• 제목/요약/키워드: controlled synthesis

검색결과 625건 처리시간 0.028초

응답형 음성제어 전동 휠체어(INMEL-1)의 설계 (Design of the Motorized Wheel Chair(INMEL-1) Controlled by Response Type Voices)

  • 정동명;홍승홍
    • 대한의용생체공학회:의공학회지
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    • 제8권2호
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    • pp.231-240
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    • 1987
  • This Paper introduces a new design of motorized wheel chair for the disabled, which is intended to improve the quality of the disabled's indoor life. This vehicle was based on high manoeuvrability of the omnidirectional drive and saftey. Usually, the vehicle controlled by a joystick but also the voice control system to be prepared for the severely disabled. This voice control system responds to the result of voice recognition, state of system or warning of dangers with voices, which has real time response and 95.3% recognition ratio and satisfactory synthesis voice Quality Therefore this system is able to provide independency in driving and the disabled's daily life.

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Xanthate-Mediated Controlled Radical Polymerizations of N-Vinylcarbazole and Synthesis of Star Polymers

  • Mori, Hideharu;Ookuma, Hiroshi;Endo, Takeshi
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.322-322
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    • 2006
  • Well-defined poly(N-vinylcarbazole), poly(NVC), was synthesized by macromolecular design via interchange of the xanthate (MADIX)/reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of a suitable xanthate-type chain transfer agent (CTA). Good control of the polymerization was confirmed by the linear first-order kinetic plot, the molecular weight controlled by the monomer/CTA molar ratio, linear increase in the molecular weight with the conversion, and the ability to extend the chains by the second addition of the monomer. Star polymers having various architectures were also synthesized using this technique.

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Controlled synthesis of reactive polymeric architectures for stimuli-responsive materials

  • Theato, Patrick;Nilles, Katja;Metz, Nadine
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.329-329
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    • 2006
  • Various new active ester monomers based on (meth)acrylates and 4-vinylbenzoic acid have been prepared. Investigation of the controlled radical polymerization behavior of the respective monomers resulted in excellent polymerization control, thus, opening synthetic routes to reactive block copolymers. Polymer analogous reactions with amines yielded functional polymers. In the case of the copolymer poly(N-isopropylacrylamide-co-acetone oxime acrylate) a lower critical solution temperature could be measured at $52^{\circ}C$. Thus, the reactive copolymer features two characters: reactive AND stimuliresponsive behavior.

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Synthesis of Monodisperse Silica Particles using Rotating Cylinder Systems

  • Cho, Young-Sang;Shin, Cheol Hwan
    • Korean Chemical Engineering Research
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    • 제54권6호
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    • pp.792-799
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    • 2016
  • Monodisperse silica nanospheres were synthesized by Stober method using rotating cylinder systems with batch or continuous manner. The particle size could be controlled by adjusting the reactant compositions such as the amount of monomer, catalyst, and water in the reaction mixture. The size and monodispersity of the ceramic particles could be controlled by changing the reaction medium with different alcohols other than ethanol or changing the reaction temperature. The effect of Taylor number (Ta) on the average diameter and standard deviation of silica particles were also studied by adjusting the rotation speed of inner cylinder, and the maximum diameter of particles was observed at Ta ${\approx}3,000$.

Controlled Synthesis of Spherical Polystyrene Beads and Their Template-Assisted Manual Assembly

  • Yoon, Seo Young;Park, Yi-Seul;Lee, Jin Seok
    • Bulletin of the Korean Chemical Society
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    • 제35권8호
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    • pp.2281-2284
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    • 2014
  • Polystyrene beads (PS beads) with narrow size distribution were synthesized, and their diameter was controlled from 1.2 to $5{\mu}m$ by varying the injection rate of a styrene solution containing initiator and the concentration of reactant, such as initiator and capping material. The diameter of the PS beads increased with increasing in the injection rates and the initiator concentration or decreasing the capping material concentration. Then, we used the PS beads as building block, and organized them into a hexagonally close-packed monolayer on substrate with template-assisted manual assembly. We showed perfect hexagonally close-packed organization of the PS beads with various sizes in large-scale area. And we demonstrated the superiority of the dry manual assembly over the wet self-assembly in terms of simplicity, speed, perfect ordering, and large scale.

전기분무법에 의해 제조되는 미립자의 형상 제어 (Controlled Morphology of Particles Prepared by Electrospray Technique)

  • 우엔 테 쭝;최진훈;윤지애;김교선
    • 산업기술연구
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    • 제35권
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    • pp.67-71
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    • 2015
  • Various structures of particles were prepared by electrospray technique. In this research, solid particles were formed by electrospraying a solution of ethanol containing polyvinyl and tetraethyl orthosilicate. During the electrospray process, the ethanol solvent was evaporated, resulting in the solidification of precursors, forming solid particles. Evaporation of ethanol solvent also enhanced the mass transport which facilitated the development of porous and hollow structures.

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핵심성장자리 수 조절을 통한 다양한 분자량을 갖는 폴리아닐린 합성 (Synthesis of Various Molecular Weight Polyaniline by Controlled Nucleation Site Number)

  • 홍장후;장관식;문우연
    • 공업화학
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    • 제17권5호
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    • pp.504-508
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    • 2006
  • 사슬성장의 핵심생성자리인 dimer (p-aminodiphenylamine)의 비율을 조절하여 아닐린 중합반응 과정에 첨가함으로서 oligomer에서 저분자량(Mw~40000)까지의 폴리아닐린 분자량이 조절되었다. 상대점도분자량 및 GPS 측정을 통하여 합성된 폴리아닐린의 분자량을 확인하였으며, UV, FT-IR, 전기전도도 등을 측정하여 분자량에 따른 폴리아닐린의 물리적, 화학적 성질을 조사하였다.

Synthesis of Monodisperse Spherical SiO2 and Self-Assembly for Photonic Crystals

  • Lee, Byung-Kee;Jung, Young-Hwa;Kim, Do-Kyung
    • 한국세라믹학회지
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    • 제46권5호
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    • pp.472-477
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    • 2009
  • Monodisperse spherical $SiO_2$ particles of various sizes ($\sim$350 nm and $\sim$800 nm) and size distributions were synthesized from TEOS and MTMS. The particle size and size distribution were controlled by changing the volume ratio of water to ethanol and the reaction temperature. Narrow-sized $SiO_2$ particles with $\sim$3% size distribution were obtained. Self-assembly of the $SiO_2$ particles for photonic crystals were performed by the solvent evaporation method. The number of ordered $SiO_2$ layers can be controlled by changing the amount of the dispersed $SiO_2$ volume fraction in the solvent.

Synthesis of Large Bumpy Silver Nanostructures with Controlled Sizes and Shapes for Catalytic Applications

  • Oh, Ju-Hwan;Kim, Do Yeon;Lee, Jae-Seung
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1001-1004
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    • 2014
  • We have synthesized disc-like large silver nanomaterials that have nanostructured bumps on the surface using smaller nanoplate seeds. The size and shape of the bumpy nanostructures are rationally controlled by changing the concentrations of nanoplate seeds, silver ion, reductant, and citrate ion. Importantly, the synthetic mechanism of these bumpy nanostructures is remarkably similar to that of the conventional seed-mediated growth based on tiny seeds. We have further investigated the catalytic properties of the bumpy nanostructures for the reduction of 4-nitrophenol, which is associated with a concomitant color change from yellow to colorless.

Synthesis of N-doped Ethylcyclohexane Plasma Polymer Thin Films with Controlled Ammonia Flow Rate by PECVD Method

  • Seo, Hyunjin;Cho, Sang-Jin;Boo, Jin-Hyo
    • Applied Science and Convergence Technology
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    • 제23권1호
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    • pp.44-47
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    • 2014
  • In this study, we investigated the basic properties of N-doped ethylcyclohexene plasma polymer thin films that deposited by radio frequency (13.56 MHz) plasma-enhanced chemical vapor deposition (PECVD) method with controlled ammonia flow rate. Ethylcyclohexene was used as organic precursor with hydrogen gas as the precursor bubbler gas. Additionally, ammonia ($NH_3$) gas was used as nitrogen dopant. The as-grown polymerized thin films were analyzed using ellipsometry, Fourier-transform infrared [FT-IR] spectroscopy, UV-Visible spectroscopy, and water contact angle measurement. We found that with increasing plasma power, film thickness is gradually increased while optical transmittance is drastically decreased. However, under the same plasma condition, water contact angle is decreased with increasing $NH_3$ flow rate. The FT-IR spectra showed that the N-doped ethylcyclohexene plasma polymer films were completely fragmented and polymerized from ethylcyclohexane.