• Title/Summary/Keyword: convergence properties

Search Result 1,908, Processing Time 0.031 seconds

A Study on Oxygen Reduction Reaction of PtM Electrocatalysts Synthesized on Graphene for Proton Exchange Membrane Fuel Cell (고분자전해질연료전지를 위한 그래핀 기반 PtM 촉매들의 산소환원반응성 연구)

  • Yang, Jongwon;Choi, Changkun;Joh, Han-Ik;Park, Jong Jin;Kwon, Yongchai
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.25 no.4
    • /
    • pp.378-385
    • /
    • 2014
  • In this research, we investigate electrical performance and electrochemical properties of graphene supported Pt (Pt/G) and PtM (M = Ni and Y) alloy catalysts (PtM/Gs) that are synthesized by modified polyol method. With the PtM/Gs that are adopted for oxygen reduction reaction (ORR) as cathode of proton exchange membrane fuel cells (PEMFCs), their catalytic activity and ORR performance and electrical performance are estimated and compared with one another. Their particle size, particle distribution and electrochemically active surface (EAS) area are measured by TEM and cyclic voltammetry (CV), respectively. On the other hand, regarding ORR activity and electrical performance of the catalysts, (i) linear sweeping voltammetry by rotating disk electrode and rotating ring-disk electrode and (ii) PEMFC single cell tests are used. The TEM and CV measurements demonstrate particle size and EAS of PtM/Gs are compatible with those of Pt/G. In case of PtNi/G, its half-wave potential, kinetic current density, transferred electron number per oxygen molecule and $H_2O_2$ production % are excellent. Based on data obtained by half-cell test, when PEMFC singlecell tests are carried out, current density measured at 0.6V and maximum power density of the PEMFC single cell employing PtNi/G are better than those employing Pt/G. Conclusively, PtNi/Gs synthesized by modified polyol shows better ORR catalytic activity and PEMFC performance than other catalysts.

Static Aeroelastic Analysis for Aircraft Wings using CFD/CST Coupling Methodology (전산유체/전산구조 연계 방법을 사용한 항공기날개의 정적 공탄성 해석)

  • Choi, Dong-Soo;Jun, Sang-Ook;Kim, Byung-Kon;Park, Soo-Hyun;Lee, Dong-Ho;Lee, Kyung-Tae;Jun, Seung-Moon;Cho, Maeng-Hyo
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.35 no.4
    • /
    • pp.287-294
    • /
    • 2007
  • A static aeroelastic analysis for supersonic aircraft wing equipped with external store under the wing lower surface is performed using computational fluid dynamics (CFD) and computational structural technology(CST) coupling methodology. Two mapping algorithms, which are the pressure mapping algorithm and the displacement mapping algorithm, are used for CFD/CST coupling. A three-dimensional unstructured Euler code and finite element analysis program are used to calculate the flow properties and the structural displacements, respectively. The coupling procedure is repeated in an iterative manner until a specified convergence criterion is satisfied. Static aeroelastic analysis for a typical supersonic flight wing is performed and final converged wing configuration is obtained after several iterations.

The behavior of collagen-like molecules in response to different temperature setting methods in steered molecular dynamic simulation (다른 온도 조절 상태에서 분자 동역학에서 콜라겐 단백질의 거동)

  • Yoon, Young-June;Cho, Kang-Hee;Han, Seog-Young
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
    • /
    • v.13 no.5
    • /
    • pp.397-402
    • /
    • 2020
  • Collagen type I is the most abundant protein in the human body. It shows viscoelastic behavior, which is what confers tendons with their viscoelastic properties. There are two different temperature setting methods in molecular dynamics simulations, namely rescaling and reassignment. The rescaling method maintains the temperature by scaling the given temperature, while the reassignment method sets the temperature according to a Maxwell distribution at the target temperature. We observed time-dependent behavior when the reassignment method was applied in tensile simulation, but not when the rescaling method was applied. Time-dependent behavior was observed only when the reassignment method was applied or when one side of the collagen molecule was stretched to a greater extent than the other side. As result, the collagen is elongated to 80nm, 100nm, 130nm, and 180nm, respectively, when the collagen is pulled by different velocities, 0.5, 1, 2, and 5 Å/ps, up to 40 Å. The results do not provide a detailed physical explanation, but the phenomena illustrated in this result are important for caution when further simulations are performed.

A Study on the Landscape Attractions Evaluative Systems of Gyeongju Historic Heritage Sites (경주 역사유적지구 매력성 평가지표 개발 연구)

  • Kang, Tai-Ho;Yu, Wen-Dong
    • Journal of the Korean Institute of Landscape Architecture
    • /
    • v.42 no.6
    • /
    • pp.31-38
    • /
    • 2014
  • This study is an evaluation index development research based on the Gyeongju Historic Heritage Sites to identify the attractive properties of Gyeongju that have helped determine the competitiveness of this historical city. Through literature reviews on these attractive factors of historic urban landscape, the Vienna memos(UNESCO, 2005) and the International Cultural Tourism Charter(ICOMOS, 1999), two professional investigations were conducted following a backup group of attraction indexes that had been received prior. In the end, 22 attraction indexes were chosen in the Urban Historical and Cultural area, the Heritage Resources area, and the Urban Environment area with three aspects based on the analysis of Importance(M), Standard deviation(SD), Content Validity Ratio(CVR), Agreement, and convergence. These indicators will be useful basic information for improving the city's historic charms. In the future, these indicators can be used as a basis for evaluating the characteristic charms of Gyeongju, through which the charm of Gyeongju can be re-recognized.

Independent Component Analysis Based on Neural Networks Using Hybrid Fixed-Point Algorithm (조합형 고정점 알고리즘에 의한 신경망 기반 독립성분분석)

  • Cho, Yong-Hyun
    • The KIPS Transactions:PartB
    • /
    • v.9B no.5
    • /
    • pp.643-652
    • /
    • 2002
  • This paper proposes an efficient hybrid fixed-point (FP) algorithm for improving performances of the independent component analysis (ICA) based on neural networks. The proposed algorithm is the FP algorithm based on secant method and momentum for ICA. Secant method is applied to improve the separation performance by simplifying the computation process for estimating the root of objective function, which is to minimize the mutual informations of the independent components. The momentum is applied for high-speed convergence by restraining the oscillation if the process of converging to the optimal solution. It can simultaneously achieve a superior properties of the secant method and the momentum. The proposed algorithm has been applied to the composite fingerprints and the images generated by random mixing matrix in the 8 fingerprints of $256\times{256}$-pixel and the 10 images of $512\times{512}$-pixel, respectively. The simulation results show that the proposed algorithm has better performances of the separation speed and rate than those using the FP algorithm based on Newton and secant method. Especially, the secant FP algorithm can be solved the separating performances depending on initial points settings and the nonrealistic learning time for separating the large size images by using the Newton FP algorithm.

The Effects of Precursor on the Formation and Their Properties of Spin-on Dielectric Films Used for Sub-50 nm Technology and Beyond (50 nm 이상의 CMOS 기술에 이용되는 Spin-on Dielectric 박막 형성과 그 특성에 미치는 전구체의 영향)

  • Lee, Wan-Gyu
    • Journal of the Korean Vacuum Society
    • /
    • v.20 no.3
    • /
    • pp.182-188
    • /
    • 2011
  • Polysilazane and polymethylsilazane based precursor films were deposited on Si-substrate by spin-coating, subsequently annealed at $150{\sim}850^{\circ}C$, and characterized. Structural analysis, shrink, compositional change, etch rate, and gap-filling were observed. Annealing the precursor films led to formation of spin-on dielectric films. C-containing precursor films showed that less loss of N, H, and C while less gain of O than that of C-free precursor films at $400^{\circ}C$, but more loss of N, H, and C while more gain of O at $850^{\circ}C$. Thus polysilazane based precursor films exhibited less reduction in thickness of 14.5% than silazane based one of 15.6% at $400^{\circ}C$ but more 37.4% than 19.4% at $850^{\circ}C$. FTIR indicated that C induced smaller amount of Si-O bond, non-uniform property, and lower resistance to chemical etching.

Improvement of the Figure of Merit in Pb[(Mg1/3Ta2/3)0.7Ti0.3]O3 Systems

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
    • /
    • v.25 no.5
    • /
    • pp.88-91
    • /
    • 2016
  • The $Pb[(Mg_{1/3}Ta_{2/3})_{0.7}Ti_{0.3}]O_3$+xwt%PbO systems at temperature of $1250^{\circ}C$ for 4 hours was successful synthesized. In this study, PbO-doped $Pb[(Mg_{1/3}Ta_{2/3})_{0.7}Ti_{0.3}]O_3$ systems with non-linear behaviors showed ordering-degree dependence at the low temperature range were prepared using the columbite precursor method. And the characteristic of remnant polarization vs. electric field were analyzed. The pyroelectric, dielectric and piezoelectric properties of partially disordered $Pb[(Mg_{1/3}Ta_{2/3})_{0.7}Ti_{0.3}]O_3$+xwt%PbO solid solutions were studied as a function of temperature, frequency, and electric field. It showed distinct features of temperature dependent of pyroelectric coefficient, spontaneous polarization and dielectric constant at about $50^{\circ}C$. The figure of merit was calculated as pyroelectric coefficient, dielectric constant and dissipation factor. It was found that the high voltage responsivity FV, high detectivity FD were $0.0373m^2/C$ and $0.6735{\times}10^{-4}Pa{-1/2}$, respectively, in the $Pb[(Mg_{1/3}Ta_{2/3})_{0.7}Ti_{0.3}]O_3$+3.0 wt%PbO system.

Stimulated Emission with 349-nm Wavelength in GaN/AlGaN MQWs by Optical Pumping

  • Kim, Sung-Bock;Bae, Sung-Bum;Ko, Young-Ho;Kim, Dong Churl;Nam, Eun-Soo
    • Applied Science and Convergence Technology
    • /
    • v.26 no.4
    • /
    • pp.79-85
    • /
    • 2017
  • The crack-free AlGaN template has been successfully grown by using selective area growth with triangular GaN facet. The triangular GaN stripe structure was obtained by vertical growth rate enhanced mode with low growth temperature of $950^{\circ}C$ and high growth pressure of 500 torr. The lateral growth rate enhanced mode of AlGaN for crack-free and flat surface was also investigated. Low pressure of 30 torr and high V/III ratio of 4400 were favorable for lateral growth of AlGaN. It was confirmed that the $4{\mu}m$ -thick $Al_{0.2}Ga_{0.8}N$ was crack-free over entire 2-inch wafer. The dislocation density of $Al_{0.2}Ga_{0.8}N$ was as low as ${\sim}7.6{\times}10^8/cm^2$ measured by cathodoluminescence. Based on the high quality AlGaN with low dislocation density, the ultraviolet laser diode epitaxy with cladding, waveguide and GaN/AlGaN multiple quantum well (MQW) was grown by metalorganic chemical vapor deposition. The stimulated emission at 349 nm with full width at half maximum of 1.8 nm from the MQW was observed through optical pumping experiment with 193 nm KrF laser. We also have fabricated the deep ridge type ultraviolet laser diode (UV-LD) with $5{\mu}m-wide$ and $700{\mu}m-long$ cavity for electrical properties. The turn on voltage was below 5 V and the resistance was ${\sim}55{\Omega}$ at applied voltage of 10 V. The amplified spontaneous emission spectrum of UV-LD was also observed from pulsed current injection.

Fine Registration between Very High Resolution Satellite Images Using Registration Noise Distribution (등록오차 분포특성을 이용한 고해상도 위성영상 간 정밀 등록)

  • Han, Youkyung
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
    • /
    • v.35 no.3
    • /
    • pp.125-132
    • /
    • 2017
  • Even after applying an image registration, Very High Resolution (VHR) multi-temporal images acquired from different optical satellite sensors such as IKONOS, QuickBird, and Kompsat-2 show a local misalignment due to dissimilarities in sensor properties and acquisition conditions. As the local misalignment, also referred to as Registration Noise (RN), is likely to have a negative impact on multi-temporal information extraction, detecting and reducing the RN can improve the multi-temporal image processing performance. In this paper, an approach to fine registration between VHR multi-temporal images by considering local distribution of RN is proposed. Since the dominant RN mainly exists along boundaries of objects, we use edge information in high frequency regions to identify it. In order to validate the proposed approach, datasets are built from VHR multi-temporal images acquired by optical satellite sensors. Both qualitative and quantitative assessments confirm the effectiveness of the proposed RN-based fine registration approach compared to the manual registration.

Vibration analysis of FG porous rectangular plates reinforced by graphene platelets

  • Zhou, Changlin;Zhang, Zhongxian;Zhang, Ji;Fang, Yuan;Tahouneh, Vahid
    • Steel and Composite Structures
    • /
    • v.34 no.2
    • /
    • pp.215-226
    • /
    • 2020
  • The aim of this study is to investigate free vibration of functionally graded porous nanocomposite rectangular plates where the internal pores and graphene platelets (GPLs) are distributed in the matrix either uniformly or non-uniformly according to three different patterns. The elastic properties of the nanocomposite are obtained by employing Halpin-Tsai micromechanics model. The GPL-reinforced plate is modeled using a semi-analytic approach composed of generalized differential quadrature method (GDQM) and series solution adopted to solve the equations of motion. The proposed rectangular plates have two opposite edges simply supported, while all possible combinations of free, simply supported and clamped boundary conditions are applied to the other two edges. The 2-D differential quadrature method as an efficient and accurate numerical tool is used to discretize the governing equations and to implement the boundary conditions. The convergence of the method is demonstrated and to validate the results, comparisons are made between the present results and those reported by well-known references for special cases treated before, have confirmed accuracy and efficiency of the present approach. New results reveal the importance of porosity coefficient, porosity distribution, graphene platelets (GPLs) distribution, geometrical and boundary conditions on vibration behavior of porous nanocomposite plates. It is observed that the maximum vibration frequency obtained in the case of symmetric porosity and GPL distribution, while the minimum vibration frequency is obtained using uniform porosity distribution.