• Title/Summary/Keyword: corrosion control

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Water Layer in Course of Corrosion of Copper in Humid Air Containing $SO_2$

  • Sasaki, Takeshi;Itoh, Jun;Ohtsuka, Toshiaki
    • Corrosion Science and Technology
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    • v.2 no.2
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    • pp.88-92
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    • 2003
  • The technique for in situ simultaneous measurements of IR-RAS and QCM, which has been developed for investigation of corrosion in gaseous environments, was employed to study the effects of an extremely thin water layer on the corrosion rate. An evaporated copper film on a QCM element was exposed to air containing water vapor and $SO_2$, and time-resolved IR-RAS spectra were measured and mass gains were simultaneously followed with QCM. The tested ranges of relative humidity (RH) and concentration of $SO_2$ were 60% - 90% and 1 - 20 ppm, respectively. On the basis of 2D-IR analysis, the corrosion products were determined to be Chevreul's salt ($CuSO_3Cu_2SO_3{\cdot}2H_2O$) and $CuSO_4{\cdot}5H_2O$. By constructing curves of the relations between band intensities of IR spectra and mass gains of QCM for the corrosion products, the time variations in each product were determined from spectral experiments on copper plates. The thicknesses of physically adsorbed water layers in course of the corrosion process were also determined from water band intensities. The results showed that the thickness of the physically adsorbed water layer increased with increase in RH, and it also increased with increase in accumulation of corrosion products. The latter is probably due to the capillary effect of the corrosion products.

Corrosion Cost Survey in Japan - Focusing on Transportation Industry -

  • Kodama, Toshiaki
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.252-258
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    • 2008
  • The Committee on the Cost of Corrosion in Japan was organized in 1999 jointly by the Japan Society of Corrosion Engineering (JSCE) and the Japan Association of Corrosion Control (JACC). Corrosion cost as of FY1997 was estimated based on the Uhlig and Hoar methods similarly to that conducted in 1974. The estimated corrosion cost of 1997 was compared with that reported for 1974 with speculation on the change in industrial environment. The overall costs estimated by the Uhlig and Hoar methods for 1997 were 3,938 billion yen and 5,258 billion yen, respectively, which were equivalent to 0.77% and 1.02% of the GNP of Japan. The process of organization formation, procedures for analyses and the results of cost evaluation were described by adjusting a focus on transportation industry.

( Control of Primary Solidification Mode for Improving Solidification Cracking Resistance , Corrosion Resistance and Cryogenic Toughness of Austenitic Stainless Steel (오스테나이트계 스테인리스강의 응고균열저항 내식성 및 극저온 초성 향상을 위한 초정응고 형식의 제어)

  • 정호신
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.2
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    • pp.208-215
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    • 1992
  • Concept of primary solidification mode control was adopted to obtain optimal solidification crack resistance, hot ductility, corrosion resistance and toughness for austenitic stainless steel. By controlling primary solidification phase as primary $\delta$ and containing no ferrite at room temperature, optimal solidification crack resistance, hot ductility, corrosion resistance and cryogenic toughness could be obtained. The optimum chemical composition of austenitic stainless steel ranges 1.46~1.55(Creq/Nieq ratio) calculated by Schaeffler's equation.

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Survey of Corrosion Cost in China and Preventive Strategies

  • Ke, Wei;Li, Zhiqiang
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.259-264
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    • 2008
  • A national consultative project entitled "corrosion cost survey in China and preventive strategies" was funded by the Chinese Academy of Engineering in 1998. Soon afterwards, an expert group was organized jointly by the Institute of Metal Research, CAS and Chinese Society of Corrosion and Protection. The report on corrosion cost survey in China was published in 2003. According to this report the overall annual corrosion cost in China estimated by the Uhlig Method and Hoar Method at 1997-2001 was found to be 200.7 billion Yuan RMB and 228.8 billion Yuan RMB respectively, which is equivalent to 2% of the gross national product of China. However the total cost of corrosion including the direct and indirect cost was estimated to be more than 500 billion Yuan RMB per year in China. Among them, corrosion cost of infrastructure ranked in first comparing with other sectors. Although corrosion costs in some sectors, such as electric power, petrochemical, oil pipeline and railway in China has reduced in the past years, significant losses are still being encountered in most sectors of industries and cost-effective methods have not always been implemented. Both successful and unsuccessful cases in corrosion control and corrosion management were collected. As the investment in capital construction continues increasing rapidly in China, the maintenance and life extension of the infrastructures will become a big issue. The preventive strategies have been suggested

Control of Galvanic Corrosion Between A516Gr.55 Steel and AA7075T6 Depending on NaCl Concentration and Solution Temperature

  • Hur, S.Y.;Jeon, J.M.;Kim, K.T.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.19 no.6
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    • pp.281-287
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    • 2020
  • Chloride ion is one of the most important corrosive agents in atmospheric corrosion, especially in marine environments. It has high adsorption rate and increases the conductivity of electrolytes. Since chloride ions affect the protective properties and the surface composition of the corrosion product, they increase the corrosion rate. A low level of chloride ions leads to uniform corrosion, whereas a high level of chloride ions may induce localized corrosion. However, higher solution temperatures tend to increase the corrosion rate by enhancing the migration of oxygen in the solution. This work focused on the effect of NaCl concentration and temperature on galvanic corrosion between A516Gr.55 carbon steel and AA7075T6 aluminum alloys. When AA7075T6 aluminum alloy was galvanically coupled to A516Gr.55 carbon steel, AA7075T6 was severely corroded regardless of NaCl concentration and solution temperature, unlike the corrosion properties of single specimen. The combined effect of surface treatment involving carbon steel and aluminum alloy on corrosion behavior was also discussed.

Corrosion control technology in water pipes by adjusting the corrosivity of drinking water : effect and impact of the lime dispersion system (수돗물 부식성 제어를 통한 수도관 부식방지기술: 석회수 분산화장치를 이용한 미네랄 공급 효과와 영향 분석)

  • Han, Keum-Seok;Park, Young-Bok;Kim, Seong-Jae;Kim, Hyen-Don;Choi, Young-June;Park, Ju-Hyun;Woo, Dal-sik;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.3
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    • pp.235-242
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    • 2018
  • Corrosion inhibitors including calcium hydroxide have been used to prevent corrosion in the pipes for tap water supply. The corrosion index (i.e., Langelier Index) differs by area and water quality. The corrosion indices of the areas studied differed by more than 2.0. The 'homogenized' calcium hydroxide was added to the treated water at the K water treatment plant, in order to increase the value of the corrosion index and the concentration of calcium. As the result, the concentration of calcium was increased while the turbidity and pH changed little. The corrosion rate of the tap water with the 'homogenized' calcium hydroxide could be slowed down pretty much. The results suggested that the technology of 'homogenization' of calcium hydroxide can applied to tap water and desalinated water to prevent corrosion in water pipes even in corrosive pipes.

Effect of Residual Chlorine Concentration on Water Pipe Corrosion and Corrosion Control Plan (수도관 부식에 대한 잔류염소 농도 영향 및 부식제어 방안)

  • Han, Keum-Seok;Park, Ju-Hyun;Park, Young-Bok;Kim, Seong-Jae;Kim, Hyen-Don;Choi, Young-June;Choi, In-cheol;Hong, Seong-Ho
    • Corrosion Science and Technology
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    • v.17 no.1
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    • pp.12-19
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    • 2018
  • Langelier Index (LI) is used as a tap water corrosiveness index. Residual chlorine in tap water induces corrosion inside water pipes. This study takes a deeper look into the effect of residual chlorine in water pipes. Comparison between tap waters of Y and K water treatment plant (WTP) shows that the LI index of K WTP is lower than that of Y. However, the corrosion rate of Y WTP is higher than that of K WTP. This means that the higher the concentration of residual chlorine in tap water, the higher the corrosion rate of pipe materials. When calcium hydroxide was added to tap water, the corrosiveness index was improved and thus the corrosion rate reduced. It is possible to increase the disinfection efficiency by increasing the duration of residual chlorine and suppressing the rust generation of water pipes and to supply minerals. A guideline for corrosion control with residual chlorine should be set up. The effects of residual chlorine should be included in the corrosiveness index of tap water.

Cathodic Protection of Onshore Buried Pipelines Considering Economic Feasibility and Maintenance

  • Choi, Byoung-Yeol;Lee, Sang-Gil;Kim, Jin-Kwang;Oh, Jin-Soo
    • Journal of Advanced Research in Ocean Engineering
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    • v.2 no.4
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    • pp.158-168
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    • 2016
  • During the installation of crude oil or gas pipelines, which pass through onshore buried pipelines or onshore pipeline from subsea pipeline to onshore plant, countermeasures need to be implemented so as to ensure a sufficient design life by protecting the steel pipes against corrosion. This can be achieved through impressed current cathodic protection method for onshore pipelines and through galvanic sacrificial anode corrosion protection method for offshore pipelines. In particular, in the case of impressed current cathodic protection, isolation joint flanges should be used. However, this makes maintenance control difficult with its installation having a negative impact on price. Therefore, in this study, the most suitable methodology for onshore pipeline protection between galvanic sacrificial anode corrosion protection and impressed current cathodic protection method will be introduced. In oil and gas transportation facilities, the media can be carried to the end users via onshore buried and/or offshore pipeline. It is imperative for the field operators, pipeline engineers, and designers to be corrosion conscious as the pipelines would undergo material degradations due to corrosion. The mitigation can be achieved with the introduction of an impressed current cathodic protection method for onshore buried pipelines and a galvanic sacrificial anode corrosion protection method for offshore pipelines. In the case of impressed current cathodic protection, isolation joint flanges should be used to discontinuity. However, this makes maintenance control to be difficult when its installation has a negative impact on the price. In this study, the most suitable corrosion protection technique between galvanic sacrificial anode corrosion protection and impressed current cathodic protection is introduced for (economic life of) onshore buried pipeline.

Effect of corrosion pattern on the ductility of tensile reinforcement extracted from a 26-year-old corroded beam

  • Zhu, Wenjun;Francois, Raoul
    • Advances in concrete construction
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    • v.1 no.2
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    • pp.121-136
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    • 2013
  • Tension tests were carried out to investigate the effect of the corrosion pattern on the ductility of tension bars extracted from a 26-year-old corroded reinforced concrete beam. The tensile behavior of corroded bars with different corrosion patterns was examined carefully, as were two non-corroded bars extracted from a 26-year-old control beam. The results show that corrosion leads to an increase in the ratio of the ultimate strength over the yield strength, but reduces the ultimate strain at maximum force of the reinforcement. Both the corrosion pattern and the corrosion intensity play an important role in the ductile properties. The asymmetrical distribution of the corrosion around the surface is a decisive factor, which can influence the ultimate strain at maximum force more seriously.

Study on the Corrosion Charactristics and its Corrosion Protection of Steel Fishing Banks (강제어촌의 부식특성과 그 방식에 관한 연구)

  • Lim, Uh-Joh;Lee, Jong-Rark
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.2
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    • pp.216-227
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    • 1992
  • The corrosion rate, behavior of corrosion fatigue and characteristic of cathodic protection for SB41 were investigated by corrosion and corrosion control tests in seawater at laboratory and coast. The main result obtained are as the following; 1) The corrosion rate of base metal (BM) is about 28-37 mg/dm super(2) day in seawater of coast. 2) The correlation between the stress intensity factor range $\Delta$K and crack propagation rate da/dN for weldment follows paris' rule in seawater : da/dN=C($\Delta$K) super(m) where m is the slope of the correlation, and is 2.02 for BM and 1.75 for heat affected zone (HAZ) respectively. 3) The corrosion sensitivity of HAZ is more sensitive than that of BM under the low region of $\Delta$K. 4) With increase of bared surace area of cathode, cathodic protection potential is increased sharply.

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