• Title/Summary/Keyword: conversion ability

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Xanthate-Mediated Controlled Radical Polymerizations of N-Vinylcarbazole and Synthesis of Star Polymers

  • Mori, Hideharu;Ookuma, Hiroshi;Endo, Takeshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.322-322
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    • 2006
  • Well-defined poly(N-vinylcarbazole), poly(NVC), was synthesized by macromolecular design via interchange of the xanthate (MADIX)/reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of a suitable xanthate-type chain transfer agent (CTA). Good control of the polymerization was confirmed by the linear first-order kinetic plot, the molecular weight controlled by the monomer/CTA molar ratio, linear increase in the molecular weight with the conversion, and the ability to extend the chains by the second addition of the monomer. Star polymers having various architectures were also synthesized using this technique.

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$CO_2$ Evolution in Peroxisomes Isolated from Spinach Leaves at Various Ages (시금치 잎의 엽영에 따라 분리한 Peroxisome에서의$CO_2$방출)

  • 이순희
    • Journal of Plant Biology
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    • v.31 no.3
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    • pp.197-203
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    • 1988
  • The rates of photorespiration and total CO2 fixation depending on leaf ages of spinach (Spinacia oleracea L.) were investigated. Metabolic rates of glycolate and glyoxylate in isolated peroxisomes were also measured. The rate of photorespiration and total CO2 fixation ability increased with the maturing of leaf, but decreased with senescence. Activities of enzymes involved in the peroxisomal photorespiratory pathway such as catalase, glycolate oxidase, NADH-glyoxylate reductase and glutamate-glyoxylate transaminase were highest in the mature leaf, but also decreased with aging of leaf. Glutamate-glyxolate transaminase activity significantly decreased with senescence, especially. the metabolic rate of glycolate was observed to be lower than that of glyoxylate in isolated peroxisomes. Glycolate seemed to be metabolized mainly to glycine, however, it also oxidized to CO2 when glycolate was supplied as a substrate for glycine synthesis instead of glyoxylate. The conversion rates of glycolate and glyxylate into CO2 increased with the senescence of leaves.

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Digital-Controlled Single-Phase Unified Power Quality Conditioner for Non-linear and Voltage Sensitive Loads

  • Ryoo Hong-Je;Kim Jong-Soo;Kisck Dragos Ovidiu
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.5B no.4
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    • pp.374-381
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    • 2005
  • The ability to provide quality power has become a significant issue in power systems. The main causes of poor power quality are harmonic currents, poor power factor, supply-voltage variations, etc. A technique of achieving both active current distortion compensation, power factor correction and also mitigating the supply-voltage variation (sag or swell) at the load side is presented in this paper. The operation and rating issues of the proposed Single-phase Unified Power Quality Conditioner are also highlighted. To reduce the total cost while simultaneously increasing the performance, the system is fully digitally controlled using the fixed-point TMS320F240 digital signal processor. The performances of the UPQC, which is composed by shunt and series PWM controlled-converters, have been verified on a laboratory prototype.

MO Theoretical Studies on Antitumor Activity of Purine Antimetabolites (퓨린 港代謝物의 抗癌活性에 관한 MO 이론적 연구)

  • Kim Ho Soon;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.239-243
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    • 1983
  • EHMO calculations were performed on several antitumor active as well as inactive purine antimetabolites. Results showed that the N atom (position 9) which corresponds to the position of sugar (position 10) linkage in DNA bases has a net negative charge for antitumor active whereas it has a positive charge for inactive purines. It was also found that overlap population was the smallest for bond between atoms 9 and 10, which agrees with the experimental findings that antitumor activity is effected after conversion to nucleotide level.

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A Study of AC-DC PWM Full-Bridge Integrated Converter Topologies

  • Gerry, Moschopoulos;Praveen Jain
    • Journal of Power Electronics
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    • v.1 no.2
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    • pp.107-116
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    • 2001
  • Two AC-DC PWM full-bridge converters that can input current to improve input power factor while performing dc-dc conversion are investigated in this paper. Both converters are simple in that they are similar to the standard PWM full-bridge converter with a diode rectifier/LC low-pass filter input, and both can operate with a simple method of PWM control. In the paper, the operation of the converters is explained and their steady-state characteristics are discussed. The feasibility of the converters and their ability to meet EN61000-3-2 Class D Standards for electrical equipment are shown with results obtained from experimental prototypes. The performance of both converters in terms of dc bus voltage level, input power factor and efficiency is compared and discussed.

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Quantification of Crystallinity Change in Celluloses during Refining

  • Kim, Chul-Hwan;Yang, Jae-Kyung;Park, Jong-Yawl
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.5
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    • pp.8-13
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    • 2000
  • X-ray diffraction technique was used to quantify change of cellulose crystallinity during refining. XRD data confirmed that fiber wall delamination was caused by the structural conversion of celluloses which occurred in a liquid medium during refining. The quantified crystallinity of celluloses in pulp fibers was closely associated with the change of fiber wall delamination, which was defined by measurement of fiber wall thickness. In particular, it was well recognized that low intensity beating showed a better response in the change of crystallinity than high intensity one. The decrease o cellulose crystallinity during refining considerably enhanced the improvement of interfiber bonding ability of a dried sheet.

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Photophysical Properties of Khellin-Dimethylfumarate C$_4$-Cyclomonoadduct

  • Shim, Sang-Chul;Kang, Ho-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.7 no.6
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    • pp.458-461
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    • 1986
  • The fluorescence intensity of khellin-dimethylfumarate C$_4$-cycloadduct (KDF) is very sensitive to temperature and to the nature of solvents, especially hydrogen-bonding ability. The fluorescence quantum yields of KDF in ethanol and isopentane at 77K are 0.73 and 0.54, respectively, both of which are much larger than the room temperature values. The phosphorescence lifetime is very long and decreases with decreasing the solvent polarity. The phosphorescence and fluorescence quantum yield ratio is very small and decreases with decreasing solvent polarity. The solvent relaxation plays an important role in the excited states of KDF. The internal conversion is a major decay process of the excited singlet state of KDF in all the solvents used at room temperature.

The Flexible Application of Real Options for Subcontractor in the Soft Drink Manufacturing Industry

  • Kume, Katsunori;Fujiwara, Takao
    • Asian Journal of Innovation and Policy
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    • v.7 no.3
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    • pp.581-605
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    • 2018
  • In the soft drink industry, especially small and medium enterprises in Japan, there is a possibility of conversion from a labor-intensive industry to a capital-intensive. The demand for soft drinks may not be satisfied in the summer because the supply is too low to meet the demand. To address this situation, this paper proposes optimal investment that integrates demand uncertainty, based on real options approach (ROA) and seasonal autoregressive integrated moving average. Two alternative options are compared and evaluated. One is the Bermudan option: to employ additional workers to elevate efficiency in summer and laying off in winter, this attitude is repeated each year. The other is the American option: to replace equipment to increase machine ability throughout the year. Results in ROA show that the highest improvement is gained if the two options are in a symbiotic relationship. Soft drink producers should search for replacing equipment, using the employees repeatedly. A temporary decision is not equal to an infinite decision.

Photophysical properties of Khellin

  • Shim, Sang-Chul;Kang, Ho-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.8 no.4
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    • pp.341-344
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    • 1987
  • The fluorescence quantum yield of khellin is sensitive to temperature and to the nature of solvents, especially the proton-donating ability in solute-to-solvent hydrogen bonding. The intersystem crossing quantum yields are 0.4 and 0.15 in acetonitrile and ethanol, respectively. The fluorescence quantum yields in ethanol and isopentane at 77 K are 0.61 and 0.07, respectively, both of which are much larger than the values at room temperature. The phosphorescence lifetime is relatively long and decreases with decreasing solvent polarity. The phosphorescence to fluorescence quantum yield ratio is very small and remains unchanged in various solvents. The results suggest that internal conversion is an important decay channel of the excited singlet state of khellin, especially in the hydrogen-bonding hydroxyl solvents.

Drying Techniques of Microalgal Biomass: A Review

  • Kim, Gyu Min;Kim, Young-Kee
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.145-150
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    • 2022
  • Microalgae are attracting attention as a resource for the production of biofuels, food nutrients, biochemicals, and bioplastics. Among a wide range of sources of the biomass, microalgae have been highlighted due to relatively easy cultivation, ability to eliminate carbon dioxide, and low culturing cost. Despite the great potential of microalgal biomass as a biological material, the complexity and relatively expensive downstream processes have inhibited the commercial use of microalgae. In this study, we reviewed recent techniques for microalgal drying for the production of microalgal based products. As drying processes comprise the largest portion of microalgae processing cost, an efficient drying technique is key to the utilization of microalgal biomass.