• 제목/요약/키워드: conversion-oriented

검색결과 80건 처리시간 0.028초

PLD를 이용한 HoMn1-x-FexO3 박막 제조 및 후방 산란형 뫼스바우어 분광 연구 (Characterization and Conversion Electron Mössbauer Spectroscopy of HoMn1-x-FexO3 Thin Films by Pulsed Laser Deposition)

  • 최동혁;심인보;김철성
    • 한국자기학회지
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    • 제17권1호
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    • pp.18-21
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    • 2007
  • Pulsed laser deposition(PLD) 박막 증착법을 이용하여 hexagonal $HoMn_{1-x}-Fe_xO_3$(x=0.0, 0.05) 물질을 박막으로 $Pt/Ti/SiO_2/Si$ 기판 위에 증착하였다. 또한 x-ray diffraction(XRD), atomic force microscopy(AFM), scanning electron microscope(SEM), 및 x-ray photoelectron spectroscopy(XPS)를 통하여 박막의 결정학적 및 미세 구조를 분석하였고, conversion electron $M\"{o}ssbauer$ spectroscopy(CEMS)를 이용하여 자기적 특성에 관해 연구하였다. 결정구조는 hexagonal 구조로써 space group이 $P6_3cm$로 분석되었고, single crystal과는 달리 (110) 방향으로 우선 배향성을 가지고 증착되었다. $HoMn_{0.95}Fe_{0.05}O_3$ 박막의 경우 single crystal과 비교했을 때 hexagonal unit cell의 $c_0$ 축은 일정하나 $a_0$ 축은 다소 감소함으로 분석되었다. 이는 박막 증착에 사용된 $Pt/Ti/SiO_2/Si$ 기판과의 lattice mismatch 때문으로 해석된다. Fe가 미량 치환된 $HoMn_{0.95}Fe_{0.05}O_3$ 박막을 상온에서 CEMS 측정을 수행한 결과, $HoMn_{0.95}^{57}Fe_{0.05}O_3$ 분말의 경우 magnetic $T_N$이 72K 부근이므로, 상온에서 doublet absorption spectrum이 관측되었고, 전기사중극자 분열값(quadrupole splitting; ${\Delta}E_Q$)이 $1.62{\pm}0.01mm/s$로 비교적 큰 값을 가짐을 확인하였다.

NOX 및 NH3 Slip 저감을 위한 Urea-SCR 제어기반 모델 개발 및 검증 (Development and Validation of Urea- SCR Control-Oriented Model for NOX and NH3 Slip Reduction)

  • 이승근;이성욱;강연식
    • 대한기계학회논문집B
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    • 제39권1호
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    • pp.1-9
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    • 2015
  • 디젤 자동차의 점점 강화되는 $NO_X$ 배기가스 규제를 만족하기 위해서는 화학공학 기반의 SCR 반응모델을 사용한 모델기반 제어 알고리즘 개발이 필요하다. 본 연구에서는 소형 경유차량을 대상으로 $NO_X$ 를 저감하기 위한 배기 후처리 시스템 모델을 설계하기 위하여 SCR 시스템 모델링과 Rig 실험 및 Matlab 을 이용하여 시뮬레이션 및 검증을 하였다. SCR Rig 실험은 디젤엔진에서 배출되는 배기가스와 같은 성분의 모사가스를 생성하여 공간속도와 온도의 변화에 의한 SCR 의 $NO_X$ 저감효율에 대한 실험 조건 및 데이터를 획득하였다. 또한, 제안된 모델은 Rig 실험에서 사용한 실험조건과 결과데이터를 이용하여 Matlab 을 통해 검증하였으며 시뮬레이션 시 필요한 모델의 파라미터 값들은 실험데이터를 기반으로 최적화하였다.

Nanotube-based Dye-sensitized Solar Cells

  • Kim, Jae-Yup;Park, Sun-Ha;Choi, Jung-Woo;Shin, Jun-Young;Sung, Yung-Eun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.71-71
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    • 2011
  • Dye-sensitized solar cells (DSCs) have drawn great academic attention due to their potential as low-cost renewable energy sources. DSCs contain a nanostructured TiO2 photoanode, which is a key-component for high conversion efficiency. Particularly, one-dimensional (1-D) nanostructured photoanodes can enhance the electron transport for the efficient collection to the conducting substrate in competition with the recombination processes. This is because photoelectron colletion is determined by trapping/detrapping events along the site of the electron traps (defects, surface states, grain boundaries, and self-trapping). Therefore, 1-D nanostructured photoanodes are advantageous for the fast electron transport due to their desirable features of greatly reduced intercrystalline contacts with specified directionality. In particular, anodic TiO2 nanotube (NT) electrodes recently have been intensively explored owing to their ideal structure for application in DSCs. Besides the enhanced electron transport properties resulted from the 1-D structure, highly ordered and vertically oriented nanostructure of anodic TiO2 NT can contribute additional merits, such as enhanced electrolyte diffusion, better interfacial contact with viscous electrolytes. First, to confirm the advantages of 1-D nanostructured material for the photoelectron collection, we compared the electron transport and charge recombination characteristics between nanoparticle (NP)- and nanorod (NR)-based photoanodes in DSCs by the stepped light-induced transient measurements of photocurrent and voltage (SLIM-PCV). We confirmed that the electron lifetime of the NR-based photoanode was much longer than that of the NP-based photoanode. In addition, highly ordered and vertically oriented TiO2 NT photoanodes were prepared by electrochemical anodization method. We compared the photovoltaic properties of DSCs utilizing TiO2 NT photoanodes prepared by one-step anodization and two-step anodization. And, to reduce the charge recombination rate, energy barrier layer (ZnO, Al2O3)-coated TiO2 NTs also applied in DSC. Furthermore, we applied the TiO2 NT photoanode in DSCs using a viscous electrolyte, i.e., cobalt bipyridyl redox electrolyte, and confirmed that the pore structure of NT array can enhance the performances of this viscous electrolyte.

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Enhanced Light Harvesting by Fast Charge Collection Using the ITO Nanowire Arrays in Solid State Dye-sensitized Solar Cells

  • Han, Gill Sang;Yu, Jin Sun;Jung, Hyun Suk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.463-463
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    • 2014
  • Dye-sensitized solar cells (DSSCs) have generated a strong interest in the development of solid-state devices owing to their low cost and simple preparation procedures. Effort has been devoted to the study of electrolytes that allow light-to-electrical power conversion for DSSC applications. Several attempts have been made to substitute the liquid electrolyte in the original solar cells by using (2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9-9'-spirobi-fluorene (spiro-OMeTAD) that act as hole conductor [1]. Although efficiencies above 3% have been reached by several groups, here the major challenging is limited photoelectrode thickness ($2{\mu}m$), which is very low due to electron diffusion length (Ln) for spiro-OMeTAD ($4.4{\mu}m$) [2]. In principle, the $TiO_2$ layer can be thicker than had been thought previously. This has important implications for the design of high-efficiency solid-state DSSCs. In the present study, we have fabricated 3-D Transparent Conducting Oxide (TCO) by growing tin-doped indium oxide (ITO) nanowire (NWs) arrays via a vapor transport method [3] and mesoporous $TiO_2$ nanoparticle (NP)-based photoelectrodes were prepared using doctor blade method. Finally optimized light-harvesting solid-state DSSCs is made using 3-D TCO where electron life time is controlled the recombination rate through fast charge collection and also ITO NWs length can be controlled in the range of over $2{\mu}m$ and has been characterized using field emission scanning electron microscopy (FE-SEM). Structural analyses by high-resolution transmission electron microscopy (HRTEM) and X-Ray diffraction (XRD) results reveal that the ITO NWs formed single crystal oriented [100] direction. Also to compare the charge collection properties of conventional NPs based solid-state DSSCs with ITO NWs based solid-state DSSCs, we have studied intensity modulated photovoltage spectroscopy (IMVS), intensity modulated photocurrent spectroscopy (IMPS) and transient open circuit voltages. As a result, above $4{\mu}m$ thick ITO NWs based photoelectrodes with Z907 dye shown the best performing device, exhibiting a short-circuit current density of 7.21 mA cm-2 under simulated solar emission of 100 mW cm-2 associated with an overall power conversion efficiency of 2.80 %. Finally, we achieved the efficiency of 7.5% by applying a CH3NH3PbI3 perovskite sensitizer.

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현대 직물디자인에 나타난 절충주의적 경향과 특징 (Eclectic Trends and Characteristics in Modern Textile Design)

  • 박남성
    • 디자인학연구
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    • 제19권1호
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    • pp.303-316
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    • 2006
  • 새로운 미의식의 창조를 위해 이질적이고 대립적인 요소를 융합 혼합하는 절충주의는 다양성, 다원화에 기초하므로서 개성화, 다양화를 추구하는 현대인의 요구에 부합되어 각광 받고 있다. 본 연구는 현대직물디자인에 표현된 절충주의 양식을 파악하기 위하여 현대예술분야를 통해 그 특성을 규명하고 이를 직물디자인에 적용시켜 새로운 경향이 제시한 미적 효과와 조형적 특성을 고찰하므로서 현대직물디자인의 변화양상을 이해하고자 하였다. 연구결과 현대 직물디자인에 나타난 경향은 다음의 3개로 구별되는데, 1) 문화적 절충에 의한 고급문화와 저급문화의 복합, 2) 시대적 절충에 의한 다양한 시대적 감각의 융합, 3) 지역적 절충에 의한 지역적 특성의 혼합으로 나타나며, 이러한 경향으로 본 직물디자인의 특징은 1) 직물디자인에 대한 시각의 전환을 가져왔고, 2) 유희적 표현을 중시하였으며 3) 다문화적 표현이 강조되고 있다. 이와 같이 직물디자인의 절충주의적 경향은 다변화되고 있는 현대 사회를 대변해주고 미래 직물디자인을 위한 하나의 가능성을 제시하여 주므로서 이에 대한 연구는 지속적으로 필요하다.

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위성링크를 위한 LAN 접속 서비스 설계과 운영 (Design and Operation of LAN Interconnection Service for Satellite Links)

  • 김정호;최경수
    • 한국정보처리학회논문지
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    • 제3권4호
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    • pp.961-968
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    • 1996
  • 무궁화 위성 과제 중에서는 지구국 시스템에서 위성 링크를 통한 LAN 상호간의 접속을 제공하기 위한 시범위성 네트워크 모듈의 구현을 수행하였다. 이 시범 네트워 크는 위성을 통하여 다양한 응용들에 대한 수행을 검증하기 위한 시험을 지원할 수있 다.본 논문에서는 위성 전송시의 장단점을 고려하여 충분히 응용할 수 있는 위성-LAN 접속 구조를 제안하였다. 본 네트워크 구조는 두개의 노드에서 복수의 논리 접속을 수행하는 연결 중심형인 위성 프로토콜을 사용함으로서 높은 데이타 전송과 위성 접속 에러율에 대한 높은 성능을 제공한다. 또한, 프로토콜 변환 방법에 따라 라우터 접속을 수행할수 있다. 위성과 네트워크 접속의 구조는 4W 고출력 증폭기가 장착된 1.8m의 안테나, 위성통신용 모뎀, 위성 네트워크 접속 장치가 설계되었다. 이 시스 템은 최대 1.544 Mbps의 전송 속도를 자원할수 있으며 네트워크 관리면에서도 우수 하게 동작하였다.

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질산염 전구체 원료로 Ex-situ 공정에 의한 GdBCO 박막 제조 (Preparation of GdBCO Thin Film by Ex-situ Process using Nitrate Precursors)

  • 김병주;이철선;이종범;이재훈;문승현;이희균;홍계원
    • Progress in Superconductivity
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    • 제13권2호
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    • pp.127-132
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    • 2011
  • Many research groups have been manufacturing coated conductor by various processes such as PLD, MOD, and MOCVD, but the methods with production cost suitable for wide and massive application of coated conductor did not develop yet. Spray pyrolysis method adopting ultrasonic atomization was tried as one of the possible option. GdBCO precursor films have been deposited on IBAD substrate by spray pyrolysis method at low temperature and converted to GdBCO by post heat treatment. Ultrasonic atomization was used to generate fine droplets from precursor solution of Gd, Ba, and Cu nitrate dissolved in water. Primary GdBCO films were deposited at $500^{\circ}C$ and oxygen partial pressure of 1 torr. After that, the films were converted at various temperatures and low oxygen partial pressures. C-Axis oriented films were obtained IBAD substrates at conversion temperature of around $870^{\circ}C$ and oxygen partial pressures of 500 mtorr ~ 1 torr in a vacuum. Thick c-axis epitaxial film with the thickness of 0.4 ~ 0.5 ${\mu}m$ was obtained on IBAD substrate. C-axis epitaxial GdBCO films were successfully prepared by ex-situ methods using nitrate precursors on IBAD metal substrate. Converted GdBCO films have very dense microstructures with good grain connectivity. EDS composition analysis of the film showed a number of Cu-rich phase in surface. The precursor solution having high copper concent with the composition of Gd : Ba : Cu = 1 : 2 : 4 showed the better grain connectivity and electrical conductivity.

영상미디어 아트 공간연출 표현특성에 관한 연구 - 미술 전시장을 중심으로 - (A Study on the Characteristics of Space Production for Art Museums Reflex Media Art)

  • 유재엽
    • 한국실내디자인학회:학술대회논문집
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    • 한국실내디자인학회 2004년도 춘계학술발표대회 논문집
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    • pp.156-160
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    • 2004
  • Our time is called as the era of information-oriented society and up-to-date scientific technology, but it can be also called as the era of image. It is because the image has much influence upon our everyday life. In the deluge of images, the delivery of image Is a better and faster synergic tool than the delivery of language, and this trend is consistent with the phases of the times in which the analog modality of synergy is converted into the digital one. The image is a picture that is formed by a physical process, and is all the figures reflected by electronic equipments that reproduce the image. After the discovery of photograph in 1893, the image has been appeared first with the form of movie, and then with the form of TV. However, the appearance of such unidirectional synergic tools as movies and TV. has provided artists with some creative motives with which they intercommunicate their messages via some experimental bidirectional synergic tools. Among image-media arts, the performance of installation and participation is an important example that causes many changes through conceptional conversion, such as the conception of the time in space and formative characteristics. What satisfy this trend have been videos, lasers, holographic, and etc. Furthermore, the appearance of computer has provided a synesthesia, that is, a virtual reality, and mixed a real image with a visional one. The image-media art will realize better synergy through combining brand new machines, informational technology, and art, and have much influence upon our everyday life formatively and artistically in the future. with this study, through analyzing the meaning of relationship between image equipments and space.

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DBS 수신을 위한 Dual Phase LNB 설계 (The Design of Dual Phase LNB for DBS Receiving)

  • 임윤두;고봉진
    • 한국항행학회논문지
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    • 제6권3호
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    • pp.188-194
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    • 2002
  • DBS(Direct Broadcasting Satellite)는 광범위한 주사영역과 고품질의 서비스를 제공하므로 정보화 사회에서 매우 유용한 매체로 활용되고 있으며 이동체에서도 위성 방송을 수신할 수 있는 기술을 필요로 한다. 본 논문에서는 한반도 연근해를 항해구역으로 하는 선박과 육상 이동체에서 DBS 수신이 가능한 trracking antenna용 Dual phase LNB를 설계하였다. 설계한 Dual phase LNB는 저잡음 증폭기 대역통과 필터 발진기, 혼합기, 중간주파 증폭기로 구성하였고 위치 추적을 위해 각각 두 입 출력 위상을 동위상으로 구현하였다. 측정 결과, 11.7 GHz~12.2 GHz의 입력신호에 대하여 잡음지수는 0.87 dBmax, 변환이득 62 dB이고, 온도특성은 $-30^{\circ}C{\sim}60^{\circ}C$에서 ${\pm}400$ kHz이고 위상잡음은 100 kHz 옵셋에서 -101 dBc/Hz로서 우수한 성능을 나타내었다.

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소비자보호를 위한 기업마아켓팅의 방향에 관한 연구 (A Study on Manufacture's Marketing for Consumer Protection)

  • 김순미
    • 대한가정학회지
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    • 제18권4호
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    • pp.75-85
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    • 1980
  • The consumer affair is one of the rapidly evolving problems in the process of recent economic growth. As the society and its economy changes, the nature and the scope of the consumer affairs also changes. while the main concept of the consumer affaires originated from the market mechanism, it is now expanding beyond the market mechanism to include everyday lives of consumers. In solving the problems which arise form the status difference between the manufacturer and the consumer the manufacturer's action is no less important the consumer's self-improvement of its status. The manufactures with the purpose of getting maximum profits from the consumers are conducting the consumer oriented managerial marketing, but this sis done form the manufacturer's point of view with the consumer's position being neglected. It is the purpose of this paper to investigate the nature and direction of the marketing from the consumer's position being neglected. It is the purpose of this paper to investigate the nature and direction of the marketing from the consumer's point of view. For this study a couple of pre-investigations were done. First, I surveyed the changing consumers with economic growth the developing process of marketing, and the cause and characteristics of the today's consumer affaires. Second, I studied the concept change of the modern marketing, and the concept of the consumerism which was materialized by this concept change. I further studied, with the consumer's point of view, the socioecological marketing which is based on the consumerism. The conclusion of this investigation is that the manufacturers should convert the in humanized marketing to the more human and environment conscious socioecological marketing because the consumer affairs which arise from the mass consumption of the modern days are expanding to include everyday's problems. This conversion naturally should be based on the human concept based consumerism. To be more effective, the manufactures should assume more social responsibilities and conduct the socioecological marketing voluntarily and willingly.

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