• Title/Summary/Keyword: content matrix

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Dependency of the Critical Carbon Content of Electrical Conductivity for Carbon Powder-Filled Polymer Matrix Composites

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.25 no.8
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    • pp.365-369
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    • 2015
  • This paper investigates the dependency of the critical content for electrical conductivity of carbon powder-filled polymer matrix composites with different matrixes as a function of the carbon powder content (volume fraction) to find the break point of the relationships between the carbon powder content and the electrical conductivity. The electrical conductivity jumps by as much as ten orders of magnitude at the break point. The critical carbon powder content corresponding to the break point in electrical conductivity varies according to the matrix species and tends to increase with an increase in the surface tension of the matrix. In order to explain the dependency of the critical carbon content on the matrix species, a simple equation (${V_c}^*=[1+ 3({{\gamma}_c}^{1/2}-{{\gamma}_m}^{1/2})^2/({\Delta}q_cR]^{-1}$) was derived under some assumptions, the most important of which was that when the interfacial excess energy introduced by particles of carbon powder into the matrix reaches a universal value (${\Delta}q_c$), the particles of carbon powder begin to coagulate so as to avoid any further increase in the energy and to form networks that facilitate electrical conduction. The equation well explains the dependency through surface tension, surface tensions between the particles of carbon powder.

Pharmaceutical Formulation and Evaluation of Sustained - Release Hydrophilic Matrix Tablet of Cefatrizine Propyleneglycol Using Polyethylene Oxide (폴리에틸렌옥사이드를 이용한 세파트리진프로필렌글리콜 서방성매트릭스 정제의 제조 및 평가)

  • Lee, Eon-Hyoung;Park, Sun-Young;Jee, Ung-Kil;Kim, Dong-Chool
    • Journal of Pharmaceutical Investigation
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    • v.31 no.1
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    • pp.37-41
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    • 2001
  • Various characteristics of polyethylene oxide (PEO) are useful for drug delivery systems. In this study, PEO was used as a sustained release matrix system containing cefatrizine propyleneglycol (Cefa-PG) which is a new semi-synthetic broad-spectrum and orally active cephalosporin. Five kinds of sustained release matrix tablets were formulated with various content of PEO and other ingredients. And three types of matrix tablets were formulated of which compositions were the same but the hardness was different. It was found that PEO content influenced drug release rate. Increasing PEO content, the drug release rate from matrix tablets was decreased. In addition, Avicel, one of the ingredients of matrix components, changed the drug release from the sustained release PEO matrix tablets. With increasing Avicel content, the rate of drug release was increased. For the effect of hardness of matrix tablets, the rate of drug release is decreased with increasing hardness. In comparison of bioavailability parameters after oral administration of Cefa-PG PEO matrix tablets and general Cefa-PG capsule in beagle dog, the sustained release PEO matrix tablets is more useful than a general dosage form. $AUC^{0-12}$ of the sustained release PEO matrix tablet and the general dosage form was 1.16 and 0.644 respectively.

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Experimental study on water exchange between crack and clay matrix

  • Song, Lei;Li, Jinhui;Garg, Ankit;Mei, Guoxiong
    • Geomechanics and Engineering
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    • v.14 no.3
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    • pp.283-291
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    • 2018
  • Cracks in soil provide significant preferential pathways for contaminant transport and rainfall infiltration. Water exchange between the soil matrix and crack is crucial to characterize the preferential flow, which is often quantitatively described by a water exchange ratio. The water exchange ratio is defined as the amount of water flowing from the crack into the clay matrix per unit time. Most of the previous studies on the water exchange ratio mainly focused on cracked sandy soils. The water exchange between cracks and clay matrix were rarely studied mainly due to two reasons: (1) Cracks open upon drying and close upon wetting. The deformable cracks lead to a dynamic change in the water exchange ratio. (2) The aperture of desiccation crack in clay is narrow (generally 0.5 mm to 5 mm) which is difficult to model in experiments. This study will investigate the water exchange between a deformable crack and the clay matrix using a newly developed experimental apparatus. An artificial crack with small aperture was first fabricated in clay without disturbing the clay matrix. Water content sensors and suction sensors were instrumented at different places of the cracked clay to monitor the water content and suction changes. Results showed that the water exchange ratio was relatively large at the initial stage and decreased with the increasing water content in clay matrix. The water exchange ratio increased with increasing crack apertures and approached the largest value when the clay was compacted at the water content to the optimal water content. The effective hydraulic conductivity of the crack-clay matrix interface was about one order of magnitude larger than that of saturated soil matrix.

MODELING OF INTERACTION LAYER GROWTH BETWEEN U-Mo PARTICLES AND AN Al MATRIX

  • Kim, Yeon Soo;Hofman, G.L.;Ryu, Ho Jin;Park, Jong Man;Robinson, A.B.;Wachs, D.M.
    • Nuclear Engineering and Technology
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    • v.45 no.7
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    • pp.827-838
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    • 2013
  • Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to $200^{\circ}C$, and for Mo content in the range of 6 - 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea's KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

Numerical study on the effect of crack network representation on water content in cracked soil

  • Krisnanto, Sugeng;Rahardjo, Harianto;Leong, Eng Choon
    • Geomechanics and Engineering
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    • v.21 no.6
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    • pp.537-549
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    • 2020
  • The presence of cracks changes the water content pattern during seepage through a cracked soil as compared to that of intact soil. In addition, several different crack networks may form in one soil type. These two factors result in a variation of water contents in the soil matrix part of a cracked soil during seepage. This paper presents an investigation of the effect of crack network representation on the water content of the soil matrix part of cracked soil using numerical models. A new method for the numerical generation of crack networks incorporating connections among crack endpoints was developed as part of the investigation. Numerical analysis results indicated that the difference in the point water content was large, whereas the difference in the average water content was relatively small, indicating the uniqueness of the crack network representation on the average water content of the soil matrix part of cracked soil.

Permeability of Silver Sulfadiazine through Crosslinked Chitosan Matrices (가교키토산 매트릭스를 통한 Silver Sulfadiazine의 투과)

  • Nah, Jae Woon
    • Journal of the Korean Chemical Society
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    • v.40 no.9
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    • pp.640-648
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    • 1996
  • Crosslinked chitosan was prepared from chitin after reaction with epichlorohydrin followed by deacetylation at C2-position. Epidermal releasing polymeric matrix was prepared after swelling crosslinked chitosan with distilled water and adding silver sulfadiazine and glycerine as a plasticiser. The release behavior of silver sulfadiazine from polymeric matrix was studied in pH 7.4 phosphate buffer solution by varing the drug content, glycerine concentration, and the thickness of the matrix. The drug release time was delayed by increasing the content of silver sulfadiazine and the thickness of the matrix, whereas decreased as glycerine concentration increased. The apparent constant(K) of release rate was independent upon the matrix thickness, but was proportional to the content of drug or glycerine of crosslinked chitosan matrix. These results indicated that chitosan matrix showed some potential as a drug delivery system for transdermal therapeutic application.

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Preparation and Evaluation of Antibacterial Transdermal Device using Chitosan Matrices (키토산 매트릭스를 이용한 향균제 경피흡수제형의 제조와 평가)

  • Kim Sun Il;Na Jae Woon
    • Journal of the Korean Chemical Society
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    • v.37 no.5
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    • pp.527-536
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    • 1993
  • The characteristics of the controlled drug release were studied for biodegradable transdermal drug delivery system. A biodegradable polymeric matrix was prepared from chitosan, silver sulfadiazine, and glycerine. The release behavior of silver sulfadiazine from chitosan matrix was consistent with the Higuchi's diffusion controlled model. The release time was delayed by increasing the content of silver sulfadiazine and thickness of the matrix, whereas decreased as glycerine concentration increased. The apparent constant (K) of release rate was proportional to the content of drug or glycerine and the thickness of chitosan matrix. These results indicated that chitosan matrix shows some potential as a drug delivery system for transdermal therapeutic application.

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The Characteristics of Chloride Fixation in Non-Sintering Cement Matrix (비소성 시멘트 경화체내 염화물 고정화 특성)

  • Mun, Kyoung-Ju;Hyoung, Won-Kil;Park, Won-Chun;So, Seung-Young;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.725-728
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    • 2006
  • This research investigates the characteristics of chloride fixation in non-sintering cement(NSC) matrix. NSC was manufactured by adding phosphogypsum and slack lime to granulated blast furnace slag as sulfate and alkali activators. As a result, the concentration of chloride ion in pore solution of NSC-solidified matrix is more low than that of OPC-solidified matrix containing the same chloride content in cement paste. Also, the concentration of chloride ion in pore solution of NSC-solidified matrix is similar with that of BSC-solidified matrix containing the same chloride content in cement paste.

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Effect of polymer addition on air void content of fine grained concretes used in TRCC

  • Daskiran, Esma Gizem;Daskiran, Mehmet Mustafa;Gencoglu, Mustafa
    • Computers and Concrete
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    • v.20 no.2
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    • pp.165-176
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    • 2017
  • Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

A Design on the Multimedia Fingerprinting code based on Feature Point for Forensic Marking (포렌식 마킹을 위한 특징점 기반의 동적 멀티미디어 핑거프린팅 코드 설계)

  • Rhee, Kang-Hyeon
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.48 no.4
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    • pp.27-34
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    • 2011
  • In this paper, it was presented a design on the dynamic multimedia fingerprinting code for anti-collusion code(ACC) in the protection of multimedia content. Multimedia fingerprinting code for the conventional ACC, is designed with a mathematical method to increase k to k+1 by transform from BIBD's an incidence matrix to a complement matrix. A codevector of the complement matrix is allowanced fingerprinting code to a user' authority and embedded into a content. In the proposed algorithm, the feature points were drawing from a content which user bought, with based on these to design the dynamical multimedia fingerprinting code. The candidate codes of ACC which satisfied BIBD's v and k+1 condition is registered in the codebook, and then a matrix is generated(Below that it calls "Rhee matrix") with ${\lambda}+1$ condition. In the experimental results, the codevector of Rhee matrix based on a feature point of the content is generated to exist k in the confidence interval at the significance level ($1-{\alpha}$). Euclidean distances between row and row and column and column each other of Rhee matrix is working out same k value as like the compliment matrices based on BIBD and Graph. Moreover, first row and column of Rhee matrix are an initial firing vector and to be a forensic mark of content protection. Because of the connection of the rest codevectors is reported in the codebook, when trace a colluded code, it isn't necessity to solve a correlation coefficient between original fingerprinting code and the colluded code but only search the codebook then a trace of the colluder is easy. Thus, the generated Rhee matrix in this paper has an excellent robustness and fidelity more than the mathematically generated matrix based on BIBD as ACC.