• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.761-766
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• 2002

This paper was peformed to verify the effect that granulated blast furnace slag gets in reinforcement corrosion resistance about chloride ion that invade from outside. An experiment accelerated for the reinforcement corrosion through repeat of brine digestion and dry. Reinforcement corrosion investigated half cell potential method of measurement by ASTM C876 and corrosion area ratio. If granulated blast furnace slag metathesis ratio is high generally that looked the corrosion of reinforcement decreasing as a result that evaluate reinforcement corrosion by ASTM C876 canon in this research. It showed high resistance about reinforcement corrosion that use normal portland cement and increase the metathesis rate of granulated blast furnace slag, as a result that evaluate metathesis rate effect of granulated blast furnace slag according to cement kind. when the test piece split destroying, area rate of reinforcement corrosion showed about result of half cell potential measurement.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.04a
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• pp.148-151
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• 1994

Up to now, sea sand without complete removal of salt is being used in the construction works because there is little satisfactory counterplan for the substitute aggregate. In the case that such sea sand is used in the reinforced concrete, the residual salt gives rise to deterioration phenmenon and iron corrosion, reducing durability of the ferro-concrete structures. The paper, an experimental study on the effect of corrosion protection by tighting concrete used SF and FA, is to investigate general steel bar's corrosion and to develop concrete using sea sand economically after it is analyzed and examinated ratio of the corrosion area affected by the autoclave cycle. As a test results, as for corrosion area ratio, it is very effective to use admixrutes such as SF and FA which decrease corrosion area remarkably with increasing the amounts of admixtures. Accordingly the use of admixtures is advantageous for tightening concrete and has an effect of salt damage prevention and rust protection in concrete used sea sand.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.325-333
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• 1998

Under the seawater environment, the reinforced concrete structure is deteriorated due to physical and chemical attacks. The main deterioration mechanism is the chloride corrosion of reinforcing steel. The corrosion inhibitors have been used to protect the rebars from corrosion which are susceptible to chlorides in concrete. However, there is not clear conclusion about corrosion inhibitors yet. In this study, it is made the accelerated experiment with 3 kinds of corrosion inhibitors for various chloride ingresses. It is estimated corrosion inhibitors that inhibitors by Half-Cell Potential, corrosion area ratio and weight loss ratio. It is concluded that inhibitors are not effective to corrosion inhibition for excessive chloride ingress. However, the effect of inhibition is directly proportional ot contents of corrosion inhibitors in some chloride ingress.

• Corrosion Science and Technology
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• v.6 no.3
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• pp.112-119
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• 2007

This paper presents the importance of corrosion control and protection technology with a real case study of heater tube rupture damaged by High temperature H2S-H2 corrosion in the refinery. The heater was operated at the Hydrocracking unit and the operation temperature and pressure was $340^{\circ}C$ and $18kg/cm^{3}$ respectively. Top side of the convection tube was thinned by high temperature hydrogen sulfide and hydrogen gas as a uniform corrosion and finally ruptured under operation pressure. Damaged area (Convection tube zone) was blocked by protection wall, so it was impossible to inspect with conventional nondestructive examination. Instead the elbow area which is out of the protection wall was inspected regularly to evaluate the corrosion rate of convection tube indirectly. However the operation temperature and the phase of the process stream was different between inside the chamber and outside the chamber. As a result, it caused severe corrosion to the horizontal convection tube inside the chamber comparing to the elbow outside the chamber. Finally convection tube was corroded more rapidly than the elbow and ruptured after 13 years operation. Because of the rupture, the heater was totally burned and the operation was stopped for 3 months until it has been reconstructed. To prevent this kind of corrosion problem and accident, corrosion control should be strengthened and protection technology should be improved.

• Corrosion Science and Technology
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• v.12 no.3
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• pp.149-157
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• 2013

In corrosion-sensitive areas of exsisting unpainted weathering steel bridges with closed box girder structures. there are some serious local corrosion problems because of rain water or dew water which can not be solved by exsisting maintenance methods. These problems must be controled technically because of bad. influence on the safety of bridge. This study is the first stage of developing the economic corrosion control manual for these local corrosion problems. Through the injection of tar sealant into the crevice of mock-up equipment, it was prooved that the corrosive sealant can be useful to corrosion control at crevice of corrosion sensitive area.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.631-634
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• 1999

A series of in-situ inspection and measurements have been conducted to estimate rebar corrosion incidence of freeway concrete bridges in Seoul metropolitan area. The results of this study have been analysed to identify the extent of chloride concentration and incidence of steel corrosion in various ages and in the different members of the structures. About 34% of the freeway structures had a value lower than - 350mV(vs CSE), so it could conclude that the excessive chloride concentration was a major cause of rebar corrosion.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.2
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• pp.147-154
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• 2005

It is found that as contents of chloride ion and age increase, area of corrosion also increases. Inare increased to 1035 days from 730 days, slope of increase of corrosion area is greatest. Non-rust inhibitor specimens show corrosion area of 8~35 times more than rust inhibitor specimens and anticorrosive effects by application of rust inhibitor can be confirmed. When chloride ion is not contained, corrosion control effects of steel reinforcing according to increase of thickness are found, but specimens having chloride ion show no regular tend of thickness and corrosion due to complex problems such as reverse diffusion of chloride and test errors.

• Corrosion Science and Technology
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• v.14 no.4
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• pp.190-194
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• 2015

The splash zone is the most corrosive area of the marine environment, and the corrosion of steel structures exposed in this area is a serious concern. DH36 steel is one of most commonly used steels for offshore oil platforms in China, and its corrosion behaviour in splash zones was studied in this paper. Polarization curves were obtained from the corroded steel exposed in this area while the morphologies and rusts of the rust steel were characterized using scanning electron microscopy and X-ray diffraction. Double rust layers were formed in the splash zone. The inner layer contained magnetite and fine flaky lepidocrocite, and the outer layer was composed of accumulated flaky lepidocrocite and a small amount of goethite. In the wet period, the iron dissolved and reacted with lepidocrocite, and magnetite appeared, while the magnetite was oxidized to lepidocrocite again during the dry period. Electrochemical reduction and chemical oxidization cycled in intermittent wetting and drying periods, and magnetite and lepidocrocite were involved in the reduction reaction, leading to serious corrosion.

• Corrosion Science and Technology
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• v.5 no.3
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• pp.106-111
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• 2006

Painting has protected metallic stack but the paint films may be degraded and corrosion problem can be arisen. To protect the painted metal stack, cathodic protection can be applied. If cathodic protection is applied to bare metal, only small area may be protected. However, if cathodic protection is applied to painted metal surface, large area can be protected and the lifetime of paint films can be extended. High corrosion resistant alloys were corroded at a Flue Gas Desulfurization (FGD) facility of power plant within a short period and thus cathodic protection can be used to protect these metals. On the base of computer simulation, if cathodic protection is applied to bare metal in a FGD environment, it was estimated that applied current could almost be spent to protect area near the anode. However, if cathodic protection is applied to high resistant-coated metal, the much larger area from the anode could be effectively protected.

• Corrosion Science and Technology
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• v.8 no.1
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• pp.27-39
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• 2009

Non metallic composite materials, for example, GECM(graphite epoxy composite material) show high specific strength because of low density. These kinds of non metallic composite materials improved the structural effectiveness and operation economics. However, if these materials contacted several metals, corrosion can be arisen since non metallic composite materials have electrical conductivity. This paper dealt with galvanic corrosion between graphite epoxy composite material and several metals. Base on the electrochemical galvanic corrosion test between GECM and metals, corrosion current of carbon steel and aluminium increased with time but corrosion current of stainless steels and titanium decreased and galvanic potential increased. This behavior shows the galvanic corrosion depends upon the presence of passive film. Also, galvanic effect of GECM coupled with ferrous alloys and non-ferrous alloys was lower than that of 100% graphite, which is attributed to lower exposed area of graphite fiber in the GECM than apparent area of the GECM specimen used for the calculation of galvanic current in this work.