• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.1
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• pp.39-43
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• 2015

The cement mixtures such as flyash, iron-slag and silica fume have been actively studied in order to increase the quality of concrete. In this study, the grinded copper-slag with different proportion was added to portland cement. The physical properties of the cement mortars, (i.e.) flowability, absorption, compressive strength and flexural strength, were investigated for the potential application to the cement. Also, the influence of the acid on the chemical resistance of the cement mortars with copper-slag was evaluated by monitoring the weight variation of the cement mortars under 5 % sulfuric acid for 28 days.

• Resources Recycling
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• v.23 no.3
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• pp.30-36
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• 2014

A large amount of waste copper slag containing about 35 ~ 45% iron has been generated and discarded every year from pyrometallurgical processes for producing copper from copper concentrate. Thus, recovery of iron from the waste copper slag is of great interest for comprehensive use of mineral resource and reduction of environment problems. In this study, a physico-chemical separation process for upgrading iron from the waste copper slag discharged as an industrial waste has been developed. The process first crushes the waste copper slag below 1 mm (first crushing step), followed by carbon reduction at $1225^{\circ}C$ for 90 min (carbon reduction step). And then, resulting material is again crushed to $-104{\mu}m$ (second crushing step), followed by wet magnetic separation (wet magnetic separation step). Using the developed process, a magnetic product containing more than 66 wt.% iron was obtained from the magnetic separation under a magnetic field strength of 0.2 T for the waste copper slag treated by the reduction reaction. At the same conditions, the percentage recovery of iron was over 72%. The iron rich magnetic product obtained should be used as a iron resource for making pig iron.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.26 no.1
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• pp.41-48
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• 2016

It is estimated that over 2 million tons of non-ferrous wastes are generated after refining. Up to now, most researches were focused on extracting precious metals and there were very few research on the utilization of the slag byproduct. In this study, we studied to evaluate whether copper slag could be used as aggregates in concrete. Fresh mortar were evaluated on the particle size and replacement ratio of the copper slag with river-sand. Experimental results indicated that flow, air content and drying shrinkage of concrete varied with particle size, which confirmed that proper classification of copper slag is very important. And, setting time and unit weight of the concrete increased with replacement ratio. When particle size of the slag was similar to the river-sand, concrete with copper slag showed slump, air content, setting time, drying shrinkage and unit weight became larger compared to the concrete using river-sand only. Therefore, it is believed that proper classification and replacement ratio should be optimized for the effective use of slag in concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.317-322
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• 2002

In modern times, the environment preservation is global tendency and self social awareness is arise. Measures to the environment preservation and pollution is going on study. One measure is recycling and reuse of by product and it is already developed in some advanced country. There is 7 hundred thousand tons of copper slag production from copper refining process in domestic. The purpose of this study is reusing copper slag -by product which produced L cooperation in domestic-as fine aggregate for producing high strength concrete and investigating the fundamental characteristics.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.1
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• pp.75-84
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• 2005

The aim of this study is to evaluate the leaching characteristics of lead, copper, cadmium, and mercury from steel making slag by seawater. To demonstrate the leaching characteristics of heavy metals from steel making slag by seawater, it was carried to various leaching tests such as regular leaching tests, liquid/sold(LS) leaching test and pH static test. From the leachability of $Pb^{+2},\;Cu^{+2},\;and\;Cd^{+2}$ from steel making slag in pH static test, it is distinguished between distilled water and seawater. With distilled water, it is very low between pH 7-8 and pH 11-12. On the other hands, with the seawater, its leaching is higher than that of distilled water. In particular, concentration of $Hg^{+2}$ leached from slag by seawater is lower than that of distilled water. Meanwhile, we found that the heavy metals from steel making slag would be dissolved and precipitated using geochemcial equilibrium program such as visual minteq. Lead and copper leached from steel making slag with seawater were dissolved nearly in the range of pH 11-12, but in the range of pH 7-10 those were precipitated about 90%. And cadmium leached from steel making slag with seawater were dissolved completely. On pH static test with distilled water, lead leached from steel making slag seemed to be similar to pH static test with seawater. However, copper and cadmium leached from steel making slag were dissolved. In general, the species of lead leached from steel making slag were formed mainly of $PbCl^+,\;PbSO_4$, the species of copper were formed mainly of $CuSO_4,\;CuCO_3$, the species of cadmium were formed mainly of $CdCl^+,\;CdSO_4$ due to being sorbed with the anions($Cl^-,\;CO_3^{-2},\;SO_4^{-2}$) of the seawater. Both pH static test with seawater and distilled water, it is not in the case of the mercury. Most of mercury leached from steel making slag was precipitated(SI=0). Because the decreasing of $Hg^{+2}$ concentrations depends ferociously on the variation of chloride($Cl^-$) existed in the seawater. $Hg^{+2}$ leached from steel making slag could be sorbed strongly with chloride($Cl^-$) compared of carbonate($CO_3^{-2}$) and sulfate($SO_4^{-2}$) in the seawater. On the basis of that result, we found that the species of mercury was formed of calomel($Hg_2Cl_2$) as one of finite solid. Due to forming a calomel($Hg_2Cl_2$) in the seawater, the stability of mercury species by steel making slag should be higher than those of lead, copper, and cadmium species. Regarding the results stated above, we postulated that the steel making slag could be recycled to sea aggregates due to being distinguishing leachability of heavy metals($Pb^{+2},\;Cu^{+2},\;Cd^{+2},\;and\;Hg^{+2}$) between leaching tests by distilled water and seawater.

• Journal of the Korea Concrete Institute
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• v.15 no.1
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• pp.35-42
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• 2003

To use ferro copper slag as aggregate in the construction, an evaluation upon the two kinds of ferro copper slag being produced was conducted to determine the basic physical, and mechanical properties, chemical component and environmental noxiousness. As a result of experiment, it was found that two kinds of ferro copper slag satisfies the physical and mechanical properties of aggregate, prescribed in KS F 2526, and that in the result of noxious heavy metal eruption test by single bach extraction, no eruption of noxious heavy metal was detected or the eruption was far below the reference value. And mortar test was conducted by replacing sand of 25, 50, 75, 100% and the performance level was presented upon reviewing the fluidity property and variable aspects of unit weight. The increase of strength in accordance with replacement rate of sand was found to be the below than the equivalent level compared to the testing specimens that did not use ferro copper slag, but those of 25% replacement rate was above than 0%. Thus, two kinds of ferro copper slag, produced in the domestic, were found to be possessing the enough physical properties to use as concrete aggregate assuming that used with sand and in particular, it was reviewed to be advantageous in manufacturing concrete or mortar that requires weight.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.345-352
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• 2017

Heavy weight concrete can be used in marine concrete structure to improve resistance against high wave energy. However, heavy weight aggregate, which is an indispensable material for heavy weight concrete, is difficult to be supplied in large quantities because its use is limited due to its high cost. In this work, the applicability of heavy weight by-products, copper and 3 month aged steelmaking slags, were evaluated as sources of heavy weight aggregate for marine concrete structures. Experimental results showed that copper slag was found to be a stable material for marine concrete structure. However, 3 month aged steelmaking slag showed significant expansion by $80^{\circ}$ water immersion test and ASTM C 1260 test. In addition, depth of chloride ion penetration in concrete was higher at which steelmaking slags were located. It was associated with porosity of steelmaking slag, and for this reason, steelmaking slag was not found to be suitable for marine concrete structure.

• Journal of the Mineralogical Society of Korea
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• v.28 no.1
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• pp.17-28
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• 2015

In order to study the mineralogical and chemical characteristics of copper slag, optical microscopy, SEM/EDS, EPMA, AAS and XRD analyses were carried out. In addition, sulfuric acid leaching experiments were performed to investigate the potential of the slag as a copper resource. It was confirmed that fayalite, chromite, bornite and chalcopyrite were contained in the slag. The slag mainly consisted of acicular fayalite and skeletal lath -euhedral chromite crystals. Also a very large amount of bornite and chalcopyrite grains were contained in the slag. The content of Fe and Cu in the slag was 18.37% and 0.93%, respectively. As a result of sulfuric acid leaching experiments, the leaching rates of Cu and Fe were increased through decreasing the slag particle size, increasing the sulfuric acid concentration and the leaching temperature. The maximum efficiency of Cu and Fe leaching were obtained under the conditions of particle size of 32 mesh, sulfuric acid concentration of 2.0 M, and leaching temperature of $60^{\circ}C$. Accordingly, it is expected that the slag could be available as a potential and alternative resource of metallic copper.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.5
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• pp.189-196
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• 2007

The purpose of this study was to analyze steel corrosion resistance of concrete containing copper slag. The specimens were made with normal portland cement and pozzolan materials with various replacement ratio and with W/B ratio ranging from 35% to 55%. Compressive strength, coefficient of chloride diffusion, corrosion area ratio and weight reduction ratio were determinated for the test. The results show that the concrete with pozzolan materials is superior resistant to chloride ions compared to the concrete without pozzolan materials. It was observed that blast furnace slag replacement ratio of 20% gives the best results with respect to chloride ion penetration and corrosion tests and observed that copper slag replacement ratio of 10% gives the seperior resistance compared to normal concrete.

• Resources Recycling
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• v.23 no.1
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• pp.33-39
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• 2014

In this study, the solubility of Cu, which is a main metal component of wasted PCB, in $CaO-SiO_2-Al_2O_3-MgO$ slag system was investigated. Each 20 grams of Cu chips and the quaternary slag manufactured was placed in an carbon crucible and melted for 10 hours in the temperature between 1673 K and 1825 K to confirm the equilibrium state. The oxygen partial pressure was controlled by the ratio of CO and Ar gas in the range of $10^{-17.23}$ to $10^{-15.83}$ atm. The concentration of Cu in the slag increased with increasing oxygen partial pressure, slag basicity, and MgO content in the slag. The concentration of Cu in the slag decreased with increasing temperature. The Cu dissolution reaction in the slag is an exothermic reaction.