• Title/Summary/Keyword: core property

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Synthesis and Electrochemical Characterization of Silica-Manganese Oxide with a Core-shell Structure and Various Oxidation States

  • Ryu, Seong-Hyeon;Hwang, Seung-Gi;Yun, Su-Ryeon;Cho, Kwon-Koo;Kim, Ki-Won;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2683-2688
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    • 2011
  • Silica-manganese oxides with a core-shell structure were synthesized via precipitation of manganese oxides on the $SiO_2$ core while varying the concentration of a precipitation agent. Elemental analysis, crystalline property investigation, and morphology observations using low- and high-resolution electron microscopes were applied to the synthesized silica-manganese oxides with the core-shell structure. As the concentration of the precipitating agent increased, the manganese oxide shells around the $SiO_2$ core sequentially appeared as $Mn_3O_4$ particles, $Mn_2O_3+Mn_3O_4$ thin layers, and ${\alpha}-MnO_2$ urchin-like phases. The prepared samples were assembled as electrodes in a supercapacitor with 0.1 M $Na_2SO_4$ electrolyte, and their electrochemical properties were examined using cyclic voltammetry and charge-discharge cycling. The maximum specific capacitance obtained was 197 F $g^{-1}$ for the $SiO_2-MnO_2$ electrode due to the higher electronic conductivity of the $MnO_2$ shell compared to those of the $Mn_2O_3$ and $Mn_3O_4$ phases.

A Study on The Core Values of Korea National Police (경찰의 핵심가치에 관한 연구)

  • Park, Hyung Sik
    • Convergence Security Journal
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    • v.14 no.3_2
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    • pp.45-50
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    • 2014
  • The police have a responsibility to ensure the safety such as the Public peace and order, life and property of the people. Therefore the police system is to be provided in the organization and functioning. And the policemen should live correctly in public or private living. The police shall perform the duties matching the expectations of the people. But in reality the poloce disappointed, so the people were often to be angry. In this paper, I want to derive the core values of the police as a way to get the confidence of the people by analyzing the code of ethics, the moral of the police institution and the great acts of policemen. Core values are the most important values as the basis for action a nd the most important foundation that make up the organizational culture. Core values of korean police are justice and the spirit of sacrifice, honor.

Synthesis and Characterization of Spherical SiO2@Y2O3 : Eu Core-Shell Composite Phosphors (구형 SiO2@Y2O3: Eu 코어-쉘 복합체 형광체 합성 및 특성)

  • Song, Woo-Seuk;Yang, Hee-Sun
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.447-453
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    • 2011
  • The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

Experimental study of buckling-restrained brace with longitudinally profiled steel core

  • Lu, Junkai;Ding, Yong;Wu, Bin;Li, Yingying;Zhang, Jiaxin
    • Structural Engineering and Mechanics
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    • v.81 no.6
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    • pp.715-728
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    • 2022
  • A new type of buckling-restrained braces (BRBs) with a longitudinally profiled steel plate working as the core (LPBRB) is proposed and experimentally investigated. Different from conventional BRBs with a constant thickness core, both stiffness and strength of the longitudinally profiled steel core along its longitudinal direction can change through itself variable thickness, thus the construction of LPBRB saves material and reduces the processing cost. Four full-scale component tests were conducted under quasi-static cyclic loading to evaluate the seismic performance of LPBRB. Three stiffening methods were used to improve the fatigue performance of LPBRBs, which were bolt-assembled T-shaped stiffening ribs, partly-welded stiffening ribs and stiffening segment without rib. The experimental results showed LPBRB specimens displayed stable hysteretic behavior and satisfactory seismic property. There was no instability or rupture until the axial ductility ratio achieved 11.0. Failure modes included the out-of-plane buckling of the stiffening part outside the restraining member and core plate fatigue fracture around the longitudinally profiled segment. The effect of the stiffening methods on the fatigue performance is discussed. The critical buckling load of longitudinally profiled segment is derived using Euler theory. The local bulging behavior of the outer steel tube is analyzed with an equivalent beam model. The design recommendations for LPBRB are presented finally.

Synthesis and Effect of Plasma Treatment of Acrylic Composite Particle Binder (아크릴계 복합입자 바인더의 제조와 플라즈마 처리영향)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.276-283
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    • 2008
  • Kind of monomer(MMA, EA, BA, St)and the monomer ratio(80/20 to 20/80) where changed in the preparation of the core shell binder, and property was improved the plasma processing. Each material changed by plasma treatment time($1{\sim}10\;s$) to change to measure the tensile strength, contact angle and adhesion peel strength for the core shell binder optimal conditions for handling the output of the surface treatment. The type of polymerization and composition of the binder is a regardless initiator of APS, the reaction temperature of $85^{\circ}C$ to 0.3 wt% of the surfactant used to indicate when the conversion rate was the highest, core shell composite particle binder got two glass temperature curves. Core shell binder after the plasma processing contact angle change is the PEA/PSt 38 percent of cases within five seconds to indicate slight decrease was a decline rapidly if not handled $0^{\circ}$ to reach. Tensile strength PSt/PMMA varies $46.71{\sim}46.27\;kg_f$/2.5 cm and adhesion strength PEA/PMMA varies $7.89{\sim}14.44\;kg_f$/2.5 cm increases. Overall, adhesion strength of core shell composite particle is in the order of order PEA>PBA>PSt for shell monomer MMA.

A study on the Half-Bridge converter combine output inductor with transformer (출력 인덕터와 변압기를 결합시킨 하프브리지 컨버터에 관한 연구)

  • Bae, Jin-Yong;Kim, Yong;Kwon, Soon-Do;Baek, Soo-Hyun;Choi, Geun-Soo
    • Proceedings of the KIEE Conference
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    • 2006.04b
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    • pp.211-215
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    • 2006
  • This paper present the Half-Bridge converter for low current output. In converter system, magnetic components are important devices used for energy storage, energy transfer, galvanic isolation and filtering. The proposed Half-Bridge converter is to reduce the number of magnetic components. The secondary rectification was discussed by comparison of center-tap type with primary center-core transformer winding and primary side-core transformer winding. A prototype featuring 400V input, 10V output, 400kHz switching frequency, and 100W output power.

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Movement Characteristics Analysis of Single Phase Transformer Winding Using Finite Element Method (유한요소법을 이용한 단상변압기권선의 운동특성해석)

  • Choi, Myoung-Jun;Kim, Hyung-Seok;Park, Il-Han
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.104-106
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    • 1996
  • In this paper, the dynamic motion driven by electromagnetic force of transformer windings is modeled and its characteristics are numerically analyzed. The electromagnetic field is obtained using the 2D finite element method taking account of anisotropic property of iron core, and the electromagnetic force on the transformer winding is calculated from Lorenz's force formula using the field distribution result. The system motion equation driven by electromagnetic force and gravitational force is numerically analyzed using the 4-order Runge-Kutta algorithm. Above analyses procedure is applied to a single-phase core-type transformer to validate its algorithm.

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Property of Thermal Conductivity of Light Weight Panel Core Using Light-Weight Aggregate (인공경량골재를 이용한 경량패널 심재의 열전도 특성)

  • 이정국;도정윤;문경주;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.131-136
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    • 2002
  • In recent year, it has been investigated on the reduction of mass of structures for the purpose of the larger space and the economy with the industry developing very fast and qualitatively. So the purpose of this study is to investigate the manufacture of light weight concrete panel using the artificial light-weight aggregate as a part of the substitution of foamed styrene and polyurethane because of narrow allocable temperature zone in use. The compressive strength, flexural strength, unit weight, absorption test and thermal conductivity were practised at 3, 7 and 28 days after manufacturing the light-weight concrete lot the panel core: the filling ratio of continuous void was defied as 40%, 50%, and 60% and water-cement rate was 35, 40 and 45%. As a result of this, it was revealed that the mixture derived from filling ration of void of 50% and water-cement ratio 40% were developing the best properties of the others.

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Benzothiazole fluorine-boron core complex: quantum luminescence controls

  • Son, Young-A;Kim, Hyung-Joo;Li, Xiaochuan
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.71-71
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    • 2012
  • To control luminescence emission property, a novel series of strong fluorescent fluorin-boron complexes were synthesized in higher yield. The resulting structural analysis was completed. Small molecules with a built-in fluorine-boron core structural architecture has been attracted considered attention as the key emissive elements due to the their good properties such as bipolar charge transport and high photo efficiency. Thus, new type of fluorine-boron(F-B) complexes are designed and prepared. Changing the substituent position on fluorophore ring provided a deep understanding on the relationship between structure and optical properties.

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A Service Framework to Digital Fulltext Image for Copyright Protection (저작권 보호를 위한 디지털 원문 서비스 프레임워크)

  • Kim Sang-Kuk;Shin Sung-Ho;Yoon Hee-Jun;Kim Tae-Jung
    • Journal of Korea Technology Innovation Society
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    • v.8 no.spc1
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    • pp.323-336
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    • 2005
  • Digital content industry is growing rapidly because of the property of high-speed networking and greater demand for digital fulltext-image. However, we know the fact that it is many difficulty in production and supply for good quality of content. Hereupon, we suggest digital fulltext-image service framework to protect copyright. More concretely, we propose integrated model and reference model to securely serve digital fulltext-image by recompositing core objects and reconstructing the value-chain structure of digital content industry to framework including the process(from its production (creators or copyrighters) to consumption (users or consumers)). Also, we construct the digital fulltext- image service system based on reference model and reconstruct its interface that occurs between core subjects.

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