• Title/Summary/Keyword: constant ratio curve

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The Effects of Cure System on Vulcanization Reaction Constant and Physical Properties of Rubber Compounds (가황시스템 변화가 배합고무의 가황반응속도 및 물리적 특성에 미치는 영향)

  • Lee, Seag;Park, Nam Cook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.419-426
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    • 1999
  • In this study, the reaction rate constant, activation energy, total crosslinking density, elastic constant, cure properties ($t_5,\;t_{90}$), modulus, and abrasion resistance of rubber compounds were investigated as a function of cure temperatures, cure systems and reinforcing filler loadings. Reaction rate constants showed strong dependence on thc carbon black loading, cure temperature and cure system, and increased sharply with increasing the reaction temperatures. The lowest activation energy was obtained in the efficient cure (EC) system which corresponds to the high level of sulfur to accelerator ratio, and the activation energy was decreased with decreasing the carbon black loadings. The change of carbon black loadings directly affects the modulus and abrasion resistance, but the change of cure system showed various effects on the rubber compounds. Increased carbon black loadings showed the high modulus, improved abrasion resistance and short scorch time but decrease in crosslinking density and elastic constant. Higher crosslinking density and elastic constant were shown in the EC cure system regardless of carbon black loadings, but scorch timc ($t_5$) was not affected by the change of the ratio of sulfur to accelerator. Rapid optimum cure time ($t_{90}$) were showen in the EC cure system. Also, the equivalent cure curve coefficient of rubber compound was 0.96 for conventional cure (CC) system, and 0.94 for semi-efficient cure (SEC) and EC system regardless carbon black loadings. As regarding the abrasion resistance, wear volume showed the logarithmic increase for the loaded weight.

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Electrical properties of $Pb(Zr_xTi_{1-x})O_3$ferroelectric thin films prepared by sol-gel processing (Sol-gel법에 의한 $Pb(Zr_xTi_{1-x})O_3$ 강유전 박막의 전기특성)

  • 백동수;박창엽
    • Electrical & Electronic Materials
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    • v.9 no.2
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    • pp.132-137
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    • 1996
  • Pb(Zr$_{x}$Ti$_{1-x}$ )O$_{3}$ solutions prepared by sol-gel processing with different Zr/Ti ratio were coated on Pt/SiO$_{2}$/Si substrates using spin coating method. Coated films were annealed by rapid thermal annealing at 650.deg. C for 20sec to fabricate Pb(Zr, Ti)O$_{3}$ ferroelectric thin films. Electrical properties of the films such as dielectric constant and loss, ferroelectric hysteresis, fatigue, switching time, and leakage current were measured. Hysteresis of the films with different Zr/Ti ratio yield Pr ranging 10-21.mu.C/cm$^{2}$, E$_{c}$ ranging 37.5-137.5kV/cm. Hysteresis curve was changed from square-type to slim type according to increasing Zr contents. Switching time was faster than 180ns, and leakage current was about 20.mu.A/cm$^{2}$. The film underwent above 10$^{8}$ cycles of reversed polarization showed fatigue with increased coercive field and decreased remnant polarization.tion.

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Design and Meshing Analysis of a Non-involute Internal Gear for Counters (계수기용 비인벌류트 치형의 내치차 설계와 물림해석)

  • Lee, Sung-Chul
    • Tribology and Lubricants
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    • v.30 no.4
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    • pp.212-217
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    • 2014
  • A counter gear transmits the rotation angle, so the angular velocity ratio of the gear does not necessarily need to be constant in the meshing process. As a pinion has a small number of teeth when combined with an internal gear for counters, tooth interference can occur with the use of an involute curve. This paper introduces circular arcs that represent a tooth profile and fillet for the profile design of a pinion through the combination of arcs with lines. The straight line of a rack tooth represents the profile of a mating internal gear. Thus, the circular arc and line maintain contact during the rotation of the counter gear. This paper presents an analysis of the meshing of the circular arc tooth and rack tooth along with the properties of the counter gear, such as the change in rotational velocity and amount of backlash. The contact ratio of the counter gear is 1 because the tooth contact occurs between circular arcs and line. The initial position of tooth contact, which denotes the simultaneous contact of two teeth, is found. As the rotation of the pinion, only one tooth keeps the contact situation. This meshing property is analyzed by the geometrical constraints of the tooth profile in contact and the results are presented as graphical diagrams in which tooth-arc movements are superimposed.

The Characteristics of Consolidation and Permeability in Normally Consolidated Region Using a Remolded Decomposed Mudstone Soil (재성형된 이암풍화토를 이용한 정규압밀영역의 압밀 및 투수특성)

  • 김영수;김기영;이상웅
    • Journal of the Korean Geotechnical Society
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    • v.16 no.2
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    • pp.61-70
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    • 2000
  • When clay foundations of embankments are treated with vertical drain, essentially, the strain occurs to vertical direction but the water flow is radial. The initial horizontal permeability and its variation with the vertical compression are key parameters for the choice of the type of drains, their spacing, and affect to the cost of the project. In this study, CRS consolidation test is performed to investigate the anisotropic characteristics of decomposed mudstone soil and direct permeability test is performed on the same specimens. The results of testing show that Ch is larger than Cv. specially, the Cv - $\sigma$v relationship for a soil sample is viewed from three different curve segments corresponding to overconsolidated, transition and normally consolidated states. The anisotropic ratio, rk(kh/kv) is 2.19. Coefficient of permeability in normally consolidated state is related to its void ratio and permeability parameter n. C can be determined from a linear plot of log[k(1+e)] versus log e. The slope, n, of graphs is the same, whereas the vertical intercept, log C, seems to vary somewhat for anisotropic.

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Loosely supported multi-span tube damping according to the support clearance (지지점 간극을 갖는 다점지지 관의 지지점 간극 크기에 따른 감쇠특성 비교)

  • Lee, Kanghee;Kang, Heungseok;Shin, Changhwan;Kim, Jaeyong;Lee, Chiyoung;Park, Taejung
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.402-403
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    • 2014
  • Damping of multi-span tube with loose supports according to the finite support clearances is investigated through the experimental modal analysis. Loose intermediate support leads to strong nonlinearity in tube dynamics, provides statistical nature, and increases tube damping through impacting and friction at the supports. Fraction of critical damping was estimated by the modal curve fitting to parameter estimation from the measured frequency response functions. Magnitude of random excitation force, which can reproduce the in-situ excitation in operating environment, was maintained as constant value with a fine tolerance during vibration testing. Range of input force was carefully selected to cover from the low magnitude excitation for linearly behaved tube motion to high magnitude of force for nonlinearly-behaved tube motion. Estimated critical damping ratio shows scatters in data and tends to increase as the magnitude of rising force and decrease with upward frequency variation. Larger size of support gap increases multi-span tube damping for high magnitude of excitation.

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The Performance Evaluation of Parallel and Single Structure MCMA-MDD Adaptive Equalizer for 16-QAM Signal (16-QAM 신호에대한 병렬 구조와 단일 구조를 갖는 MCMA-MDD 적응 등화기의 성능 평가)

  • Lim, Seung-Gag
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.12 no.4
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    • pp.15-22
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    • 2012
  • This paper deals with the performance comparison and evaluation of blind adaptive equalizer, the PMCMA-MDD and DW-MCMA, that is used for compensation of the amplitude and phase distortion which occurs in the time dispersive channel. Basically, these algorithms are modification of MCMA cost function in order to obtain the fast convergence speed and reduced residual isi by taking the parallel and serial double structured and the combination of the concept of RCA for the updating the tap coefficient. We implements the algorithm of it and compare the recovered constellation, residual isi, MSE characteristics curve and SER in the signal to noise ratio given the time dispersive channel. As a result of simulation, the PMCMA-MDD has a good in recovered constellation than DW-MCMA. But in the SER, the DW-MCMA has a good than PMCMA-MDD.

The Fluorescence Behavior of the Responsive Macrocycle by Aromatic Imine Molecules

  • Choi, Chang-Shik;Jeon, Ki-Seok;Lee, Ki-Hwan
    • Journal of Photoscience
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    • v.11 no.32
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    • pp.71-74
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    • 2004
  • The macrocycle L exhibited a switch on-off behavior through the fluorescent responses by aromatic imine molecule 1 (X=H) / trifluoroacetic acid (TFA). In the 'switch on' state, it was supposed that the aromatic imine molecule 1 is in the cavity of macrocycle L and a photoinduced electron transfer (PET) from the nitrogen of azacrown part to the anthryl group is inhibited by the interaction between the aromatic imine molecule 1 and the azacrown part of macrocycle L. In the 'switch off' state, it was supposed that the protonated imine molecule 1 is induced by the continuous addition of TFA and a repulsion between the protonated azacrown part and the protonated imine molecule 1 is occurred. It was considered that this process induces the intermolecular PET from the protonated imine molecule 1 to the anthryl group of macrocycle L because of a proximity effect between the anthryl group and the protonated imine molecule 1. From the investigation of the transient emission decay curve, the macrocycle L showed three components (3.45 ns (79.72%), 0.61 ns (14.53%), and 0.10 ns (5.75%). When the imine molecule 1 was added in the macrocycle L as molar ratio=1:1, the first main component showed a little longer lifetime as 3.68 ns (82.75%) although the other two components were similar as 0.64 ns (14.28%) and 0.08 ns (2.96%). On the contrary, when the imine molecule 3 (X=C1) was added in the macrocycle L as molar ratio=l:1, all the three components were decreased such as 3.27 ns (69.83%), 0.44 ns (13.24%), and 0.06 ns (16.93%). The fluorescent pH titration of macrocycle L was carried out from pH=3 to pH=9. The macrocycle L and C $U^{2+}$- macrocycle L complex were intersected at about pH=5, while the E $u^{3+}$ -macrocycle L complex was intersected at about pH=5.5. In addtion, we investigated the fluorescence change of macrocycle L as a function of the substituent constant ($\sigma$$_{p}$$^{o}$) showing in the para-substituent with electron withdrawing groups (X=F, Cl) and electron donating groups (X=C $H_3$, OC $H_3$, N(C $H_3$)$_2$), respectively, as well as non-substituent (X=H).).ctively, as well as non-substituent (X=H).

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Propagation Characteristics of Fatigue Microcracks on Smooth Specimen of $2_{1/4}$ Cr-1 Mo Steel ($2_{1/4}$ Cr-1 Mo강의 평활재상의 미소한 표면피로균열의 성장특성)

  • Suh, Chang-Min;Woo, Byung-Chul;Jang, Hui-Rak
    • Journal of Ocean Engineering and Technology
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    • v.4 no.2
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    • pp.250-250
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    • 1990
  • In this paper, fatigue tests were carried out at stress test levels of 461 MPa, 441 MPa, and 431 MPa by using smooth specimen of$2_{1/4}$ Cr-1 Mo steel with the stress ratio(R) of 0.05. The initiation, growth and coalescense process of the major cracks and sub-cracks among the fatigue cracks on the smooth specimen are investigated and measured under each stress level at a constant cycle ratio by the replica technique with optical microscope. Some of the important results are as follows: In spite of the difference of stress levels, the major crack data gather into a small band in the curve of surface crack length and crack depth against cycle ratio N/Nf. The sub-crack data, however, deviate from the band of the major crack. The growth rates, da/dN, of major and sub-crack plotted against the stress intensity factor range, ${\Delta}K$, have the tendency to be compressed on a relatively small band. But it is more effective to predict fatigue life through major cracks. The propagation behavior of surface microcracks on the smooth specimens coincides with that of the specimen having an artificial small surface defect or through crack.

Numerical finite element study of a new perforated steel plate shear wall under cyclic loading

  • Farrokhi, Ali-Akbar;Rahimi, Sepideh;Beygi, Morteza Hosseinali;Hoseinzadeh, Mohamad
    • Earthquakes and Structures
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    • v.22 no.6
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    • pp.539-548
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    • 2022
  • Steel plate shear walls (SPSWs) are one of the most important and widely used lateral load-bearing systems. The reason for this is easier execution than reinforced concrete (RC) shear walls, faster construction time, and lower final weight of the structure. However, the main drawback of SPSWs is premature buckling in low drift ratios, which affects the energy absorption capacity and global performance of the system. To address this problem, two groups of SPSWs under cyclic loading were investigated using the finite element method (FEM). In the first group, several series of circular rings have been used and in the second group, a new type of SPSW with concentric circular rings (CCRs) has been introduced. Numerous parameters include in yield stress of steel plate wall materials, steel panel thickness, and ring width were considered in nonlinear static analysis. At first, a three-dimensional (3D) numerical model was validated using three sets of laboratory SPSWs and the difference in results between numerical models and experimental specimens was less than 5% in all cases. The results of numerical models revealed that the full SPSW undergoes shear buckling at a drift ratio of 0.2% and its hysteresis behavior has a pinching in the middle part of load-drift ratio curve. Whereas, in the two categories of proposed SPSWs, the hysteresis behavior is complete and stable, and in most cases no capacity degradation of up to 6% drift ratio has been observed. Also, in most numerical models, the tangential stiffness remains almost constant in each cycle. Finally, for the innovative SPSW, a relationship was suggested to determine the shear capacity of the proposed steel wall relative to the wall slenderness coefficient.

A Study on Variation of Ultimate Pullout Resistance and Failure Behavior for Vertical Plate Anchors in Sands (앵커의 극한 지지력 변화와 파괴 거동에 관한 연구)

  • 장병욱;황명수
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.32 no.4
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    • pp.71-80
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    • 1990
  • Model tests for the ultimate pullout resistance of anchorages and investigation of failure behaviors in cohesionless soil have been conducted. The factors affecting the anchorage are mostly the geometry of the system, and soil properties of sands. The main conclusions of the experimental work were as follows. 1. The load - displacement relationship can be a form of parabolic curve for all plates. 2. The change in ultimate pullout resistance of anchor is mostly affected by embedment ratio and size of anchor, and influenced to a lesser degree by its shape. 3. Critical embedment ratio which is defined as the failure mode changes from shallow to deep mode is increased with increasing height of anchor. 4. For a constant anchor height, as the width of anchor increases the ultimate pullout resistance also increases. However, considering the efficiency of anchor for unit area, width of anchor does not appear to have any sigrnificant contribution on increasing anchor city. 5. Anchor capacity has a linear relation to sand density for any given section and the rate of change increases as the section increases. Critical depth determining the failure patterns of anchor is decreased with a decrease of sand density. 6. With increasing inclination angle, size of anchor, and decreasing embedment ratio, the ultimate pullout resistance of anchor under inclined loading is significantly decreased. 7. The ultimate pullout resistance of double anchor, a method of improving single of anchor capacity, is influenced by the center - to - center spacing adjacent anchors. It is also found that tandem and parallel anchor rigging arrangements decrease the anchor system capacity to less than twice the single anchor capacity due to anchor interference.

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