• 제목/요약/키워드: copper loss

검색결과 302건 처리시간 0.024초

Vicinal Oxime 리간드의 새로운 구리(II) 착물에 대한 합성, 특성 및 ESR 연구 (Synthesis, Characterization and ESR Studies of New Copper(II) Complexes of Vicinal Oxime Ligands)

  • El-Tabl, Abdou S.;Shakdofa, Mohamad M.E.;El-Seidy, Ahmed M.A.
    • 대한화학회지
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    • 제55권4호
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    • pp.603-611
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    • 2011
  • Ethoxylacetyl oxime 리간드 [HL, (1) 및 $H_2L^1$, (3)]와 아세트산 구리(II) 일수화물을 반응시켜 팔면체 및 사각평면착물을 각각 얻었다. 이들 착물을 원소분석, IR 및 UV-Vis 스펙트럼, 자기수자율, 전기전도도 및 ESR 스펙트럼으로 조사하였다. DMF에서 이들 착물의 몰전기전도도 측정한 결과 비이온성을 보였다. 실온 및 77 K에서 [$(L)_2Cu(H_2O)_2$], (2) 착물의 ESR 스펙트럼은 배위결합성을 갖는 축대칭($d_{x2-y2}$)의 특성을 보이며, 또한 전형적인 쌍극자 상호작용에 의해 큰 띠나비를 갖는다. 그러나 착물 [$(L^1)Cu$], (4)는 고체상태에서 큰 띠넓임으로 인해 초미세 갈라짐이 관찰되지 않았는데, 이는 구리(II) 결합자리들 사이의 스핀-교환 상호작용에 의한 것으로 확인되었다. 실온에서 도포된 구리(II) 착물의 스펙트럼은 배위된 질소원자로 인해 극초미세 갈라짐을 보였다. 또한 이 물질은 공유 결합성을 갖는 축형태($d_{x2-y2}$)의 특성을 보이고, 구리(II) 이온의 환경은 기본적으로 사각-평면 배열을 갖는다. 77 K의 얼어있는 메탄올에서 [$(L_1)Cu$], (4)의 스펙트럼은 이합체 화합물의 삼중항 상태의 특성을 보이며, 두 구리(II) 이온 중심 사이의 거리를 계산한 결과 4.8 이다.

전자폐기물에서 회수된 조금속으로부터 팔라듐 분리를 위한 전해공정에 관한 연구 (A Study on the Electrolytic Process for Palladium Separation from Recovered Crude Metal of Electronic Waste)

  • 박성철;한철웅;김용환;정연재;이만승;손성호
    • 자원리싸이클링
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    • 제30권6호
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    • pp.76-82
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    • 2021
  • 폐 전자폐기물에서 건식정련 및 팔라듐 농축공정으로 제조된 조금속으로부터 팔라듐 분리 및 고순도 동 회수가 가능한 전해공정 연구를 수행하였다. 조금속 내 팔라듐 및 불순금속을 전해분리 시키기 위한 기초 연구로서 각 금속별 산화전위를 평가한 결과 구리, 철 및 니켈은 전해액에 용해되고, 팔라듐 및 알루미늄은 산화물 형태 슬라임 회수가 가능한 것으로 나타났다. 조금속 사용 팔라듐 분리 전해공정 시 팔라듐은 산화물 형태의 슬라임으로 분리되어 97.46 %의 손실이 거의 없는 팔라듐 회수가 가능하였고, 음극에서의 전착층에서는 4N급 구리를 회수하였다.

도전성이 높은 안정화층을 고려한 YBCO 선재의 전송전류 손실 해석 (Analysis of transport current loss considering the conductive layer of YBCO wires)

  • 강명훈;한병욱;정두영;임희현;임형우;차귀수;이희준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.191-193
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    • 2006
  • YBCO wire has a metal substrate to improve the texture structure and highly conductive layers to increase the cryogenic stability. When AC current flows in the YBCO wire, magnetic field which is generated by the AC current magnetizes the metal substrate and induces the eddy current in the stabilizing layer. To examine the effect of the metal substrate and the conducting layer on the transport current loss of YBCO wire, this paper presents the transport current loss of YBCO wire which has metal substrate and conductive layer. YBCO wire with Ni-W substrate and copper layer were chosen as the model HTS wire for numerical calculation. Finite element method has been used to calculate the transport loss and the results of numerical calculation was compared with analytic calculation suggested by Norris.

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적응 FLC-FNN 제어기에 의한 IPMSM의 효율 최적화 제어 (Efficiency Optimization Control of IPMSM with Adaptive FLC-FNN Controller)

  • 최정식;고재섭;정동화
    • 전기학회논문지P
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    • 제56권2호
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    • pp.74-82
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    • 2007
  • Interior permanent magnet synchronous motor(IPMSM) has become a popular choice in electric vehicle applications, due to their excellent power to weight ratio. This paper proposes efficiency optimization control of IPMSM drive using adaptive fuzzy learning control fuzzy neural network (AFLC-FNN) controller. In order to maximize the efficiency in such applications, this paper proposes the optimal control method of the armature current. The controllable electrical loss which consists of the copper loss and the iron loss can be minimized by the optimal control of the armature current. The minimization of loss is possible to realize efficiency optimization control for the proposed IPMSM. The optimal current can be decided according to the operating speed and the load conditions. This paper considers the design and implementation of novel technique of high performance speed control for IPMSM using AFLC-FNN controller. Also, this paper proposes speed control of IPMSM using AFLC-FNN and estimation of speed using ANN controller. The back propagation neural network technique is used to provide a real time adaptive estimation of the motor speed. The proposed control algorithm is applied to IPMSM drive system controlled AFLC-FNN controller, the operating characteristics controlled by efficiency optimization control are examined in detail.

다중 HFC를 이용한 IPMSM 드라이브의 효율 최적화 제어 (Efficiency Optimization Control of IPMSM Drive using multi HFC)

  • 최정식;고재섭;강성준;백정우;장미금;김순영;정동화
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2009년도 추계학술대회 논문집
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    • pp.355-358
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    • 2009
  • This paper proposes efficiency optimization control of IPMSM drive using multi hybrid fuzzy controller(HFC). The design of the speed controller based on fuzzy-neural network that is implemented using fuzzy control and neural network. The design of the current based on HFC using model reference and the estimation of the speed based on neural network using ANN controller. In order to maximize the efficiency in such applications, this paper proposes the optimal control method of the armature current. The controllable electrical loss which consists of the copper loss and the iron loss can be minimized by the optimal control of the armature current. The minimization of loss is possible to realize efficiency optimization control for the proposed IPMSM The optimal current can be decided according to the operating speed and the load conditions. This paper considers the design and implementation of novel technique of high performance speed control for IPMSM using multi HFC. Also, this paper proposes speed control of IPMSM using HFC1, current control of HFC2-HFC3 and estimation of speed using ANN controller. The proposed control algorithm is applied to IPMSM drive system controlled HFC, the operating characteristics controlled by efficiency optimization control are examined in detail.

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고효율 벡터제어 유도전동식 구동 시트템에 관한 연구 (A Study on High Efficiency Vector Controlled Induction Motor Drive System)

  • Kim, Heung-Geun
    • 대한전기학회논문지
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    • 제39권11호
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    • pp.1174-1182
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    • 1990
  • A hgih efficiency and good dynamic performance drive system of an induction motor is presented in this paper using vector control technique. If the induction motor is driven under light loads with rated flux, the iron loss is excessively large compared with the copper loss, resulting in poor motor efficiency. High efficiency drive of an induction motor can be achieved by adjusting the flux level which leads the total motor loss to be a minimum value. Generally reducing the flux degrades the dynamic performance, but the dynamic performance of the proposed system is also maintained high. If the d-axis is coincident with rotor flux phasor in synchronous rotating reference frame, the stator current can be decoupled as flux component and torque component. At steady state, the developed motor torque is proportional to the product of the flux and torque component. The combination of the two components minimizing the motor loss could be found with numerical method. As the procedure to obtain the optimal combination is too hard, it is found experimentally. The system block diagram is suggested for maximum efficiency control. The proposed system is studied through digital simulation and verified with experiment. The experimental results show the possiblity of a high efficiency drive with good dynamic performance of maximum efficiency control.

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COPPER ENHANCEMENT OF L-DOPA-INDUCED OXIDATIVE DNA DAMAGE AND CELL DEATH VIA REDOX CYCLING

  • Lee, Jeong-Sang;Surh, Young-Joan
    • 한국독성학회:학술대회논문집
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    • 한국독성학회 2001년도 International Symposium on Dietary and Medicinal Antimutgens and Anticarcinogens
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    • pp.113-113
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    • 2001
  • Dopamine, a principal neurotransmitter in the central nervous system, accounts for 90% of total catecholamines. It serves as a precursor of certain hormones, melanins, noradrenalin and adrenalin. Parkinsonian disease (PD) is characterized by selective loss of dopaminergic neurons in the substantia nigra pars compacta and a significant dimunution in the neostriatal content of dopamine and its metabolites.(omitted)

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A Study on Dielectric Properties of Printed Circuit Board(PCB) Materials in the Frequency Range of 100MHz to 1Ghz

  • Kim, Jong-Heon;C. Venkataseshaiah;Lee, Joon-Ung
    • Journal of Electrical Engineering and information Science
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    • 제2권5호
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    • pp.40-44
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    • 1997
  • This paper presents the results of studies made for measuring the relative complex permittivity of PCB sheet material in he frequency a range of 100MHz∼1GHz using vector network analyzer. A measurement cell was developed for this purpose using broad-band impedance method and the dielectric constant and loss tangent of two PCBV sheet materials, glass-epoxy and teflon, were measured. The effect of copper cladding was studied.

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인버터구동 선형유도전동기의 특성해석에 관한 연구 (Finite Element Analysis of Inverter-fed Linear Induction Motors)

  • 임달호;김창업;김한종
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 하계학술대회 논문집 A
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    • pp.53-55
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    • 1995
  • This paper presents the characteristics of linear induction motors fed by a voltage source PWM inverter. In the calculation, 2D finite element method is used considering the movement by moving mesh. Integro-differential approach is adopted for the copper loss calculation considering the skin effect.

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Preliminary study on a 3D field permanent magnet flux switching machine - from tubular to rotary configurations

  • Wang, Can-Fei;Shen, Jian-Xin
    • Journal of international Conference on Electrical Machines and Systems
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    • 제1권4호
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    • pp.505-508
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    • 2012
  • A permanent magnet flux switching (PMFS) machine has a simple rotor, whilst both magnets and coils are set in the stator, resulting in easy removal of heat due to both copper loss and eddy current loss in magnets. However, the volume of magnets used in PMFS machines is usually larger than in conventional PM machines, and leakage flux does exist at the non-airgap side. To make full use of the magnets and gain higher power density, a novel 3-dimensional (3D) field PMFS machine is developed. It combines merits of the tubular linear machine, external-rotor rotary machine and axial-flux rotary machine, hence, offers high power density and peak torque capability, as well as efficient utility of magnets owing to the unique configuration of triple airgap fields.