• Title/Summary/Keyword: core-shell structures

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Multiform Oxide Optical Materials via the Versatile Pechini-type Sol-Gel Process

  • Lin, J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1247-1250
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    • 2008
  • This presentation highlights work from the authors' laboratories on the various kinds of oxide optical materials, mainly luminescence and pigment materials with different forms (powder, core-shell structures, thin film and patterning) prepared by the Pechini-type sol-gel (PSG) process. The PSG process which uses the common metal salts (nitrates, acetates, chlorides etc) as precursors and citric acid (CA) as chelating ligands of metal ions and polyhydroxy alcohol (such as ethylene glycol or poly ethylene glycol) as cross-linking agent to form a polymeric resin on molecular level, allowing the preparation of many forms of luminescent materials.

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Magnetic Properties of Fe Nanoparticles Synthesized by Chemical Vapor Condensation

  • Park, C. J.;Kim, B. K.;X. L. Dong
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.228-229
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    • 2000
  • Magnetic Fe nanoparticles were synthesized by CVC process using Fe(CO)$\sub$5/ as precursors. The nanoparticles have core-shell structures with uniform dispersion. For the specific purposes, the micostructures as well as the magnetic states of Fe nanoparticles can be controlled by adjusting the process parameters, such as the carrier gases, the decomposition temperature, the cooling of powder, etc.

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A Study on the Standardized Finite Element Models for Carbody Structures of Railway Vehicle Made of Sandwich Composites (샌드위치 복합재 적용 철도차량 차체 구조물의 표준유한요소모델 제시 연구)

  • Jang, Hyung-Jin;Shin, Kwang-Bok;Ko, Hee-Young;Ko, Tae-Hwan
    • Journal of the Korean Society for Railway
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    • v.13 no.4
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    • pp.382-388
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    • 2010
  • This paper describes the standardized finite element model for carbody structures of railway vehicle made of sandwich composites. Recently, sandwich composites were widely used to railway vehicle due to the improvement of energy efficiency, high specific stiffness and strength, weight reduction and space saving in korea. Therefore, structural integrity should be verified using finite element analysis prior to the manufacture of composite railway vehicle. The standardized finite element model for composite carbody structures was introduced through comparing the results of real structural test under vertical, compressive, twisting load and natural frequency test of various railway vehicles in this study. The results show that the quadratic shell element is suitable to model the reinforced metal frame used to improve the flexural stiffness of sandwich panel compared to beam element, and layered shell and solid element are recommended to model the skin and honeycomb core of sandwich panel compared to sandwich shell element. Also, the proposed standard finite element model has the merit of being applied to crashworthiness problem without modifications of finite element model.

Smart analysis of doubly curved piezoelectric nano shells: Electrical and mechanical buckling analysis

  • Arefi, Mohammad
    • Smart Structures and Systems
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    • v.25 no.4
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    • pp.471-486
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    • 2020
  • Stability analysis of three-layered piezoelectric doubly curved nano shell with accounting size dependency is performed in this paper based on first order shear deformation theory and curvilinear coordinate system relations. The elastic core is integrated with sensor and actuator layers subjected to applied electric potentials. The principle of virtual work is employed for derivation of governing equations of stability. The critical electrical and mechanical buckling loads are evaluated in terms of important parameters of the problem such as size-dependent parameter, two principle angle of doubly curved shell and two parameters of Pasternak's foundation. One can conclude that mechanical buckling loads are decreased with increase of nonlocal parameter while the electrical buckling loads are increased.

Vibration characteristic analysis of sandwich cylindrical shells with MR elastomer

  • Yeh, Jia-Yi
    • Smart Structures and Systems
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    • v.18 no.2
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    • pp.233-247
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    • 2016
  • The vibration characteristic analysis of sandwich cylindrical shells subjected with magnetorheological (MR) elastomer and constraining layer are considered in this study. And, the discrete finite element method is adopted to calculate the vibration and damping characteristics of the sandwich cylindrical shell system. The effects of thickness of the MR elastomer, constraining layer, applied magnetic fields on the vibration characteristics of the sandwich shell system are also studied in this paper. Additionally, the rheological properties of the MR elastomer can be changed by applying various magnetic fields and the properties of the MR elastomer are described by complex quantities. The natural frequencies and modal loss factor of the sandwich cylindrical shells are calculated for many designed parameters. The core layer of MR elastomer is found to have significant effects on the damping behavior of the sandwich cylindrical shells.

Numerical frequency analysis of skew sandwich layered composite shell structures under thermal environment including shear deformation effects

  • Katariya, Pankaj V.;Panda, Subrata K.
    • Structural Engineering and Mechanics
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    • v.71 no.6
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    • pp.657-668
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    • 2019
  • The numerical thermal frequency responses of the skew sandwich shell panels structure are investigated via a higher-order polynomial shear deformation theory including the thickness stretching effect. A customized MATLAB code is developed using the current mathematical model for the computational purpose. The finite element solution accuracy and consistency have been checked via solving different kinds of numerical benchmark examples taken from the literature. After confirming the standardization of the model, it is further extended to show the effect of different important geometrical parameters such as span-to-thickness ratios, aspect ratios, curvature ratios, core-to-face thickness ratios, skew angles, and support conditions on the frequencies of the sandwich composite flat/curved panel structure under elevated temperature environment.

Synthesis of Ultra-long Hollow Chalcogenide Nanofibers

  • Jwa, Yong-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.3.1-3.1
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    • 2011
  • Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

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Preparation of 40 wt.% Ag-coated Cu Particles with Thick Ag Shells and Suppression of Defects in the Particles (두꺼운 Ag shell이 형성되는 40 wt.% Ag 코팅 Cu 입자의 제조 및 입자 내 결함 억제)

  • Choi, Eun Byeol;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.65-71
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    • 2017
  • To prepare the Cu-based filler material indicating enhanced oxidation resistance property and Ag content, Ag-coated Cu particles was fabricated by Ag plating of 40 wt % on the spherical Cu particles with an average size of $2{\mu}m$ and their oxidation behavior was also evaluated. In the case that ethylenediaminetetraacetic acid was used alone, the fabricated particles frequently showed broken structures such as delamination at Ag shell/core Cu interface and hollow structure that are induced by excessive galvanic displacement reaction. As a result, fraction of defect particles increased up to 19.88% after the Ag plating of 40 wt.%. However, the fraction in the 40 wt.% Ag-coated Cu particles decreased to 9.01% and relatively smooth surface and dense microstructure in the Ag shell were also observed with additional usage of hydroquinone as a complexing agent. Ag-coated Cu particles having the enhanced microstructure did not show any weight increase by oxidation for exposure to air at $160^{\circ}C$ for 2 h, indicating increased oxidation resistance property.

Preparation of Porous Nanostructures Controlled by Electrospray

  • Nguyen, Dung The;Nah, In Wook;Kim, Kyo-Seon
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.627-631
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    • 2015
  • Various solid structures were prepared by electrospray technique. In this process, liquid flows out from a capillary nozzle under a high electrical potential and is subjected to an electric field, which causes elongation of the meniscus to form a jet. In our study, by controlling the amount of polyvinyl pyrrolydone in precursor solution, the jet either disrupted into droplets for the formation of spherical particles or was stretched in the electric field for the formation of fibers. During the electrospray process, the ethanol solvent was evaporated and induced the solidification of precursors, forming solid particles. The evaporation of ethanol solvent also enhanced the mass transport of solutes from the inner core to the solid shell, which facilitated fabrication of porous and hollow structure. The network structures were also prepared by heating the collector.