• 제목/요약/키워드: continuous flow-through system

검색결과 139건 처리시간 0.031초

꽃게, 중하 및 징거미새우의 유생과 성체에 대한 황화수소의 급성독성 (Acute toxicity of hydrogen sulfide to larvae and adults of blue crab Portunus trituberculatus white shrimp Metapenaeus monoceros and prawn Macrobrachium nipponens)

  • 강주찬
    • 한국어병학회지
    • /
    • 제10권1호
    • /
    • pp.65-72
    • /
    • 1997
  • 유용 갑각류인 꽃게, 중하 및 징거미새우의 유생과 성체에 대한 황화수소의 급성독성 실험 결과로부터 이들 갑각류에 대한 독성수준, 독성순위 및 유생과 성체와의 독성차를 검토하였다. 황화수소에 대한 꽃게, 중하 및 징거미새우 유생의 96시간 반수치사농도(96hr-$LC_{50}$)는 각각 7.3, 9.3 및 $9.0{\mu}g/\ell$으로 독성순위는 꽃게>징거미새우>중하순으로 나타났다. 한편, 성체에 대한 황화수소의 96hr-$LC_{50}$값은 꽃게 $42.5{\mu}gS/\ell$, 중하 $37.8{\mu}gS/\ell$, 징거미새우 $56.6{\mu}gS/\ell$로 독성순위는 중하>꽃게>징거미새우 순으로 유생과는 다른 경향을 나타내었다. 황화 수소는 꽃게, 중하 및 징거미새우의 유생에 대하여 성체에 비해 각각 5.8, 4.1, 6.3배의 강한 독성을 나타냈다.

  • PDF

인천항 VTS의 효율적인 운영방안에 관한 연구 (A Study on the Efficient Operation of VTS in Inchon)

  • 김상환;박진수
    • 한국항해항만학회:학술대회논문집
    • /
    • 한국항해항만학회 1998년도 제 23회 정기총회 및 추계학술발표회
    • /
    • pp.11-25
    • /
    • 1998
  • Many Countries have made efforts to assist ships navigate accurately , safely and expeditiously for the safety control against increasing marine traffic , in their coastal waters. However, they are exposed in spite of these efforts,to risks of casulaties and marine polluation caused by traffic congestion when ships are navigating through waterways approaches to ports or harbors and in narrow fairways. Therefore, efficient control of VTS in Port is necessary nowadays to provide ships with necessary service , which interacts with shipping and organize the flow of traffic so as to maximize the efficiency of the port or harbor while minimizing the risk of accident and environmental pollution. Even though the navigation condition of ships is very inferior compared to other ports in Korea, such as the big difference between the ebb and flood tide, the frequent fog, the narrow fairway , the density of navigation traffic in Inchon Port is high and transportation quantity of dangerous cargoe increases gradually. In cosideration of the characteristics of natural circumstance and traffic circumstance the VTS established newly in Inchon port have to operate efficiently. The purpose of this study is to help efficient operation of VTS in Inchon port by accomplishing both the literature research and questionnaire survey. Questionnaire survey was read to the VTS personnel in Inchon Port and customer familiar to Inchon Port such as ship navigators, pilots, shipping companies and so on. Most of ship navigators who occupy half of the respondents are Korean Officer who had responded while they were calling at Inchon port. The conclusions and recommendations includes ; First, the service area should be extended over Designated area to provide the vessel with navigational assistance service regarding the information of traffic congestion area, fishing boat and small ship's activities. Second, the types of information service to be offered are ship's movement and weather condition inthe vicinity of the port and state of fairway in the approaching channel to thte fairway. Third, VTS personnel should be upgraded by the on-the-job training and continuous simulation training as well as supplement of the qualified personnel for VTS operation. Fourth , the Harbor Master System to be introduced for safe navigation and efficient port operation.

  • PDF

단이론과 모멘트방법을 이용한 데옥시리보뉴클레오사이드의 평형상수의 계산 및 비교 (Comparison and Estimation of Equilibrium Constants for Deoxyribonucleosides by Plate Theory and Moment Method)

  • 이주원;노경호
    • 공업화학
    • /
    • 제8권3호
    • /
    • pp.403-409
    • /
    • 1997
  • 데옥시리보뉴클레오사이드의 평형상수를 단이론과 모멘트방법에 의해서 일정 용매 조성법 역상 고성능 액체크로마토그래피(Reversed-Phase High Performance Liquid Chromatography)를 이용하여 계산하였다. 이동상은 물을 기본으로 유기용매로서 acetonitrile과 methanol을 사용하였다. 단이론은 선형 흡착식으로부터 나온 모델로 일정한 유속으로 용매가 column의 단을 평형을 이루면서 지나간다는 가정 하에서 이루어졌다. 모멘트 방법은 실험결과로부터 얻은 peak에서 첫 번째 절대 모멘트를 구하여 평형상수를 계산하는 방법이다. 이 두가지 방법에 의한 다섯 가지의 데옥시리보뉴클레오사이드의 평형상수값은 서로 근사하였고, 용량인자를 이용하여 구한 평형상수의 값과도 비슷하였다. 평형상수는 이동상에서의 organic modifier의 양의 semi-log의 관계식으로 표리되었고 단이론에 의해 계산된 용출곡선은 실험값과 잘 일치하였다.

  • PDF

지류하천의 상·하류 수질변화 비교: 낙동밀양 중권역 내 계성천 화포천을 대상으로 (Comparison of Changes in Upstream and Downstream Water Quality of Tributary Rivers: Gyeseong-stream and Hwapo-stream in Nakdongmiryang Watershed)

  • 심규현;김경훈;김성민;김용석;김진필
    • 한국물환경학회지
    • /
    • 제36권5호
    • /
    • pp.445-452
    • /
    • 2020
  • Tributary is a part of life space for people and a very important place that accommodates rest recreation and other daily activities. absolutely insufficient basic data about water quality and flow rate are available for basin management. Efficient water and basin management systems, which are also supported by local residents can be established by securing such basic data of major tributaries in the Nakdong river system. In this study, the fluctuation characteristics of upstream and downstream water pollution levels were compared using the measurement results of the water environment measurement network and the tributary monitoring project for the gyeseong-stream and Hwapo-stream in the Nakdong-miryang watershed. In 2017, when water pollution is the highest, it was confirmed that the annual average rainfall was the lowest. Although the upstream and downstream water quality tendencies of the Gyeseong-stream are similar, the water quality concentrations of the Gyeseong-stream are relatively different. But although the Hwapo stream has various causes of pollution, there was not much difference in the level of pollution between the upper and lower streams. In addition, both rivers need the ability to purify rivers by securing sufficient water for river maintenance, and if the correlation between water quality items can be inferred through continuous monitoring of tributaries where the aspect of water quality change is unclear, water quality management Determined to be efficient operation.

Numerical Simulation of an Impinging Jet with Various Nozzle-to-strip Distances in the Air-knife System

  • So, Hong-Yun;Yoon, Hyun-Gi;Chung, Myung-Kyoon
    • Corrosion Science and Technology
    • /
    • 제9권6호
    • /
    • pp.239-246
    • /
    • 2010
  • When galvanized steel strip is produced through a continuous hot-dip galvanizing process, the thickness of the adhered zinc film is controlled by impinging a thin plane nitrogen gas jet. The thickness of the zinc film is generally affected by impinging pressure distribution, its gradient and shearing stress at the steel strip. These factors are influenced by static pressure of gas spraying at air knife nozzle, a nozzle-to-strip distance and strip and a geometric shape of the air knife, as well. At industries, galvanized steel strip is produced by changing static pressure of gas and a distance between the air knife nozzle and strip based on experimental values but remaining a geometric shape of nozzle. Splashing and check-mark strain can generally occur when a distance between the air knife nozzle and strip is too short, while ability of zinc removal can lower due to pressure loss of impinging jet when a distance between the air knife nozzle and strip is too long. In present study, buckling of the jet and change of static pressure are observed by analyzing flow characteristics of the impinging jet. The distance from the nozzle exit to the strip varies from 6 mm to 16 mm by an increment of 2 mm. Moreover, final coating thickness with change of a distance between the air knife nozzle and strip is compared with each case. An ability of zinc removal with the various distances is predicted by numerically calculating the final coating thickness.

탄소에어로젤 복합전극의 전기용량적 탈이온 공정 특성 (Characteristics of Capacitive Deionization Process using Carbon Aerogel Composite Electrodes)

  • 이기택;조원일;조병원
    • 전기화학회지
    • /
    • 제8권2호
    • /
    • pp.77-81
    • /
    • 2005
  • 전기화학적으로 이온을 흡착시켜 이온을 제거하는 capacitive deionization(CDI)공정용 전극으로 탄소에어로젤에 실리카젤이 첨가된 다공성 탄소에어로젤 복합전극을 사용하여 1,000ppm NaCl수용액에서 탈염 특성에 대한 충전과 방전시 시간에 따른 전류 변화, CDI효율을 조사하였다. Paste rolling법으로 제조된 $10\times10cm^2$다공성 탄소에어로젤 복합전극은 촉매 분야에서 활용되고 있는 다공성 지지체인 실리카젤을 첨가함으로써 CDI 반응진행에 대한 전극활물질 탈락이 없이 전극의 성형성이 크게 향상되었고, 친수성과 전극의 기계적 강도 증가 및 CDI 효율을 증가시킬 수 있었다. 이러한 45개의 전극을 하나의 묶음으로 네 개의 단을 직렬연결 하여, CDI 시스템을 구성하였고 충전 시에는 1.2V, 방전 시에는 0.001V를 각각 10분간 인가하여 실험한 결과 $99\%$ 이상의 CDI 효율을 달성하였다.

수직 라인 관측시스템을 이용한 제주 동부 해안대수층에서 해수침투 모니터링 평가 (Saltwater Intrusion Monitoring Evaluation through Automatic Vertical Line Method in a Costal Aquifer of the Eastern Part of Jeju Island)

  • 장호준;하규철;황인욱;김기표;박원배
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제26권3호
    • /
    • pp.1-13
    • /
    • 2021
  • Groundwater monitoring is commonly practiced with real-time sensors placed in several depth spots in aquifer. However, this method only provides monitoring data at the point where the sensors are installed. In this study, we developed a vertical line monitoring system (VLMS) that can provide continuous data of groundwater parameters along the vertical depth. The device was installed in a well located on the coast of the eastern part of Jeju island to monitor electrical conductivity, temperature, salinity, pH, dissolved oxygen, and oxidation-reduction potential over approximately 3 months from September 11 to December 3, 2020. The results indicated that the groundwater levels fluctuated with the tidal change of seawater level, and the upper and lower boundaries of the freshwater and saltwater zone in the groundwater were located at below 16 m and 36 m of mean sea level, respectively. There was a large variation in EC values during the high tide and temperature change was the greatest during flow tide. Although further investigation is needed for improvement of the device to obtain more accurate and reliable data, the device has a potential utility to provide fundamental data to understand the seawater intrusion and transport mechanisms in coastal aquifers.

반연속 흐름 2단 토양 컬럼에서의 사염화 에틸렌(PCE)의 혐기성 환원탈염소화 (Anaerobic Reductive Dechlorination of Tetrachloroethylene (PCE) in Two-in-series Semi-continuous Soil Columns)

  • 안영호;최정동;김영;권수열;박후원
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제11권2호
    • /
    • pp.68-76
    • /
    • 2006
  • 실험실 규모의 반연속 흐름 2단 토양컬럼을 이용하여 사염화에틸렌(PCE)에서 에틸렌으로의 혐기성 환원 탈염소화 반응특성을 조사하였다. 국내의 TCE로 오염된 현장에서 토양을 채취하여 컬럼 반응조에 충진하고, lactate(전자공여체 그리고/혹은 탄소원으로서)와 PCE를 함유한 현장 지하수를 컬럼 반응조로 주입하였다. 운전초기 약 50일 경과기간 동안 유입 lactate와 PCE의 질량비는 620:1이었는데, 이때 PCE에서 cis-DCE로의 불완전한 환원성 탈염소화가 관찰되었다. 그러나 유입 lactate와 PCE의 질량비를 5,050:1로 증가시킨 두번째 운전기간동안 PCE에서 ethylene로의 완벽한 탈염소화를 관찰할 수 있었는데, 이는 초기 운전기간 동안의 적절한 전자공여체의 공급의 중요성을 보여 주었다. PCE에서 cis-DCE로의 탈염소화율은 $0.62{\sim}1.94\;{\mu}mol$ PCE/L pore volume/d이었고, cis-DCE에서 ethylene으로의 탈염소화율은 $2.76\;{\mu}mol$ cis-DCE/L pore volume/d으로 나타났다. 전체 시스템에서의 PCE에서 ethylene으로의 전환율은 $1.43\;{\mu}mol$ PCE/L pore volume/d이었다. 본 실험에서 PCE에서 cis-DCE로의 분해단계에서 수소의 농도는 $10{\sim}64\;mM$, 그리고 cis-DCE에서 에틸렌으로의 분해단계에서 수소의 농도는 $22{\sim}29\;mM$이었다. 본 연구에서의 이러한 긍정적인 실험 결과는 본 연구에서 조사된 TCE로 오염된 지하수의 현장 생물학적 복원을 위해 혐기성 환원 탈염소화 공정의 적용 가능성을 보여준다.

통일신라시대(統一新羅時代) 불교건축(佛敎建築)의 변화(變化) (The Change in the Buddhist Architecture of the Unified Silla Period (668-935))

  • 김성우
    • 건축역사연구
    • /
    • 제1권2호
    • /
    • pp.68-84
    • /
    • 1992
  • The development of Buddhist architectures of the Unified Silla period have been generally understood to have paired pagoda instead of one which had been popular until before the unification. Besides the stylistic categorization of paired pagoda system, there had been no further investigation reported concerning whether there was any detailed process of change within the development of paired pagoda style. This paper aims to identify such change inside the development of paired pagoda style, which, externally, seems to be the same pattern of site design maintained throughout the period of Unified Silla that lasted for about three centuries. Since the temple sites of study are in the same pattern of layout, the method of investigation has to be such that can identify the subtle changes that, in external appearance, are not easily discernible. Hence, this research compared the dimensions of important measurement of five temple sites to be able to clarify the process of minor changes. Among many sites of Silla temples, only five were suitable for the research since detailed measurement were possible through field research or the report of excavation. They are the sites of Sachonwang-sa, Mangduk-sa, site of Kunsuri, and Bulguk-sa. Although the five sites have the same style of paired pagoda, it is clear that there were consistant flow of change. Even though the motivation of such change were not strong enough to change the site pattern itself, it resulted continuous minor changes such as the size and location of architectures. The size of image hall, for example, was growing larger and larger as time goes on, while, the size of Pagoda was getting smaller. In the same way, the size of middle gate became smaller while the size of lecture hall became larger, although the rate of change in these cases were not as severe as that of image hall and pagoda. At the same time, pagoda was coming closer to the middle gate leaving larger space in front of the image hall. Such aspect is even more meaningful considering the fact that the pagoda, from the 8th century in Japan and China, moved outside of the major precinct. The image hall, too, moved toward the middle gate slightly so that the space in front of the lecture hall became more spacious. Such changes, of course, were not accidental but they are the same continuous motivation of change that caused the changes before the period of unification. Enlargement of image hall and reduction of pagoda, for example, represent the changing relative importance of religious meaning. Hence, it is evident that one can not easily imterprete the development of one style only by categorizing it to be one same style. In the veiwpoint of the underlying motivation of change, the fact that one style persisted for a certain period of time, does not mean there had been no change, but means that it was the time of motivational accumulation, causing minor changes within the same style, to be able to create major change coming after.

  • PDF

금속산화물 담지촉매상에서 연속 습식 TCE 분해반응 (Continuous Wet Oxidation of TCE over Supported Metal Oxide Catalysts)

  • 김문현;추광호
    • Korean Chemical Engineering Research
    • /
    • 제43권2호
    • /
    • pp.206-214
    • /
    • 2005
  • $TiO_2$에 담지된 불균일 촉매상에서 ppm 수준으로 존재하는 수중 유기오염물질들을 제거하기 위한 모델반응으로 액상 trichloroethylene(TCE) 분해반응을 선정하였으며, 여러 반응변수의 동시제어가 가능하도록 디자인된 연속 흐름식 고정층 반응기 내에서 incipient wetness 기법으로 제조된 여러 전이금속 산화물 촉매들의 TCE 분해활성을 조사하였다. 선택된 반응조건에서 모델반응의 내부확산저항은 없었으며, $36^{\circ}C$의 반응온도에서 촉매표면에 흡착에 의한 액상 TCE 제거된 정도는 무시할 만하였고 촉매반응에 의해서만 제거될 수 있었다. TCE 제거반응에 대한 촉매들의 활성 및 반응시간에 따른 분해효율의 의존성은 사용된 금속 산화물 및 담지체의 종류에 따라 달라지는 것으로 나타났다. 5 wt.% $CoO_x$/$TiO_2$ 촉매는 본 대상반응에 대하여 가장 우수한 활성을 갖는 것으로 나타났으며, 반응시간의 경과 정도에 따라 TCE 분해효율이 점진적으로 증가하여 안정되는 전이구간의 존재를 확인할 수 있었다. 이와 같은 촉매활성의 반응시간 의존성은 반응 초기와 일정시간 경과 후의 $TiO_2$ 표면에 존재하는 $CoO_x$의 표면구조가 상이할 뿐만 아니라 반응시간 경과와 함께 활성이 더욱 높은 Co species의 표면노출을 암시하고 있다. $NiO_x$, $CrO_x$와 같은 금속 산화물 촉매들의 반응활성은 매우 낮은 수준이었다. $TiO_2$와 MFI를 담지체로 하여 각각 incipient wetness법과 이온교환법으로 제조된 $CuO_x/TiO_2$, Cu-MFI, $FeO_x/TiO_2$ 및 Fe-MFI의 TCE 제거효율을 반응시간의 함수로 살펴본 결과, Cu 촉매들에서 관찰되는 반응시간-분해효율 거동과는 다른 현상이 $FeO_x/TiO_2$와 Fe-MFI 촉매상에서 관찰되었다. $36^{\circ}C$의 반응온도에서 전반응시간 동안에 5 wt.% $FeO_x/TiO_2$ 촉매상에서 TCE 제거반응은 일어나지 않았으나, 1.2 wt.% Fe-MFI의 경우 반응 초기에 높은 제거율을 일정시간 동안 유지하다가 서서히 감소하는 비활성화 현상이 발생하였다. 이는 동일한 활성성분이 사용된다 할지라도 그 제조방법에 따라 촉매활성이 달라질 수 있음을 보여주고 있으며, 액상반응 중에 일어나는 활성성분의 redox cycle이 중요한 역할을 할 수 있음을 암시하고 있다. 가장 우수한 $CoO_x/TiO_2$ 촉매의 TCE 분해활성에 미치는 $CoO_x$ 담지량, 반응온도 등의 영향을 조사한 결과, 최적의 $CoO_x$ 담지량이 존재하였고 반응온도가 높을수록 TCE 제거효율은 높게 나타났다. 반응 중에 $CoO_x$ leaching에 의한 $CoO_x$의 손실이 확인되었으나 TCE 전환율에 영향을 미칠 정도는 아닌 것으로 판단되었다.