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A Study on the Precipitation Behavior of $L2_1$-type $Ni_2AlTi$ Phase in B2-Ordered NiAl System (B2-규칙 NiAl계에 $L2_1$$Ni_2AlTi$상의 석출거동에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.4
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    • pp.187-194
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    • 2007
  • A transmission electron microscope (TEM) investigation has been performed on the precipitation of $L2_1$-type $Ni_2AlTi$ phase in B2-ordered NiAl system. The hardness after solution treatment is high in NiAl-Ti alloys suggesting the large contribution of solid solution strengthening in this alloy system. However, the amount of age hardening is not large as compared to the large microstructural variations during aging. At the beginning of aging, the $L2_1$-type $Ni_2AlTi$ precipitates keep a lattice coherency with the NiAl matrix. By longer periods of aging $Ni_2AlTi$ precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. Misfit dislocations, which are observed on {100} planes of H-precipitates have the Burgers vector of a <100> with a pure edge type. The lattice misfits of NiAl-$Ni_2AlTi$ system is estimated from the spacings of misfit dislocations to be 1.1% at 1273 K. The lattice misfits decrease with increasing aging temperature in this system.

Shear strengthening of reinforced concrete beams with rectangular web openings by FRP Composites

  • Abdel-Kareem, Ahmed H.
    • Advances in concrete construction
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    • v.2 no.4
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    • pp.281-300
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    • 2014
  • This study presents the experimental results of twenty three reinforced concrete beams with rectangular web openings externally strengthened with Fiber Reinforced Polymers (FRP) composites bonded around openings. All tested beams had the same geometry and reinforcement details. At openings locations, the stirrups intercepted the openings were cut during fabrication of reinforcement cage to simulate the condition of inclusion of an opening in an existing beam. Several design parameters are considered including the opening dimensions and location in the shear zone, the wrapping configurations, and the amount and the type of the FRP composites in the vicinity of the openings. The wrapping configurations of FRP included: sheets, strips, U-shape strips, and U-shape strips with bundles of FRP strands placed at the top and sides of the beam forming a fan under the strips to achieve closed wrapping. The effect of these parameters on the failure modes, the ultimate load, and the beam stiffness were investigated. The shear contribution of FRP on the shear capacity of tested beams with web openings was estimated according to ACI Committee 440-08, Canadian Standards S6-06, and Khalifa et al. model and examined against the test results. A modification factor to account for the dimensions of opening chords was applied to the predicted gain in the shear capacity according to ACI 440-08 and CSA S6-06 for bonded Glass Fiber Reinforced Polymers (GFRP) around openings. The analytical results after incorporating the modification factor into the codes guidelines showed good agreement with the test results.

Corrosion behavior of Mg-(0~6)%Zn Casting Alloys in 1M NaCl Solution (1M NaCl 용액에서 Mg-(0~6)%Zn 주조 합금의 부식 거동)

  • Hwang, In-Je;Kim, Young-Jig;Jun, Joong-Hwan
    • Journal of Korea Foundry Society
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    • v.36 no.4
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    • pp.117-125
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    • 2016
  • The effects of the Zn content on the microstructure and corrosion behavior in 1M NaCl solution were investigated in Mg-(0~6)%Zn casting alloys. The MgZn phase was scarcely observed in the Mg-1%Zn alloy, while the Mg-(2~6)%Zn alloy consisted of ${\alpha}$-(Mg) and MgZn phases. With an increase in the Zn content, the amount of the MgZn phase was gradually increased. Immersion and electrochemical corrosion tests indicated that the Mg-1%Zn alloy had the lowest corrosion rate among the alloys, and a further increase in the Zn content resulted in the deterioration of the corrosion resistance. Microstructural examinations of the corroded surfaces and EIS analyses of surface corrosion films revealed that the best corrosion resistance at 1%Zn was associated with the absence of MgZn phase particles in the microstructure and the contribution of Zn element to the formation of a protective film on the surface. A micro-galvanic effect by the MgZn particles led to the increased rate of corrosion at a higher Zn content.

Nitrogen Translocation and Dry Matter Accumulation of Direct Seeded Rice in No Tillage Rice-Vetch Cropping

  • Cho, Young-Son;Lee, Byung-Jin;Choe, Zhin-Ryong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.1
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    • pp.44-48
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    • 1999
  • Uptake, assimilation and translocation of nitrogen and dry matter assimilation and translocation in ten rice cultivars were observed in no-till direct-sown rice-vetch cropping system. There was a large degree of variation in N-uptake, grain yield, nitrogen translocation efficiency and dry matter assimilation and translocation in tested rice cultivars. Forty kg N/ha base, as compound fertilizer (21-17-21% of N-P-K) three weeks after sowing and 30 kg N/ha top-dressed at panicle initiation stage as in the form of (NH$_4$)$_2$$CO_2$ was applied. ‘Newbounet’, ‘Daesanbyeo’, and ‘Hwayeongbyeo’ showed higher translocation efficiency. The contribution of pre-heading dry matter assimilates to grain ranged from 33% to 99% of dry grain weight. Dry matter of ‘Calrose 76’ was lower than Newbounet but N content was higher in Calrose 76 than Newbonnet. By maturity, N content in vegetative parts declined considerably more than dry matter, vegetative and reproductive parts, N translocation efficiency, and N harvest index. Nitrogen translocation efficiency was greater in ‘Nonganbyeo’, Daesanbyeo, and Newbounet. Grain N concentration was positively correlated with N concentration or N content of the vegetative parts at heading in Nonganbyeo, ‘Dasanbyeo’, ‘Dongjinbyeo’, and Newbonnet. These results indicated that the greater amount of dry matter and N accumulated before heading stage, the higher translocation rates of dry matter to grain and the greater net losses at maturity.

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Climate Change Issues of Paper Manufacturing Production at Phong Khe Craft Village

  • Ha, Vu Thi Hong;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.27 no.1
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    • pp.40-50
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    • 2018
  • Today, the development of industries and rapid urbanization has a profound impact on the human environment. It can be said that the environment in the craft village is most affected. The environment in these areas is severely degraded and depending on the type of production, the environment in the craft villages is different. In Phong Khe ward of Bac Ninh Province, Vietnam, there are over 204 small and large facilities of recycling and producing paper. The paper facilities produce about 200,000 tons of paper each year and the amount of paper produced is not less than 500 tons each day in Phong Khe. They are creating livelihoods for more than 6,000 workers and generating local budgets from VND- 50 billion to VND 60 billion per year. Despite this great contribution, the use of old machines and "backward" modes of production means that paper recycling has caused serious air, soil, and water pollution in the region. The specific objectives of this study were as follows: (1) provide an overview of paper production process in the Phong Khe paper craft village; (2) comprehensive literature review of the current status of water environment, atmosphere environment, soil environment and solid waste; (3) figure out about waste treatment in Phong Khe ward.

Rheology and morphology of concentrated immiscible polymer blends

  • Mewis, Jan;Jansseune, Thomas;Moldenaers, Paula
    • Korea-Australia Rheology Journal
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    • v.13 no.4
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    • pp.189-196
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    • 2001
  • The phase morphology is an important factor in the rheology of immiscible polymer blends. Through its size and shape, the interface between the two phases determines how the components and the interface itself will contribute to the global stresses. Rheological measurements have been used successfully in the past to probe the morphological changes in model blends, particularly for dilute systems. For more concentrated blends only a limited amount of systematic rheological data is available. Here, viscosities and first normal stress differences are presented for a system with nearly Newtonian components, the whole concentration range is covered. The constituent polymers are PDMS and PIB, their viscosity ratio can be changed by varying the temperature. The data reported here have been obtained at 287 K where the viscosities of the two components are identical. By means of relaxation experiments the measured stresses are decomposed into component and interfacial contributions. The concentration dependence is quite different for the two types of contribution. Except for the component contributions to the shear stresses there is no clear indication of the phase inversion. Plotting either the interfacial shear or normal stresses as a function of composition produces in some cases two maxima. The relaxation times of these stresses display a similar concentration dependence. Although the components have the same viscosity, the stress-component curves are not symmetrical with respect to the 50/50 blend. A slight elasticity of one of the components seems to be the cause of this effect. The data for the more concentrated blends at higher shear rates are associated with a fibrillar morphology.

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The Soil Improvement and Plant Growth on the Newly-Reclaimed Sloped land VI. Relationship between annual change of soil phsico-chemical properties and yield of silage corn (신개간경사지 토양개량과 작물생육에 관한 연구 VI. 토양의 물리화학성 년차간 변화가 옥수수 청예수량에 미치는 영향)

  • 허봉구;김무성
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.1
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    • pp.22-29
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    • 1991
  • This study was experimented to obtain the basic information on the changeable aspect and improvement of soil fertility in newly-reclaimed sloped land. Silage corn was cultivated under the six different treatments for 4 years. The relation between the amount or ratio of annual changes of soil physico-chemical properties and yield of silage corn were analyzed. Soil bulk density was decreased in 3rd year at topsoil, but that decreased in 4th year at subsoil. Soil organic matter also decreased in 2nd year at topsoil, and decreased continuously at subsoil. Bulk density and hardness of soil depths showed significant negative simple correlation with dry matter yield and cation exchange capacity showed positive. Correlation coefficient of chemical properties with dry matter yield were low. The range of annual changes of moisture percent, hardness and organic matter were wider than the other properties. The significantly different of physical properties were higher than the chemical properties, and those of topsoil were higher than subsoil. According to multiple regression between yield and physico-chemical properties of subsoil, bulk density and cation exchange capacity were in the greatest contribution at the variations, but bulk density was greatest at the ratios.

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The effect of fuel evaporation in the intake valve back on mixture preparation (흡기밸브에서의 연료증발이 혼합기 형성에 미치는 영향)

  • 박승현;이종화;유재석;신영기;박경석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.107-115
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    • 1999
  • Hydrocarbon emission from spark ignition engines deeply relates with fuel evaporation mechanism. Therefore, fuel evaporation on the back of the intake valve is very important to understand fuel evaporation mechanism during engine warm up period. Intake valve heat transfer model was build up to estimate the amount of fuel evaporation on the intake valve back . Intake valve temperature was measured intake valve temperature is increased rapidly during few seconds right after engine start up and it takes an important role on fuel evaporation. The liquid fuel evaporation rate on the intake valve back proportionally increases as valve temperature increases, however its contribution slightly decreases as intake port wall temperature increases. The fuel evaporation rate on the valve back is about 40∼60% during engine warm-up period and it becomes about 20∼30% as intake port wall temperature increases. The estimation model also makes possible model also makes possible to review the effect of valve design parameters such as the valve mass and seat area on fuel evaporation rate through intake valve heat transfer.

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Precipitation of L21-type Ni2AlTi Phase in B2-type Intermetallic Compounds NiTi (B2형 금속간화합물 NiTi 중에 L21형 Ni2AlTi상의 석출)

  • Han, Chang-Suk
    • Korean Journal of Materials Research
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    • v.17 no.8
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    • pp.420-424
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    • 2007
  • Precipitation behavior has been studied in NiTi-based ordered alloy using transmission electron microscopy. The hardness after solution treatment is high in NiTi alloy suggesting the large contribution of solid solution strengthening in this alloy system. However, the amount of age hardening is not large as compared to the large microstructural variations during aging. At the beginning of aging, the $L2_1-type$ $Ni_2AlTi$ precipitates keep a lattice coherency with the NiTi matrix. By longer periods of aging $Ni_2AlTi$ precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. Misfit dislocations, which are observed on {100} planes of H-precipitates have the Burgers vector of a <100> with a pure edge type. The lattice misfits of $NiTi-Ni_2AlTi$ system is estimated from the spacings of misfit dislocations to be 1.3% at 1273 K. The lattice misfits decrease with increasing aging temperature in this system.

Chemical Properties of Sediment in Nanakita Estuarine Tidal Flat: Estimation of Sedimentary Organic Matter Origin by Stable Isotope and Fatty Acid

  • Shin, Woo-Seok;Aikawa, Yoshio;Nishimura, Osamu
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.77-82
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    • 2012
  • The spatial variation of organic matter sources in tidal flat sediment of the Nanakita River estuary, involving Gamo lagoon on the north-east coast of Honshu Island, Japan, was examined using carbon stable isotopes and fatty acid biomarkers. The spatial variation of total organic carbon (TOC) contents and ${\delta}^{13}C$ values were highly variable in between the stations, such as sandy flat (1.3 mg/g, -21.0‰), sand-muddy flat (2.6 mg/g, -21.9‰), and muddy flat (24.9 mg/g, -25.9‰), respectively. Particularly, at the muddy flat, high TOC content and low ${\delta}^{13}C$ value of the sediments indicated that the surface sediment was composed largely of terrestrial organic matter. Whereas, at the sandy flat and sand-muddy flat, the high ratios of diatom and bacteria biomarkers indicated the high contribution of abundant microorganism along with marine organic matter in sediment composition. From these results, it considered that the amount and origin of transported sedimentary organic matter indicated different characteristics in this study stations.