10Ta-10Nb alloy after hot-rolling, warm-rolling, solution and aging treatment were investigated. According to TEM results, the microstructures after solution treatment were composed of mostly ${\alpha}$ phase with a trace of ${\beta}$ phase due to adding ${\beta}$-phase stabilizer tantalum and niobium. The microstructures after warm-rolling is coarse and elongated ${\alpha}$ phase and hot rolling resulted in very fine ${\alpha}$ widmanst$\ddot{a}$tten. The highest value of hardness was obtained by aging treatment at $400^{\circ}C$ for 20hr in which microstructure consisted of very fine ${\alpha}$ phase in ${\beta}$ matrix.

Effects of flushing techniques on water quality at extremity with low chlorine residuals in drinking water distribution systems (수질 취약지역 및 관말에서 플러싱 적용 먹는물 수질 개선 효과)

  • Ko, Kyung-Hoon;Kweon, Ji-Hyang;Kim, In-Ja;Lim, Woo-Hyuk
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.313-324
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    • 2011
  • Several complaints from consumers on red or turbid waters were often filed at the same places although various efforts were made to improve water quality in the drinking water plant. The red water problems were occurred due to corrosion of main water pipe, especially at extremity. The low concentrations of chlorine indicating poor water quality were detected at the problematic location. To solve the poor water quality at the extremity, flushing techniques, i.e., conventional flushing, unidirectional flushing, and continuous flushing, were recently practiced. In this study, effects of conventional flushing on water qualities were examined by comparing turbidity and residual chlorine before and after flushing. In addition, more detailed analyses on water qualities at the tap water were conducted to learn a reduction pattern during flushing. Five items from geographic information system of water distribution were used to obtain a relationship with water quality, washing duration or amounts of washing water. The flushing was effective to meet the National Drinking Water Quality Standard with simple and relatively short time operation. The key operational parameter in flushing was amounts of washing water which should be estimated based on water quality of the consumer's tap water. The positive relationship between the residual chlorine and pipe length implied that detention time in the pipeline was the main cause of the complaints. More experiments on effectiveness of flushing are needed to determine reasonable strategies of flushing.

Wear Mechanisum of Carbon Bearing BOF Refreactories (전로용 MgO-C질 내화벽돌의 손상요인)

  • 김의훈;오영우;이철수;김종성;김종희
    • Journal of the Korean Ceramic Society
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    • v.23 no.1
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    • pp.51-59
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    • 1986
  • It was the first time the MgO-C brick was developed for the lining materials in the hot spots in electric are furnace in 1972. MgO-C brick is high registant to thermal and structural spalling. Futhermore for the reason that carbon is hard to react with slag and MgO is high fireproof MgO-C brick shows a high corrosion registance to slag attack compared with conventional basic refractories. Owing to their excellent properties the use of MgO-C refractories are being developed widely in the field of shaped refractories and even in that of monolithic refractories. In this paper the oxidation of carbon the infiltration of slag into the brick texture and effects of additions were investigated. The results obtained were as follows : 1) The use of fused MgO-clinker and high purity carbon as raw materials increased the corosion registance and hot modulus of rupture of MgO-C brick. 2) As the oxidation reaction of the carbon proceeded the slag infiltrated into the brick texture. And then the slag components reacted with the MgO grains and formed low melting point compounds particulary CaO.MgO.$SiO_2$ and 3CaO.MgO.$2SiO_2$ that resulted in the wear of the brick. 3) It is recongnized the Al, Si, $B_3C$ effects on the oxidation registant properties of MgO-C brick by contribu-ting to the decrease of permeability according to the formation of $Al_4C_3$, SiC, $B_2O_3$ and the decrease of open pores relating to the formation of MgO.Al2O3, $SiO_2$, 3MgO.$B_2O_3$ at the decarbonized layer.

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THE EFFECTS OF HEAT TREATMENT ON MECHANICAL PROPERTIES AND METAL RELEASE FROM HEAT-TREATED ORTHODONTIC ARCHWIRES (열처리한 교정용 호선의 기계적 성질과 금속유리에 대한 연구)

  • Choi, Chul Min;Rhee, Byung Tae
    • The korean journal of orthodontics
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    • v.20 no.2
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    • pp.381-390
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    • 1990
  • The purpose of this study was to evaluate the effects of heat treatment on mechanical properties in $0.016^{{\prime}{\prime}}{\times}0.022^{{\prime}{\prime}}$ blue Elgiloy wires and to measure the amounts of nickel and chromium released from the wires in artificial saliva. Ultimate tensile strength, yield strength and elongation were measured with universal testing machine (Instron). and the amounts of nickel and chromium released from the sample were measured with atomic absorption spectrophotometer after one week immersion in the artificial saliva. Ultimate tensile strength and yield strength were progressively increased below $1000^{\circ}F$, but elongation was decreased. And the results were reversed above $1100^{\circ}F$. After heat treatment of the sample for 9 minutes at $1000^{\circ}F$, the maximum tensile strength and yield strength were $213.6kg/mm^2$, $140.1kg/mm^2$, respectively. Both tensile strength and yield strength were decreased progressively above $1100^{\circ}F$. Elongation was appeared the minimum value (8.6%) after heat treatment for 9 minutes and 12 minutes at $1000^{\circ}F$. There was a pronounced increase in nickel and chromium liberation with increasing time and temperature. The maximum amounts of nickel and chromium released form the sample were $4.947{\mu}m/cm^2$, $3.088{\mu}g/cm^2$, respectively after heat treatment for 12 minutes at $1300^{\circ}F$. Heat treatment is applied to orthodontic wires, especially cobalt-chromium alloys, for the purpose of stress-relievning and hardening. When the heat-treatment of orthodontic wires, the heating procedure should be well controlled in order to have no effect on corrosion resistance and mechanical properties.

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An Experiemtnal Study on the Air Permeability Effect on Concrete Carbonation (콘크리트의 중성화에 영향을 미치는 투기성에 관한 실험적 연구)

  • 권영진;김무한;강석표;유재강
    • Journal of the Korea Concrete Institute
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    • v.13 no.3
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    • pp.277-284
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    • 2001
  • Hardened concrete contains pores of varying types and sizes, and therefore the transport of air through concrete can be considered. The rate of permeability will not only depends on the continuity of pores, but also on the moisture contents in concrete and finishing material on concrete. Also it knows that the durability of reinforced concrete structure is concerned with air permeability which effects on the carbonation occurred by invasion of CO2 gas and the corrosion of steel bar occurred by O$_2$. In this paper, the effects of curing conditions and finishing materials on carbonation and air permeability are investigated according to the accelerated carbonation test. As results, carbonation velocity and air permeability are effected by curing conditions and finishing materials, and air permeability coefficient is effected by moisture content. Also the relationship between carbonation velocity coefficients and air permeability coefficients has been quite well established.

The Effect of Citric Acid on Copper Chemical Mechanical Polishing (구연산이 Copper Chemical Mechanical Polishing에 미치는 영향)

  • Jung, Won-Duck;Park, Boum-Young;Lee, Hyun-Seop;Lee, Sang-Jic;Chang, One-Moon;Park, Sung-Min;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.565-566
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    • 2006
  • Slurry used in metal chemical mechanical polishing normally consists of an oxidizer, a complexing agent, a corrosion inhibitor and an abrasive. This paper investigates effects of citric acid as a complexing agent for Cu CMP with $H_2O_2$ as an oxidizer. In order to study chemical effects of a citric acid, x-ray photoelectron spectroscopy were performed on Cu sample after Cu etching test. XPS results reveal that CuO, $Cu(OH)_2$ layer decrease but Cu/$Cu_2O$ layer increase on Cu sample surface. To investigate nanomechanical properties of Cu sample surface, nanoindentation was performed on Cu sample. Results of nanoindentation indicate wear resistance of Cu Surface decrease. According to decrease of wear resistance on Cu surface, removal rate increases from $285\;{\AA}/min$ to $8645\;{\AA}/min$ in Cu CMP.

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Effect of Ear and Near-side Single Circular Pit Depth and Bulk Stress on Magnetic Flux Leakage at ferromagnetic Pipeline (강자성 배관 외.내부 면의 단일 원형 홈의 깊이와 부피응력이 누설자속에 미치는 영향)

  • Ryu, Kwon-Sang;Park, Young-Tae;Atherton, D.L.;Clapham, L.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.3
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    • pp.263-269
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    • 2003
  • Magnetic flux leakage (MFL) signals were used for corrosion inspection of buried oil and gas pipeline. 3D finite element analysis was used to examine the effects of far and near-side pit depth and tensile stress on MFL signals. Anisotropci materials were used, and the effects of simulated tensile stress on MFL were investigated. The axial and radial MFL signals depended on far and near-side single pit depth and on the bulk stress, but the circumferential MFL signal did not depend on them. The axial and radial MFL signals increased with increasing pit depth and the bulk stress, but the circumferential MFL signal was scarcely changed.

Experimental and numerical investigation of strengthened deficient steel SHS columns under axial compressive loads

  • Shahraki, Mehdi;Sohrabi, Mohammad Reza;Azizyan, Gholam Reza;Narmashiri, Kambiz
    • Structural Engineering and Mechanics
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    • v.67 no.2
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    • pp.207-217
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    • 2018
  • In past years, numerous problems have vexed engineers with regard to buckling, corrosion, bending, and overloading in damaged steel structures. This article sets out to investigate the possible effects of carbon fiber reinforced polymer (CFRP) and steel plates for retrofitting deficient steel square hollow section (SHS) columns. The effects of axial loading, stiffness, axial displacement, the position and shape of deficient region on the length of steel SHS columns, and slenderness ratio are examined through a detailed parametric study. A total of 14 specimens was tested for failure under axial compression in a laboratory and simulated using finite element (FE) analysis based on a numerical approach. The results indicate that the application of CFRP sheets and steel plates also caused a reduction in stress in the damaged region and prevented or retarded local deformation around the deficiency. The findings showed that a deficiency leads to reduced load-carrying capacity of steel SHS columns and the retrofitting method is responsible for the increase in the load-bearing capacity of the steel columns. Finally, this research showed that the CFRP performed better than steel plates in compensating the axial force caused by the cross-section reduction due to the problems associated with the use of steel plates, such as in welding, increased weight, thermal stress around the welding location, and the possibility of creating another deficiency by welding.

The Effects of Scale Growth Inhibition on Water Pipe using Frequency Driver (Frequency Driver를 이용한 냉온수관의 스케일 방지억제효과)

  • Jang, Mi-Jeong;Sung, Il-Wha
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.4
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    • pp.258-266
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    • 2011
  • Scale induced by hardness materials in water must be controled because of it can be result in remarkable damages of pipeline as well as water quality deterioration. Especially hot water system is one of scale management required facility as scale formation can be accelerated by temperature. The scale control performance of frequency driver (FD) was tested instead of existing methods such as chemical, physical and electromagnetic methods which needs chemicals and electric power. Three kinds of pipe coupons were submerged in test water with 500 mg/L of hardness for 33 days and XRD and SEM were analysed for comparing scale formation characteristics of these coupons. Calcite ($CaCO_3$) which came from hardness of water was formed on only cast iron pipe coupon and this coupon showed higher corrosion rate than copper and stainless steel pipe coupon. Hot water circulating system connected cast iron pipe with and without FD was operated with 300 mg/L of hardness water at $50^{\circ}C$ for monitoring of scale formation and water quality with and without FD. XRD showed that FD leaded to magnetite ($Fe_3O_4$) scale which is good scale for preventing corrosion than calcite and SEM image also indicated the scale control effect of FD. Scales of 16% on pipe joint, 14% on pipe length, and 42% on heat exchanger decreased with FD comparing scales of those parts without FD. From the results of water quality, FD reduced crystallization of hardness material without chemical reaction in water and it can indicate that FD is safe and proenvironmental technology for scale reduction.