• 한국가스학회:학술대회논문집
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• 2001.10a
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• pp.58-68
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• 2001

Microbiologically influenced corrosion (MIC) of carbon steel gas pipeline in soil environments was investigated at field and laboratory MIC is very severe corrosion and it is not easy to distinguish this corrosion from Inorganic corrosion because of its localized, pitting-type character Therefore, it is important to provide proper assessment techniques for the prediction, detection, monitoring and mitigation of MIC. It is possible to predict the MIC risk, i.e., the activity of sulfate-reducing bacteria (SRB) through the analysis of soil environments. Chemical, microbiological and surface analysis of corrosion products and metal attacked could reveal the possibility of the occurrence of MIC. Various electrochemical and surface analysis techniques could be used for the study of MIC. Among these techniques, thin-film electrical resistance (ER) type sensors are promising to obtain localized corrosion rate of MIC induced by SRB. It is also important to study the effect of cathodic protection (CP) on the MIC In case of coated pipeline, the relationship between coating disbondment and the activity of SRB beneath the disbanded coating is also important.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.1
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• pp.187-192
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• 2021

In this study, Inconel 625 was used as a thermal spray material to prevent dew point corrosion damage to the economizer tube, and sealing treatment was performed after applying the arc thermal spray coating technology. Various electrochemical experiments were conducted in the 0.5 wt% sulfuric acid solution to analyze the corrosion resistance of the thermal spray coating (TSC) layer. After the anodic polarization experiment, the degree of corrosion damage was determined through a scanning electron microscope and EDS component analysis. When measuring the open circuit potential, the effect of the sealing treatment was confirmed through stable potential formation of the TSC+sealing treatment (TSC+Sealing). As a result of the anodic polarization experiment, the passivation region was confirmed in TSC and TSC+Sealing, and corrosion resistance was improved as no corrosion damage was observed. In addition, the corrosion resistance of TSC+Sealing was the best when analyzing the corrosion potential and corrosion current density calculated by Tafel analysis.

• 보존과학연구
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• s.32
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• pp.89-98
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• 2011

It is quite difficult to identify its corrosion compound because they have a wide variety of crystal structures and they are mixed with two component. This study was conducted with the standard iron corrosion compounds through the analysis by Raman Micro-Spectroscopy, which aims to obtain standard Raman Data. To assess the reliability of standard iron corrosion compounds, SEM-EDS analysis and XRD analysis were conducted. Through SEM-EDS analysis, the elements of corrosion compound matched with those of standards iron corrosion compounds except Goethite. XRD analysis showed that the structures of corrosion compounds were identical to those of standard iron corrosion compounds, however, it was identified that Iron sulfate ($FeSO_4{\cdot}6H_2O$) is the Rozenite ($FeSO_4{\cdot}4H_2O$). Through Raman Micro-Spectroscopy analysis, the new peak was detected from the wavenumbers of hydroxide and iron oxide. It is considered that it is due to changes in the wavelength of the laser. As the wavenumbers of iron chloride and iron sulfate have been identified, eight kinds of Raman Data were obtained. It can be considered to contribute to cultral heritage for iron objects that Raman Micro-Spectroscopy analysis which is relatively easy to compare material properties and structures can be highly applicable to the research on cultural heritage with the limited amount of samples.

• Computers and Concrete
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• v.29 no.1
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• pp.1-14
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• 2022

Several aspects influence corrosive processes in reinforced concrete (RC) structures such as environmental conditions, structural geometry and mechanical properties. Since these aspects present large randomnesses, probabilistic models allow a more accurate description of the corrosive phenomena. Besides, the definition of limit states in the reliability assessment requires a proper mechanical model. In this context, this study proposes a straightforward methodology for the mechanical-probabilistic modelling of RC structures subjected to reinforcements' corrosion. An improved damage approach is proposed to define the limit states for the probabilistic modelling, considering three main degradation phenomena: concrete cracking, rebar yielding and rebar corrosion caused either by chloride or carbonation mechanisms. The stochastic analysis is evaluated by the Monte Carlo simulation method due to the computational efficiency of the Lumped Damage Model for Corrosion (LDMC). The proposed mechanical-probabilistic methodology is implemented in a computational framework and applied to the analysis of a simply supported RC beam and a 2D RC frame. Curves illustrate the probability of failure evolution over a service life of 50 years. Moreover, the proposed model allows drawing the probability of failure map and then identifying the critical failure path for progressive collapse analysis. Collapse path changes caused by the corrosion phenomena are observed.

• Corrosion Science and Technology
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• v.10 no.3
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• pp.95-100
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• 2011

Protective coatings play an important role in the protection of metallic structures against corrosive environment. The main function of anticorrosive coating is to prevent the materials from corrosive agents, such as water, oxygen and ions. In the study, the corrosion protection properties of urethane and epoxy coating systems were evaluated using EIS methods exposed to the corrosion acceleration test such as Norsok M501, Prohesion and hygrothermal cyclic test. AFM analysis of the coating systems was carried out to monitor the change of roughness of coatings. Urethane coating system was more stable than the epoxy coating under given cyclic conditions. Water uptake into the urethane coatings was less than that into the epoxy coating. The urethane coating system showed better corrosion protection than epoxy coating system based on the changes of the impedance modulus at low frequency region with exposure time. Consequently, the corrosion protection properties of the epoxy and urethane coatings was well correspond with their surface roughness changes and water uptakes.

• Corrosion Science and Technology
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• v.18 no.4
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• pp.117-120
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• 2019

Considering the tendency of development of electrification vehicles, development and verification of new evaluation technology is needed because of new technology applications. Recently, as the battery package is set outdoors of an electric vehicle, such vehicles are exposed to corrosive environments. Among major components connected to the battery package, rust prevention of high-voltage cables and connectors is considered the most important issue. For example, if corrosion of high voltage cable connectors occurs, the corrosion durability assessment of using an electric vehicle will be different from general environmental corrosion phenomena. The purpose of this study is to investigate the corrosion mechanism of high voltage cable connectors of an electric vehicle under various driving environments (road surface vibration, corrosion environment, current conduction by stray current, etc.) and develop an optimal rust prevention solution. To improve our parts test method, we have proposed a realistic test method to reproduce actual electric vehicle corrosion issues based on the principle test.

• International Journal of Railway
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• v.4 no.4
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• pp.86-92
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• 2011

Chloride ion diffusion at the corner of rectangular-shaped concrete structures is presented. At the corner of rectangular-shaped concrete, chloride ion diffusion is in two-dimensional process. Chloride ions accumulate from two orthogonal directions, so that corrosion-free life of concrete structures is significantly reduced. A numerical procedure based on finite element method is used to solve the two-dimensional diffusion process. Orthotropic property of diffusion coefficient of concrete is considered and chloride ion profile obtained from numerical analysis is used to produce transformed diffusion coefficient. Comparisons of experimental data are also carried out to show the reliability of proposed numerical analysis. As a result of two-dimensional chloride diffusion, corrosion-free life of concrete structure for railway is estimated using probability of corrosion initiation. In addition, monographs that produces transformed diffusion coefficient and corrosion-free life of concrete structure are made for maintenance purpose.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.228-233
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• 2004

The length of city gas pipeline is increasing with expansion of natural gas transmission rapidly. A lot of the expense was paid for repair and maintenance with increasing of pipeline length and the cost of repair and maintenance by the corrosion was the highest. It is necessary to evaluate integrity in case of thickness reduction by corrosion. There are a lot of assessment criteria for corrosion defect in foreign countries but they are not suitable for application in the country directly. In this work, we performed the burst test and the finite element analysis for city gas pipeline, KS D3507 and KS D3631 for city gas transmission, and developed the assessment method of corrosion defect, which is suitable for domestic condition.

• Corrosion Science and Technology
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• v.18 no.2
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• pp.49-54
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• 2019

The purpose of this paper is to present failure analysis, of the heat exchanger tube in a district heating system. SS304 stainless steel is used, as material for the heat exchanger tube. The heat exchanger operates in a soft water environment containing a small amount of chloride ions, and regularly repeats operation and standstill period. This causes concentration of chloride ions on the outer surface of the tube, as well as repeat of thermal expansion, and shrinkage of the tube. As a result of microscopic examination, cracks showed transgranular as well as branched propagation, and many pits were present, at the initiation point of each crack. Energy disperstive spectroscopy analysis showed Fe and O peak, as well as Cl peak, meaning that cracks were affected by Cl ion. Failure of the tube was caused by chloride-induced stress corrosion cracking by thermal stress, high temperature, and localized enrichment of chloride ions.

• Korean Journal of Heritage: History & Science
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• v.53 no.1
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• pp.24-33
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• 2020

In excavated bronze artifacts, corrosion products of various shapes and colors are observed due to multiple corrosion factors coexisting in the burial environment, and these corrosion products can constitute important data not only in terms of long-term corrosion-related information, but also in connection with preservation of artifacts. As such, scientific analysis is being carried out on the corrosion layer and corrosion products of bronze artifacts, and the corrosion mechanism and the characteristics of corrosion products elucidated, which is essential for interpreting the exposed burial environment and its association with corrosion factors inside the burial environment. In this study, after classifying excavated bronze artifacts according to alloy ratio and fabrication technique, comprehensive analysis of the surface of corrosion artifacts, corrosion layer, and corrosion products was carried out to investigate the corrosion mechanism, formation process of the corrosion layer, and characteristics of corrosion products. The study designated two groups according to alloy ratio and fabrication technique. In Group 1, which involved a Cu-Sn-Pb alloy and had no heat treatment, the surface was rough and external corrosion layers were formed on a part, or both sides, of the inside and the outside, and the surface was observed as being green or blue. α+δ phase selection corrosion was found in the metal and some were found to be concentrated in an empty space with a purity of 95 percent or more after α+δ phase corrosion. The Cu-Sn alloy and heat-treated Group 2 formed a smooth surface with no external corrosion layer, and a dark yellow surface was observed. In addition, no external corrosion layer was observed, unlike Group 1, and α corrosion was found inside the metal. In conclusion, it can be seen that the bronze artifacts excavated from the same site differ in various aspects, including the formation of the corrosion layer, the shape and color of the corrosion products, and the metal ion migration path, depending on the alloy ratio and fabrication technique. They also exhibited different corrosion characteristics in the same material, which means that different forms of corrosion can occur depending on the exposure environment in the burial setting. Therefore, even bronze artifacts excavated from the same site will have different corrosion characteristics depending on alloy ratio, fabrication technique, and exposure environment. The study shows one aspect of corrosion characteristics in specific areas and objects; further study of corrosion mechanisms in accordance with burial conditions will be required through analysis of the corrosive layer and corrosive product characteristics of bronze artifacts from various regions.