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Effect of particle size of TiO2 and octyl-methoxycinnamate (OMC) content on sun protection factor (SPF)

  • Choi, Jaeyeong;Kim, Suyeon;Kim, Woonjung;Eum, Chul Hun;Lee, Seungho
    • Analytical Science and Technology
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    • v.30 no.4
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    • pp.159-166
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    • 2017
  • Exposure to UV light, i.e., UV-A (320-400 nm) or UV-B (290-320 nm) radiation, can cause skin cancer. Titanium dioxide ($TiO_2$) effectively disperses UV light. Therefore, it is used as a physical UV filter in many UV light blockers. Usually, the $TiO_2$ content in commercialized UV blockers is 25 % at most. To block UV-B, a chemical UV blocker, octyl-methoxy cinnamate (OMC) is used. OMC is commonly used in combination with $TiO_2$. In this study, $TiO_2$ and OMC were mixed in different proportions to produce UV blockers with different compositions. Also the changes in the sun protection factor (SPF) based on the composition and $TiO_2$ particle sizes were investigated. In order to analyze the $TiO_2$ particle size, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) were used. The results showed that the SPF was influenced by the proportion of $TiO_2$ and OMC, where the proportion of $TiO_2$ induced a more significant influence. In addition, changes in the $TiO_2$ particle size based on the proportion of OMC were observed.

Effects of Prostacyclin [PGI2] on Myocardial Protection in the Isolating Working Heart Model (적출활동심장에서 Prostacyclin [PGI2]의 심근보호효과)

  • Lee, Gil-No;Kim, Gyu-Tae
    • Journal of Chest Surgery
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    • v.20 no.4
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    • pp.643-654
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    • 1987
  • The effect of prostacyclin[PGI, ] on myocardial preservation during global ischemia was studied in the isolating working rabbit heart model. Forty hearts underwent a 15 minute period of retrograde nonworking perfusion with Krebs-Henseleit buffer solution [37*C] and were switched over to the working mode for 15 minutes. After baseline measurement of heart rate, peak aortic pressure, aortic flow, and coronary flow, all hearts were subjected to 60 minutes of ischemic arrest at 10*C induced with St. Thomas Hospital cardioplegic solution: Group I had single dose cardioplegia, Croup II double dose, Croup III oxygenated double dose, and Group IV single dose with PCI, infusion [10ng/min./gm heart weight]. Hearts were then revived with 15 minute period of nonworking reperfusion at normothermia, followed by 30 minutes of working perfusion. Repeat measurements of cardiac function were obtained and expressed as a percent of the preischemic baseline values. Oxygen content of arterial perfusate and coronary effluent was measured by designed time interval. Leakage of creatine kinase was determined during post-ischemic reperfusion period. Finally wet hearts were weighed and placed in 120*C oven for 36 hours for measurement of dry weight. In the PGI, treated group [IV], heart rate increased consistently throughout the period of reperfusion from 100*5.0% [p<0.001] to 107*6.2% [p<0.001]. The percent recovery of aortic flow showed 95*5.7% [p<0.001] at the first 3 minute and full recovery through the subsequent time. Coronary flow was augmented significantly in the 3 minute [96*6.2%, p<0.001] and then sustained above baseline values. Among the Croup I, II, and III, all hemodynamic values were significantly below preischemic levels. PGI2 relatively increased oxygen delivery [1.22*0.19ml/min, p<0.001] and myocardial oxygen consumption [0.90*0.13ml/min, p<0.001] during reperfusion period. Leakage of creatine kinase in the PGI2 group was 9.3*1.58IU/15min [p<0.001]. This was significantly lower than Group I [33.0*2.68 IU/15min]. The water content of PCI2 treated hearts [81*0.9%, p<0.001] was also lower than the other groups.

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Content-based Shot Boundary Detection from MPEG Data using Region Flow and Color Information (영역 흐름 및 칼라 정보를 이용한 MPEG 데이타의 내용 기반 셧 경계 검출)

  • Kang, Hang-Bong
    • Journal of KIISE:Software and Applications
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    • v.27 no.4
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    • pp.402-411
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    • 2000
  • It is an important step in video indexing and retrieval to detect shot boundaries on video data. Some approaches are proposed to detect shot changes by computing color histogram differences or the variances of DCT coefficients. However, these approaches do not consider the content or meaningful features in the image data which are useful in high level video processing. In particular, it is desirable to detect these features from compressed video data because this requires less processing overhead. In this paper, we propose a new method to detect shot boundaries from MPEG data using region flow and color information. First, we reconstruct DC images and compute region flow information and color histogram differences from HSV quantized images. Then, we compute the points at which region flow has discontinuities or color histogram differences are high. Finally, we decide those points as shot boundaries according to our proposed algorithm.

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Dielectric Characteristics due to the nano-pores of SiOCH Thin Flm (기공형성에 의한 SiOCH 박막의 유전 특성)

  • Kim, Jong-Wook;Park, In-Chul;Kim, Hong-Bae
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.3
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    • pp.19-23
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    • 2009
  • We have studied dielectric characteristics of low-k interlayer dielectric materials was fabricated by plasma enhanced chemical vapor deposition (PECVD). BTMSM precursor was introduced with the flow rates from 24 sccm to 32 sccm by 2 sccm step in the constant flow rate of 60 sccm $O_2$. Then, SiOCH thin film deposited at room temperature was annealed at temperature of $400^{\circ}C$ and $500^{\circ}C$ for 30 minutes in vacuum. The vibrational groups of SiOCH thin films were analyzed by FT/IR absorption lines, and the dielectric constant of the low-k SiOCH thin films were obtained by measuring C-V characteristic curves. With the result that FTIR analysis, as BTMSM flow rate increase, relative carbon content of SiOCH thin film increased from 29.5% to 32.2%, and increased by 32.8% in 26 sccm specimen after $500^{\circ}C$ annealing. Dielectric constant was lowest by 2.32 in 26 sccm specimen, and decreased more by 2.05 after $500^{\circ}C$ annealing. Also, leakage current is lowest by $8.7{\times}10^{-9}A/cm^2$ in this specimen. In the result, shift phenomenon of chemical bond appeared in SiOCH thin film that BTMSM flow rate is deposited by 26 sccms, and relative carbon content was highest in this specimen and dielectric constant also was lowest value

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The effects of limestone powder and fly ash as an addition on fresh, elastic, inelastic and strength properties of self-compacting concrete

  • Hilmioglu, Hayati;Sengul, Cengiz;Ozkul, M. Hulusi
    • Advances in concrete construction
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    • v.14 no.2
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    • pp.93-102
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    • 2022
  • In this study, limestone powder (LS) and fly ash (FA) were used as powder materials in self-compacting concrete (SCC) in increasing quantities in addition to cement, so that the two powders commonly used in the production of SCC could be compared in the same study. Considering the reduction of the maximum aggregate size in SCC, 10 mm or 16 mm was selected as the coarse aggregate size. The properties of fresh concrete were determined by slump flow (including T500 time), V-funnel and J-ring experiments. The experimental results showed that as the amount of both LS and FA increased, the slump flow also increased. The increase in powder material had a negative effect on V-funnel flow times, causing it to increase; however, the increase in FA concretes was smaller compared to LS ones. The increase in the powder content reduced the amount of blockage in the J-ring test for both aggregate sizes. As the hardened concrete properties, the compressive and splitting strengths as well as the modulus of elasticity were determined. Longitudinal and transverse deformations were measured by attaching a special frame to the cylindrical specimens and the values of Poisson's ratio, initiation and critical stresses were obtained. Despite having a similar W/C ratio, all SCC exhibited higher compressive strength than NVC. Compressive strength increased with increasing powder content for both LS and FA; however, the increase of the FA was higher than the LS due to the pozzolanic effect. SCC with a coarse aggregate size of 16 mm showed higher strength than 10 mm for both powders. Similarly, the modulus of elasticity increased with the amount of powder material. Inelastic properties, which are rarely found in the literature for SCC, were determined by measuring the initial and critical stresses. Crack formation in SCC begins under lower stresses (corresponding to lower initial stresses) than in normal concretes, while critical stresses indicate a more brittle behavior by taking higher values.

Compressive Strength Characteristics of Light-weight Air Foamed Soil Using Dredged Silty Soils (준설 실트질 점토를 이용한 경량기포혼합토의 압축강도 특성)

  • Kim, Donggyu;Yoon, Yeowon;Yoon, Gillim
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.5
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    • pp.27-33
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    • 2017
  • In this research, laboratory tests were carried out to investigate the engineering properties of Light-Weight Air Foamed Soil (LWAS) based on silty clays with the animal foaming agent and cement. LWAS has been used as an embankment material over soft ground for road and side extension of the existing road. In field, unit weight and flow value is measured right after producing in mixing plant in order to control the quality of LWAS, and laboratory tests are carried out to confirm the quality through compressive strength of LWAS as well. In this research, direct estimation of the specification requirement of strength using flow values in field is the main purpose of the study together with other characteristics. From the test results, it can be seen that flow values increase with the initial water content and unit weight increases with the depth due to material segregation. Compared to the upper specimen, lower end of 60 cm specimen shows about 2 times higher compressive strength. Relationship between flow values and normalized factor presented by Yoon & Kim (2004) was presented. With that relationship, compressive strength can be predicted from flow values in field. From the relationship, the normalized factor was calculated. Thereafter calculated compressive strengths according to the flow values were compared to measured strengths in the laboratory. The higher the initial water content of the dredged soil has, the better relationship between predicted and measured shows. Therefore it is necessary to predict the compressive strength in advance through the relationship between the flow value and the normalized factor to reflect it in the design stage.

Conceptual Design on the Marketing Platform for E-Books - The Business Model on the Notion of Social Cooperative - (디지털 출판물 유통 플랫폼 개념설계에 관한 연구 - 사회적 협동조합형 비즈니스 모델 -)

  • Chung, Jun Min
    • Journal of Korean Library and Information Science Society
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    • v.50 no.4
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    • pp.33-55
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    • 2019
  • A marketing platform based on the legal deposit system was designed. It is an e-book distribution platform that systematically binds library networks nationwide by linking with the National Library's deposit system to complete the existing paper that the library should become a publishing platform. The purpose is to bundle e-books into a distribution space and naturally assemble readers to serve as virtual platforms for domestic publishers, authors, bookstores, and platforms running various publishing / subscribing services. The premise is not a sale of e-books, but a rental concept, but the platform is valid regardless. In addition, the platform takes the form of social cooperatives to represent the interests of all members involved in publishing services. The lead-based distribution platform is the most ideal business model to compromise with reality. Conceptually, the service of the publishing content-related industry is a model in which all content is supplied from the lead-bone system, which is a collaborative space, and technically, the central e-book database controls the flow of all content, but the publishing content-related industry takes the form of controlling its flow through virtual.

A Study on Transport Characteristics of MTBE(Methyl Tertiary Butyl Ether) in Soil (MTBE(Methyl Tertiary Butyl Ether)의 토양내 이동특성에 관한 연구)

  • Cho, Ki-Chul;Park, Chang-Woong;Choi, Won-Joon;Kang, Seung-Yub;Hwang, Jong-Hyun;Kim, Youn-Soo;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.2
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    • pp.190-198
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    • 2008
  • In this stduy, the column experiments were carried out assuming the soil was contaminated by leakage of gasoline containing MTBE from USTs and pipes around gas stations. Then, characteristics of MTBE transport in the soil were investigated using CXTFIT program. The column experiments with different soil properties, moisture content, organic matter content and flow rate were carried out. Some parameters(D, R, $\beta$, $\omega$) used in two-site non-equilibrium adsorption model were obtained from measuring the MTBE concentration in injection-liquid and in effluent and using CXTFIT program. In addition, The characteristics of MTBE transport in the soil was found using BTCs and obtained parameters. Consequently, the advection decreased as the increase of the content of fine particle and organic, while the MTBE transport by advection was enhanced as increasing flow rate and moisture content.

A study of Compositional range of Ti-Si-N films for the ULSI diffusion barrier layer (ULSI 확산억제막으로 적합한 Ti-Si-N의 조성 범위에 관한 연구)

  • 박상기;강봉주;양희정;이원희;이은구;김희재;이재갑
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.321-327
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    • 2001
  • Ti-Si-N films obtained by using RF reactive sputtering of targets with various Ti/Si ratios in a $N_2(Ar+N_2)$ gas mixture have been investigated in terms of films resistivity and diffusion barrier performance. The chemical bonding state of Si in the Ti-Si-N film which contained a higher Si content was in the form of amorphous $Si_3N_4$, producing increased film resistivity with increased $N_2$flow rate. Lowering the Si content in the deposited Ti-Si-N film favored the formation of crystalline TiN even at low $N_2$flow rates, and leads to low film resistivity. In addition increasing the N content led to Ti-Si-N films having a higher density and compressive stress, suggesting that the N content in the films appear to be one of the most important factors affecting the diffusion barrier characteristics. Consequently, we proposed the optimum composition in the range of 29~49 at.% of Ti, 6~20 at.% of Si, and 45~55 at.% of N for the Ti-Si-N films having both low resistivity and excellent diffusion barrier performance.

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Control of Grade Change Operations in Paper Plants Using Model Predictive Control Method (모델예측제어 기법을 이용한 제지공정에서의 지종교체 제어)

  • Kim, Do-Hun;Yeo, Yeong-Gu;Park, Si-Han;Gang, Hong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2003.11a
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    • pp.230-248
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    • 2003
  • In this work an integrated model for paper plants combining wet-end and dry section is developed and a model predictive control scheme based on the plant model is proposed. Closed-loop process identification method is employed to produce a state-space model. Thick stock, filler flow, machine speed and steam pressure are selected as Input variables and basis weight, ash content and moisture content are considered as output variables. The desired output trajectory is constructed in the form of 1st-order dynamics. Results of simulations for control of grade change operations are compared with plant operation data collected during the grade change operations under the same conditions as in simulations. From the comparison, we can see that the proposed model predictive control scheme reduces the grade change time and achieves stable steady-state.

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