• Title/Summary/Keyword: copper corrosion

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Influence of Polarization Behaviors on the ECM Characteristics of SnPb Solder Alloys in PCB (PCB에서의 ECM 특성에 미치는 SnPb 솔더 합금의 분극거동의 영향)

  • Lee Shin-Bok;Yoo Young-Ran;Jung Ja-Young;Park Young-Bae;Kim Young-Sik;Joo Young-Chang
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.167-174
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    • 2005
  • Smaller size and higher integration of electronic components make smaller gap between metal conducting layers in electronic package. Under harsh environmental conditions (high temperature/humidity), electronic component respond to applied voltages by electrochemically ionization of metal and metal filament formation, which lead to short failure and this phenomenon is termed electrochemical migration(ECM). In this work, printed circuit board(PCB) is used for determination of ECM characteristics. Copper leads of PCB are soldered by eutectic solder alloys. Insulation breakdown time is measured at $85^{\circ}C,\;85{\%}RH$. CAF is the main mechanism of ECM at PCB. Pb is more susceptible to CAF rather than Sn, which corresponds well to the corrosion resistance of solder materials in aqueous environment. Polarization tests in chloride or chloride-free solutions fur pure metal and eutectic solder alloys are performed to understand ECM characteristics. Lifetime results show well defined log-normal distribution which resulted in biased voltage factor(n=2) by voltage scaling. Details on migration mechanism and lifetime statistics will be presented and discussed.

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Development of Remote Reld Testing Technique for Moisture Separator & Reheater Tubes in Nuclear Power Plants (원자력발전소 습분분리재열기 튜브 원격장검사 기술 개발)

  • Nam, Min-Woo;Lee, Hee-Jong;Kim, Cheol-Gi
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.4
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    • pp.339-345
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    • 2008
  • The heat exchanger tube in nuclear power plants is mainly fabricated from nonferromagnetic material such as a copper, titanium, and inconel alloy, but the moisture separator & reheater tube in the turbine system is fabricated from ferromagnetic material such as a carbon steel or ferrite stainless steel which has a good mechanical properties in harsh environments of high pressure and temperature. Especially, the moisture separator & reheater tubes, which use steam as a heat transfer media, typically employ a tubing with integral fins to furnish higher heat transfer rates. The ferromagnetic tube typically shows superior properties in high pressure and temperature environments than a nonferromagnetic material, but can make a trouble during the normal operation of power plants because the ferrous tube has service-induced damage forms including a steam cutting, erosion, mechanical wear, stress corrosion cracking, etc. Therefore, nondestructive examination is periodically performed to evaluate the tube integrity. Now, the remote field testing(RFT) technique is one of the solution for examination of ferromagnetic tube because the conventional eddy current technique typically can not be applied to ferromagnetic tube such as a ferrite stainless steel due to the high electrical permeability of ferrous tube. In this study, we have designed RFT probes, calibration standards, artificial flaw specimen, and probe pusher-puller necessary for field application, and have successfully carry out RFT examination of the moisture separator & reheater tube of nuclear power plants.

Optimal Design of a Coil for Improved Heating Efficiency of Electric Induction Boiler (전기유도보일러의 발열효율개선을 위한 권선최적설계)

  • Kim, Youn-Hyun;Kim, Sol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.476-482
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    • 2019
  • Regulatory protocols such as the Convention on Climate Change and the regulation of greenhouse gas emissions act as catalysts for the development of high-efficiency energy equipment and the efficient use of energy. Among the fields where energy consumption is high, the electric heating equipment is not efficient. The electric boiler mainly uses a method of circulating water by contacting the heater. When the existing electric boiler is used, the water minerals are contacted with the high-temperature heater to be carbonized and adsorbed, thereby promoting the corrosion of the heater and lowering the efficiency of the heater. For this reason, an electric induction boiler, which has high energy efficiency and is applied to an induction heating system that can uniformly heat the object to be heated rather than conduction or convection heating, is in the limelight. This method induces a boiler pipe And it is recognized as an alternative that can solve the problem that occurs when heating is performed by direct heating. Despite the fact that research on induction heating has been conducted for a relatively long period of time, there have been few studies on the electrothermal technology using induction heating. Therefore, in this paper, to improve the heat efficiency of electric induction boiler, the influence of the cross sectional area, number of windings and winding layers is analyzed by finite element method through parametric study method. The method of finding the design point which maximizes the total loss is proposed by the alternating winding design method which can maximize the heat generation by analyzing copper and iron losses.

Jangdo(Small Ornamental Knives) manufacturing process and restoration research using Odong Inlay application (오동상감(烏銅象嵌)기법을 활용한 장도(粧刀)의 제작기술 및 복원연구)

  • Yun, Yong Hyun;Cho, Nam Chul;Jeong, Yeong Sang;Jang, Chu Nam
    • Korean Journal of Heritage: History & Science
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    • v.49 no.2
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    • pp.172-189
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    • 2016
  • In this research, literature research on the Odong material, mixture ratio, casting method and casting facility was conducted on contemporary documents, such as Cheongong Geamul. Also, a long sword was produced using the Odong inlay technique. The sword reproduction steps were as follows; Odong alloying, silver soldering alloying, Odong plate and Silver plate production, hilt and sheath production, metal frame and decorative elements, such as a Dugup (metal frame), production, Odong inlay assembly and final assembly. For the Odong alloy production, the mixture ratio of the true Odong, which has copper and gold ratio of 20:1, was used. This is traditional ratio for high quality product according to $17^{th}$ century metallurgy instruction manual. The silver soldering alloy was produced with silver and brass(Cu 7 : Zn 3) ratio of 5:1 for inlay purpose and 5:2 ratio for simple welding purpose. The true Odong alloy laminated with silver plate was used to produce hilt and sheath. The alloy went through annealing and forging steps to make it into 0.6 mm thick plate and its backing layer, which is a silver plate, had the matching thickness. After the two plates were adhered, the laminated plate went through annealing, forging, engraving, silver inlaying, shaping, silver welding, finishing and polishing steps. During the Odong colouring process, its red surface turns black by induced corrosion and different hues can be achieved depending on its quality. To accomplish the silver inlay Odong techniques, a Hanji saturated with thirty day old urine is wrapped around a hilt and sheath material, then it is left at warm room temperature for two to three hours. The Odong's surface will turn black when silver inlay remains unchanged. Various scientific analysis were conducted to study composition of recreated Odong panel, silver soldering, silver plate and the colouring agent on Odong's surface. The recreated Odong had average out at Cu 95.57 wt% Au 4.16wt% and Cu 98.04 wt% Au 1.95wt%, when documented ratio in the old record is Cu 95wt% and Au 5wt%. The recreated Odong was prone to surface breakage during manufacturing process unlike material made with composition ratio written in the old record. On the silver plate of the silver and Odong laminate, 100wt% Ag was detected and between the two layers Cu, Ag and Au were detected. This proves that the adhesion between the two layers was successfully achieved. The silver soldering had varied composition of Ag depending on the location. This shows uneven composition of the silver welding. A large quantities of S, that was not initially present, was detected on the surface of the black Odong. This indicates that presence of S has influence on Odong colour. Additional study on the chromaticity, additional chemical compounds and its restoration are needed for the further understanding of the origin of Odong colour. The result of Odong alloy testing and recreation, Odong silver inlay long sword production, scientific analysis of the Odong black colouring agent will form an important foundation of knowledge for conservation of Odong artifact.