• 한국식품위생안전성학회지
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• 제14권1호
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• pp.84-89
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• 1999

Octenylscuccinated corn starches prepared by reaction of corn starch with 1-octenylsuccinic anhydride(OSAn) and their degree of substitution (DS), reaction efficiency(RE), residual octenylsuccinic acid (OSA), and physicochemical properties were compared with those of the native corn starch. DS increased with increase of OSAn and RE was much nearly the same regardless of increased of OSAn. The content of residual of residual OSA was significantly lower than that of regulation of food additives. And as washing frequency of dispersion of the reactant was increased, the content of residual OSA of octenylsuccinated starch was decreased. Raid Visco-Analyzer initial pasting temperature and setback of octenylsuccinated starches decreased whereas peak viscosity and breakdown increased. When DS of octenylsuccinated starches increased, temperature of initial gelatinization of octenylscuccinated starches drastically decreased. The octenylsuccinated starches also formed clearer pastes. The solubility was much nearly the same regardless of increase of DS at 7$0^{\circ}C$ but the swelling power increased 1.2~1.7 times higher than that of native corn starch at 7$0^{\circ}C$. The water binding capacity of octenylsuccinated starches also decreased.

• 펄프종이기술
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• 제31권5호
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• pp.24-30
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• 1999

Crosslinked corn starches were prepared to increase their molecular weights and their performance as a component of Compozil system was evaluated and compared with that of potato starches. It was shown that greater improvements in retention and strength properties could be achieved when crosslinded cationic corn starches rather than conventional cationic potato starches were used especially at high conductivity because of their molecular rigidity.

• Preventive Nutrition and Food Science
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• 제2권1호
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• pp.23-28
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• 1997

Physicohemical properties of corn starches isolated from non-glutinous and corn grains fol-lowing γ-irradiation up to 10kGy were investigated. Blue value, water binding capacity and swelling power decreased, while alkali number ad solubility increased by γ-irradiation , which was more pronounced in glu-tinous corn starch than in non-glutinous corn starch. The optical transmittance increased with an increment of heating temperature and applied irradiation doses. No significant difference was observed in Hunter's color value between both starches isolated from non- irradiated and irradiated and irradiated corn grains. Amylograph viscosities decreased remarkably as dose levels increased. The overall effects of γ-irradiation was more distinguished in glutinous starch than in non-glutinous starch.

• Preventive Nutrition and Food Science
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• 제5권1호
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• pp.20-24
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• 2000

A study was carried out to establish the detection method of irradiated corn, potato, and sweet potato starches. The samples were packed in polyethylene bags and irradiated with 1, 3, 5, 7, 10, and 15 kGy using a Co-60 irradiator. The maximum viscosity of irradiated and unirradiated corn, potato, and sweet potato starches reduced by increase of irradiation dose levels and showed significant differences which clearly showed the effect of irradia-tion dose levels (p<0.05). Regression expressions and coefficients (p<0.000) or corn, potato, and sweet potato starches were y=-38.538x+718.23(r2=0.9761), y=669.97e-0.1372x (r2=0.9820) and y=-42.544x+730.26(r2=0.9939), respectively. Nor-malized parameter A,B and C values showed a dose dependent relationship and were a better parameter for detecting the irradiated starches than that of the maximum viscosity itself.

• 한국식품과학회지
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• 제25권6호
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• pp.710-715
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• 1993

강남콩, 녹두, 옥수수전분을 99% 메탄올로 탈지시키고 추출된 지질을 에테르로 탈지시료전분에 첨가한 다음 이화학적 특성과 호화양상을 알아보았다. 전분입자의 형태는 강남콩전분과 녹두전분이 둥근타원형이었고 옥수수전분은 다각형이었으며 시료처리 후에도 모양은 변하지 않았다. X-ray 회절도에 나타난 결정형은 모두 Ca형을 보였고 탈지전분의 결정성의 정도는 생전분에 비해 감소하였으나 지질을 첨가한 전분은 증가하였는데 옥수수전분인 경우는 생전분보다 낮게 강낭콩전분과 녹두전분은 더 높게 증가하였다. 아밀로오스의 함량은 탈지 후 증가하였으나 지질을 첨가한 다음에는 감소하였고, 물결합능력에서는 지질첨가전분이 생전분과 탈지전분보다 높게 나타났다. 팽윤력과 용해도는 모든 시료전분에서 온도증가에 따라 상승하였고, 강남콩전분과 녹두전분은 탈지전분, 생전분, 지질첨가전분 순으로 높게 나타났으며, 옥수수전분만이 다른 양상을 보였다. 아밀로그라프에 의한 호화온도는 강남콩, 녹두, 옥수수전분이 각각 $87,\;67,\;80^{\circ}C$였으며 강남콩전분을 제외한 탈지시료전분에서는 최고점도, 냉각점도, consistency, setback 모두 생전분보다 감소하였고 지질첨가전분에서는 녹두전분은 생전분보다는 낮게 탈지전분보다는 높게 증가하였으며 옥수수전분인 경우 최고점도는 생전분과 유사하였으나 다른 특성치들은 생전분과 탈지전분보다 더 증가하였다.

• Preventive Nutrition and Food Science
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• 제3권4호
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• pp.303-308
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• 1998

Influence of amylose content on formation and characteristics of enzyme-resistant starch (RS) was investigated by scanning electron microscopy, X-ray diffractometry and differential scanning calorimetry. RS yield increased up to 36.1 % as the amylose content of corn starch increased. Starch granules of Amyulomaize V and Ⅶ were more rounded and smaller than those of regular corn ; some were elongated and had appendages. After autoclaving -cooling cycles, the granular structure disappeared and a continous spongy-like porous network was visible in regular corn starch ; the granular structure was stillevident in parts in Amylomaize V and Ⅶ starches. In all isolated RS residues , the porous structures were no longer visible and more compact formations predominated. While regular corn starch showed an A-type X-ray profile, Amylomaize V and Ⅶ starches exhibited a combination of B- and V-types. Regular corn starch lost most of its crystallinity during autoclaving , but the crystallinity was still left in Amylomaize starches as diffuse or poor B-types. All RS residues showed the presence of poor B-type regardless of amylose contents. Transition temperatures and enthalypy of native starches were a little higher in Amylomaize V and Ⅶ starches than those of regular corn starch . Regardless of amylose contents, all RS residues exhibited an endothermic transition over a similar temperature range (135 $^{\circ}C$~169$^{\circ}C$), with a mean peak temperature of ~154$^{\circ}C$, which is generally foud for retrograded amylose crystallities. Higher transition temperature, enthalypy, and RS yield of AMylomaize V and Ⅶ starches were related granular stability shown by the microscopic and crystallographic studies.

• 한국식품과학회지
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• 제26권4호
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• pp.475-478
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• 1994

식품에 사용되는 화학적 변성전분류와 acetyl화 전분이 사용된 라면의 돼지 췌장 ${\alpha}-amylase$에 의한 in vitro 소화율($37^{\circ}C$에서 6시간)을 비교하였다. Native potato starch와 acetylated potato starch의 가수분해율은 각각 64.5%와 59.3%, native와 hydroxypropylated corn starch는 70.5%와 60.4%, 그리고 native와 hydroxypropylated high amylose corn starch는 65.2%와 57.3%로서 native한 것들이 유도체들보다 높았다. Waxy corn starch들의 소화율은 pregelatinized(74.3%)>native(72.1%)>acetylated(66.5%)>acetyl distarch adipate(56.4%)>hydroxypropyl distarch phosphate(50.7%)의 순으로 감소하였다. 국내에서 생산, 판매되고 있는 5개 회사의 봉지라면과 용기라면에 대한 실험에서는 실제 조리조건에서 소화율에 유의적 차이를 보이지 않았다. 결론적으로 화학적 변성전분의 소화율은 천연전분보다 낮지만 상용식품에서의 사용량이 매우 낮으므로 식품 섭취에 따른 전분질의 소화율에는 큰 영향을 미치지 않을 것으로 판단된다.

• 펄프종이기술
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• 제30권2호
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• pp.30-39
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• 1998

Effect of cationic starches and anionic colloidal silica on retention and drainage characteristics of Compozil system was investigated. Depending upon the degree of substitution and molecular weight of cationic starches and morphological characteristics of anionic colloidal silica, retention and drainage properties of Compozil system were significantly influenced. When cationic starch addition level increased above a certain limit retention and stock freeness were decreased. To elucidate this an electrostatic coagulation mechanism occurring between unadsorbed starch molecules and anionic colloidal silica was proposed. Unstructured colloidal silica showed greater improvement in retention than structured colloidal silica. Cationic corn starches with different degree of substitution and molecular weights were prepared and their effect as a constituent of Compozil system was also evaluated. By controlling the molecular weight and degree of substitution of cationic corn starch it was possible to achieve significant improvement in fines retention. Cationic corn starch with higher degree of substitution maintained its retention efficiency even when the stock conductivity was increased. Turbidity measurement technique was found to be a simple and useful method to measure the retention characteristics.

• 한국식품영양과학회지
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• 제31권2호
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• pp.189-195
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• 2002

전분의 물리화학적 성질과 기능 특성을 개선하여 식품에서의 이용성을 확대하고자, 0.25, 0.5, 0.75, 1.0과 1.5% active Cl/g starch를 포함하는 NaOCl 용액으로 pH 7.0, $25^{\circ}C$에서 10분간 처리하여 산화 전분을 제조한 후 산화전분의 이화학적 특성과 호화 특성을 비교 분석하였다. 산화전분은 입자의 형태와 크기에 차이가 없었고, 뚜렷한 복굴절 현상을 보였다. 무처리 전분과 산화전분의 겉보기 아밀로오스 함량은 차이가 없었으며, 가용성 아밀로오스의 함량은 증가하였다 산화됨에 따라 X-선 회절도의 피크 강도와 위치가 변하여 상대적 결정화도가 감소하였고, 용해도와 팽윤력이 증가하였다. 아밀로그램에서 산화전분은 호화 개시 온도가 무처리 전분과 차이가 없었으나 산화제의 처리 농도가 증가됨에 따라 최고 점도와 setback이 감소하였다.

• 한국식품영양학회지
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• 제9권4호
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• pp.424-429
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• 1996

전분의 첨가가 냉동면의 조직감과 관능적 특성에 미치는 영향을 밝히기 위하여 감자초산변성전분, 옥수수초산변성전분, 찰옥수수전분, 옥수수전분, 감자전분, 밀전분 등 6종의 전분을 함량별로 첨가하여 복합분을 제조하였다. 이들의 아밀로그래프, 제면시의 조리시험, 냉동, 해동후 면의 최대절단강도를 측정하고 관능평가하였다. 감자초산변성전분과 감자전분을 첨가한 복합분의 호화개시온도는 대조구인 소맥분 100%보다 다소 낮아졌다. 최고점수는 초산변성전분류, 찰옥수수, 감자전분을 첨가한 경우 다소 높아졌다. 조리시의 체적과 중량은 다소 증가하고 고형분 용출량은 변성전분과 찰옥수수전분을 참가한 경우 다소 감소하였다. 냉동, 해동 조리 후 면의 최대절단강도는 감자초산변성전분 15%와 20%, 옥수수초산변성전분 15%를 첨가한 경우에 대조구보다 커졌다. 감자전분을 제외한 나머지 5종의 전분을 첨가시에 냉동면의 조직감과 색깔이 다소 향상되는 것으로 나타났다. 그 중에서 감자초산변성전분의 효과가 가장 높았다.