• Title/Summary/Keyword: cordierite

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Preparation and Properties of Cordierite Aluminium Titanate Composites (코디에라이트-티탄산알루미늄 복합체의 제조 및 특성)

  • 송휴섭;김상우;장성도;손용배
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.345-354
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    • 1990
  • The densification behaviro and resulting properties of cordierite-aluminium titanate composites containing 5 to 40wt.% aluminium titanate were investigated. Compared with cordierite monolithics a substantial increase of sintering temperature range for composites was observed, which was due to the formation of cordierite and glass phase at relatively low temperatures. The bending strength of composites showed its maximum at 30wt.% aluminium titanate content, which was about 50% increase relative to the cordierite monolithics, then decreased by a small amount at 40wt.% aluminium titanate content. The decrease was explained by the increase of microcracks whose presence was confirmed by the hysteresis of thermal expansion curve of composites. However, the microcracks formed was not severe enough to produce a significant decrease in strength, which was also evidenced by the continuous increase of thermal expansion coefficient up to 40wt.% aluminium titanate content.

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Studies of the Mullite-Cordierite Composites as a Substrate Material (기판재료로서의 물라이트-코디어라이트 복합재료에 관한 특성)

  • 김경용;김윤호;정형진;김석수;김병호
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.394-400
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    • 1990
  • Mullite and cordierite were prepared by the sol-gel route. Boehmite, fumed silica and Mg(NO3)2$.$6H2O were their starting materials. Mullite and cordierite powder were mixed by various weight percent. These mixed sols were ball-milled for 48hrs, dried at 100$^{\circ}C$, pressed, cold isostatic pressed and sintered at 1490$^{\circ}C$ for 2hrs. Mullite-cordierite composites sintered at 1490$^{\circ}C$ for 2hrs had>98% of theoretical density. Bending strength of the sintered bodies were 329-249MPa, dielectric constant 7.1-6.7 at 1MHz and thermal expansion coefficient at 800$^{\circ}C$ was matched with Si in the range of 30-35wt% cordierite.

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Low Temperature Fireable Cordierite/Microcomposite Ceramic Substrates (Cordierite/Microcopmposite 저온 소성 세라믹 기판재료)

  • 구본급
    • Journal of the Microelectronics and Packaging Society
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    • v.2 no.1
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    • pp.49-58
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    • 1995
  • 출발물질은 cordierite 유리와 borosilicate/Si3N4 복합분말을 사용하였다. Cordierite 유리조성은 무게비로 17.8MgO-23.1Al2O3-48.1ASiO2-5.0ZnO-1.0B2O3를 선택하였다. Borosilicate/Si3N4복합분말은 sol-gel법으로 a-si3N4 core 분말에 borosilicate 겔을 코팅하여 얻었다. 복합분말과 cordierite 유리 분말을 부피비로 0/100, 12.5/87.5 및 25/75의 조성으로 혼합하여 tape casting 에 의해 green sheet를 제작하였다. 이들 sheet들을 800~100$0^{\circ}C$에서 2시간 소성하여 얻은 시편을 SEM, XRD, 밀도, 유전상수 등을 측정하여 저 유전율의 저온 소성 기판재료를 제조하기 위한 조건들을 검토하였다.

Cordierite Powder Preparation from Alkoxides without Using Organic Solvents (유기용매의 사용없이 알콕사이드로부터 코디어라이트 분말제조)

  • Ryu, S.C.;Kim, H.R.;Kim, K.;Park, H.C.
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.291-297
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    • 1994
  • Cordierite powders were prepared by controlled hydrolysis of metal alkoxides with catalysts in water medium without using organic solvents. Water was adjusted to a certain pH by HC1 and NH4OH. $\alpha$-Cordierite powder was prepared from aluminum isopropoxide, tetraethyl orthosilicate and magnesium ethoxide mixed with water adjusted to pH of 3. At water pH of 11, $\alpha$-cordierite, mullite and $\beta$-quartz phases were coexisted. The powders were freeze dried, calcined and then fired at different temperatures. The characteristics of powders were examined by means of DTA, X-ray diffraction, FT-IR, and electron microscopy. It was found that $\alpha$-cordierite could be synthesized at temperature of 120$0^{\circ}C$ from the powders prepared by alkoxides with water medium without organic solvents.

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Effect of SiC on the Mullite-Cordierite Composite Properties

  • Motaman, A.;Amin, S.A.;Jahangir, A.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1067-1070
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    • 2006
  • Experimental samples were produced with mullite and cordierite powders with SiC. Effects of temperature, atmosphere and additive on the composite properties were investigated by XRD, STA and PSA methods. Results show that samples containing calcinate cordierite and calcinate mullite with SiC baked in air atmosphere have not suitable properties at the temperature range of $1380-1450^{\circ}C$ due to SiC intensive oxidation, while argon atmosphere decrease SiC oxidation. Using $Bi_2O_3$ as the additive, cordierite phase formation and prevention from SiC oxidation at low temperatures were achieved, leading to the improvement of physical and mechanical properties

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The Effect of $MnO_{2}$ on the Characteristics of an Infrared Radiator of Cordierite System with Pressing Method (成形法에 따른 Cordierite系 赤外線 放射體의 諸特性에 미치는 $MnO_{2}$의 影響)

  • 강이국;신용덕
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.44 no.6
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    • pp.799-805
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    • 1995
  • An infrared radiator of cordierite system were manufactured byslurry casting anddry pressing method. The characteristics of cordierite (2MgO.2Al$_{2}$O$_{3}$.5SiO$_{2}$)+30wt% clay+Xwt% MnO$_{2}$ of infrared radiator have been investigated as a function of MnO$_{2}$ additives (X=0, 0.1, 0.25, 0.5, 1.0, 1.5, 2.0, 2.5). The thermal expansioncoefficient was decreased with increasing amounts of MnO$_{2}$ additives. Otherwise, the spectral emissivity was increased in the below 4.5.mu.m wavelength. Also, the infrared radiator of cordierite system which spectral emissivity was approximately 1.0 can be attainable at from 4.5.mu.m to 8.mu.m wavelength. The spectral emissivity was decreased from 8.mu.m to 14.mu.m above X=2.5.

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Effects of MnO$_2$additives on the thermal properties of infrared radiator of Cordierite system (Cordierite계 적외선 방사체의 열적 특성에 미치는 MnO$_2$의 영향)

  • 송창열;강이국;최두선;신용덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.133-137
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    • 1994
  • Infrared radiator of Cordierite system were manufactured using Cordierite(2Mgo$.$2Al$_2$O$_3$$.$5SiO$_2$) and Clay 30wt% as main materials and addition of MnO$_2$ from 0. 1 to 2 5wt% of Dry pressing and slip casting The effects of MnO$_2$ additives on the thermal properties of infrared radiator of Cordierite system. The more the thermal expansion could be lowered the more the amount (wt%) of additives MnO$_2$is increased in the below 4.5$\mu\textrm{m}$. The high efficiency Infrared radiator of Cordierite system using dry pressing method when the amount of additives MnO$_2$is 2.0 wt%

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A Study on Rheological Behavior of Cordierite Honeycomb Extrusion Paste (코디어라이트 허니컴 압출용 혼합체의 점성거동에 관한 연구)

  • Song, Yong-Ik;Kim, Hyung-Tae;Lee, Jin-Gu;Yoon, Won-Jung;Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.44-51
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    • 2010
  • The rheological behavior of a cordierite honeycomb extrusion paste was investigated by measuring torque values in a Brabender plastograph. The extrusion pastes were formulated using binder (methy cellulose, MC), solvent (water), plasticizer (ploy ethylene glycol, PEG) and lubricants (oleic acid, OA). The mixing sequence and optimum organic binder, at least for homogeneous mixed state, can be determined from the rheological point of view. 3%MC-30%$H_2O$-1.5%PEG-1.0%OA with respect to the cordierite powder was chosen as a binder composition for the extrusion process of cordierite powder.

Preparation and Characteristics of Catalyst Coated Cordierite Filter (촉매 처리된 코디어라이트 필터의 제조 및 그 특성)

  • Kim, Yeong-Bae;Jo, Eul-Hun;Jang, Yun-Yeong;Sin, Min-Cheol;Lee, Hui-Su;Choe, Deok-Gyun
    • Korean Journal of Materials Research
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    • v.12 no.2
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    • pp.129-134
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    • 2002
  • The optimum condition for fabricating cordierite disc type filter element was deduced. Cordierite monolith was used as starting material for filter element because it has many advantages such as high thermal shock resistance and good catalytic activity compared with $TiO_2$and SiC. The contents of organic additives and foaming agent were optimized to control the porosity and mechanical strength of cordierite filter. Among the required properties to be adopted as filter elements, the pressure drop and NOx removal efficiency were investigated depending on processing variables. It was found that pressure drop depends on particle size distribution of cordierite monolith and organic additives added as forming agent. The pressure drop at 5cm/sec of face velocity was in the range of 15~655mm$H_2O$ at room temperature. The NOx removal efficiency of catalytic filter with $V_2O_5$ as catalyst was over 85% at $450^{\circ}C$.

A Study on the Combustion Characteristics over Pd/cordierite Catalyst (Pd/cordierite 촉매상에서 메탄의 연소 특성 고찰)

  • Cho, Won-Ihl;Oh, Young-Sam;Park, Dal-Ryung;Baek, Young-Soon;Pang, Hyo-Sun;Mok, Young-Il
    • Journal of Energy Engineering
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    • v.6 no.1
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    • pp.34-40
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    • 1997
  • This study aims to investigate the application possibility on natural gas in relation to the catalytic combustion of methane on Pd/cordierite catalyst which is currently used as an automobile converter catalyst. The surface area of the catalyst tested was determined to be about 18.7㎡/g and to keep stable condition in structure at mid-high temperatures. The activation energy for methane combustion reaction was estimated to be 19.2 kcal/mol and a hysterisis on the catalyst activity was observed in terms of the catalyst deactivation as the reaction temperature was varied for the methane combustion. On Pd/cordierite catalyst, The characteristics of methane combustion were studied as functions of space velocity and air/fuel ratios below 700$^{\circ}C$.

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