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Residue Dissipation Patterns of Neonicotinoid Acetamiprid and Thiamethoxam in Swiss Chard for the Harvest Periods under Greenhouse Conditions (시설재배 근대 중 Neonicotinoid계 살충제 Acetamiprid 및 Thiamethoxam의 생산단계 잔류특성)

  • Chang, Hee-Ra;You, Jung-Sun;Do, Jung-Ah
    • Korean Journal of Environmental Agriculture
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    • v.37 no.2
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    • pp.97-103
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    • 2018
  • BACKGROUND: Dissipation of acetamiprid and thiamethoxam in greenhouse grown chard samples was evaluated at 5 intervals including the pre-harvest interval after application. This study was conducted to determine the residue levels, the biological half-lives and dissipation rate of acetamiprid and thiamethoxam in chard under controlled conditions. METHODS AND RESULTS: Acetamiprid and thiamethoxam were applied in accordance with good agricultural practices for chard. Chard samples were collected at 0, 1, 2, 3, 5, 7, 10 and 14 days after application. Quantitaion was performed by HPLC-DAD system with C18 column. Limit of quantification (LOQ) of acetamiprid and thiamethoxam were both 0.02 mg/kg for chard. The recovery of acetamiprid and thiamethoxam were 77.8~107.5% and 94.3~108.6% at two concentration levels. The half-lives of pesticide dissipation in chard for two fields were 11.9 and 8.2 days for acetamiprid and 3.6 and 3.3 days for thiamethoxam respectively. The dissipation rate of acetamiprid and thiamethoxam were estimated according to the statistics method with a 95% confidence. CONCLUSION: Dissipation of acetamiprid and thiamethoxam in chard were determined under greenhouse. The concentration of acetamiprid and thiamethoxam in chards at 0 days after application were below specified by Korean MRL. Dissipation rate constant will be useful to set the pre-harvest residue limit for public health and consumer protection.

The Comparison of Experimental Results of Liquid Ejector Performance to Predictions by the Computer Aided Design Program (液休용 이젝터 性能에 관한 CAD와 實驗結果와의 比較)

  • 김경근;김명환;홍영표;고상철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.3
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    • pp.520-527
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    • 1988
  • Liquid ejectors are widely used as marine pumps, inducer stage for the boiler feed water pump, boiler recirculating pump, cooling water recirculating pump in boiling water type nuclear reactor and a deep well pump, because of their high working confidence and simplicity. Furthermore, it requires only a modest net positive suction head for cavitation-free operation and it can be installed in remote location from mechanical power source. It is not easy to presume the friction losses, because it is complicately affected by area ratio, flowrate ratio, nozzle spacing, throat length, shape of liquid ejector and so on. Therefore, the optimization of liquid ejector design is still dependent, to a large extent, on the experimental results and empirical procedures. On the design of the liquid ejector, the area ratio and the nondimensional throat length are the most important design factors among the mentioned above. In this experiment, the effects of the area ratio and the nondimensional throat length to ejector efficiency are carried out systematically by the combination of 4 kinds of motive nozzle and 2 kinds of throat length. In this paper, the present experimental results are compared with the calculated ones by the previous computer aided design program based on one dimensional flow equation. And also, an empirical equation for the working limit of liquid ejector is reported.

Residue Dissipation Kinetics and Safety Evaluation of Insecticides on Strawberry for the Harvest Periods in Plastic-covered Greenhouse Conditions (시설재배 딸기의 생산단계에서 살충제 잔류량에 따른 반감기 및 감소상수 산출에 의한 안전성 평가)

  • Chang, Hee-Ra;You, Jung-Sun;Ban, Sun-Woo
    • Korean Journal of Environmental Agriculture
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    • v.39 no.2
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    • pp.122-129
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    • 2020
  • BACKGROUND: Dissipation patterns of insecticides (acequinocyl, clothianidin, diflubenzuron, thiacloprid, and thiamethoxam) on strawberry grown in plastic-covered greenhouse were evaluated at 7 intervals including the preharvest interval after application. This study was performed to determine the residue concentrations, half-lives and dissipation rates in strawberry for the harvest periods. METHODS AND RESULTS: Acequinocyl, clothianidin, diflubenzuron, thiacloprid, and thiamethoxam were applied in accordance with critical good agricultural practices for strawberry. Strawberry samples were collected at 0, 1, 2, 3, 5, 7 and 10 days after application. Quantitaion was performed by HPLC/DAD and HPLC-MSMS system with C18 column. The limit of quantitation (LOQ) values varied between were 0.00025~0.05 mg/kg on strawberry. The recoveries of acequinocyl, clothianidin, diflubenzuron, thiacloprid and thiamethoxam at two concentrations ranged from 70.9~104.9% on strawberry. The half-lives of pesticide dissipation on strawberry for two fields ranged from 1.3~8.2 days. The dissipation rates were evaluated according to the statistics method with a 95% confidence. CONCLUSION: The residue levels of insecticides (acequinocyl, clothianidin, diflubenzuron, thiacloprid, and thiamethoxam) on strawberry at 0-day after application were below the specified values by Korean MRL. To estimate dissipation rate constant of pesticides on crop for harvest periods, it is important to set the pre-harvest residue limit for human health and consumer protection in Korea.

OPΔT and OTΔT Trip Setpoint Generation Methodology (OPΔT 및 OTΔT트립설정치의 생산방법)

  • Ki In Han
    • Nuclear Engineering and Technology
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    • v.16 no.2
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    • pp.106-115
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    • 1984
  • Core safety limits define reactor operating conditions and parameters that will assure fuel rod and reactor system's integrity. Limiting safety system settings (LSSS) programmed into reactor protection system (RPS) then ensure a rapid reactor trip to prevent or suppress conditions which might violate the core safety limits. Generation of the LSSS must properly take into account uncertainties in both calculated and measured parameters in order to assure, with an appropriate degree of confidence, that the RPS will protect the core safety limits. Reviewed in this report are Westinghouse RPS setpoint generation philosophy, methodology of safety limit development and LSSS generation procedure. The Westinghouse RPS trip setpoint generation methodology has been established based on the calculation of core safety limits and the selection of LSSS allowing appropriate uncertainties in a conservative manner. Such conservative values of setpoint assure a high degree of core protection against fuel melting and occurrence of DNB.

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Estimating Permissible Intake Level for Endosulfan Using Benchmark Dose based on Reproductive Tonicity (생식독성과 Benchmark Dose를 활용한 Endosulfan의 노출허용수준 산출)

  • 이효민;윤은경;염영나;황명실;양기화;신효선
    • Toxicological Research
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    • v.18 no.1
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    • pp.65-71
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    • 2002
  • A benchmark dose (BMD) approach has been evaluated us a replacement for the traditional NOAEL methodology currently being wed to assess the noncancer effects of toxicants. The endocrine disrupt-ing effect of endosulfan which showed decrement of sperm count and testicular testosterone level in animals, was currently reported. The amount of endosulfan used as pesticide in the country has been continuously increased. The aim of this study was to suggest the permissible intake level (PIL), corresponding to Accept-able Daily Intake (ADI), based on endocrine disrupting effect wing BMD. Various animal data were collected by consideration of critical effect showing endocrine disruption and an animal data for reproductive toxicity was selected. The Power model from BMD software for induction of $BMD_10$ having meaning which is the dose at the 95% lower confidence limit on a 10% response was used due to that the form of selected dose-response animal data was continuous data. The $BMD_10$ was estimated to be 0.393 mg/kg/day based on reproductive toxicity showing decrement of sperm count. The permissible intake level (PIL) was calculated by dividing the $BMD_10$ by the uncertainty factors of 100 with consideration of from animal to human and human variability. The PIL as 0.004 mg/kg/day was compared with traditional ADI as 0.006 mg/kg/day based on the incidence of marked progressive glomerulonephrosis and blood vessel aneurysm in males.

The Present Condition of Running School-based Enterprises and Tasks in the Future (학교 기업의 운영 현황과 향후 과제 - 경남정보대학 학교 기업 베이커리를 사례로 -)

  • Choi, Seok-Hyun;Choi, Jung-Su
    • Culinary science and hospitality research
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    • v.11 no.4 s.27
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    • pp.164-177
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    • 2005
  • This study is the present condition of running school based enterprises and tasks in the future, based on the 'regulations for establishment and management of school based enterprises' which came into effect in March, 2004. The investigation showed that 80% of respondents knew about the KIT's school-based enterprise, the bakery. And it seems that the fact that the college is running the bakery does not inspire any special confidence in the products. The students doesn't seem to purchase the products as much as staffs and the professors do, so more active promotions are necessary for student customers. The answer we got to the question 'if you enjoy the our bread and cookies, would you recommend them to your friends or family?' shows that some limit to the 'word of mouth marketing.' And increase in sales of the school based enterprise is closely related to how many times the customers visit the bakery. The school-based enterprise is regarded as one of the most effective alternatives to practice filed based education and innovate teaching methods.

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Antimicrobial Activity and Acute Toxicity of Natural Rutin (천연 Rutin의 항균효과와 급성독성에 미치는 영향)

  • Rym, Kyo-Hwan;Eo, Seong-Kug;Kim, Young-So;Lee, Chong-Kil;Han, Seong-Sun
    • Korean Journal of Pharmacognosy
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    • v.27 no.4
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    • pp.309-315
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    • 1996
  • As part of our search for less toxic antimicrobial agents from natural resources, antimicrobial activity of rutin isolated from Sophora japonica was tested in vitro against four kinds of gram positive bacteria and four kinds of gram negative bacteria by serial broth dilution method. Among eight kinds of bacteria tested, the antimicrobial activity of rutin was the most potent against Mycobacterium smegmatis showing MIC of $375\;{\mu}g/ml$. The acute toxicity of rutin was examined in mice and rats. and $LD_{50}$ value administered intraperitoneally in mice was 650 mg/kg(Confidence limit: 894-1,473 mg/kg). There were no significant changes in serum biochemical values and histopathological changes as compared with those of control after intraperitoneal administration with rutin in rats.

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Study on Inhalation Toxicity of 1-Hexene in SD Rats (SD Rats를 이용 1-hexene의 흡입독성 연구)

  • 김현영;임철홍;정용현;이권섭;이성배;이준연;한정희;전윤석;이용묵
    • Environmental Analysis Health and Toxicology
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    • v.16 no.4
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    • pp.211-221
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    • 2001
  • The purpose of this study was to investigate the acute (4 hours) and repeated-dose (6 hours a day, 5 days a week, 4 weeks) toxic effects of 1-hexene on Sprague-Dawley (SD) rats which were treated by inhalation. The results were as follows; 1. The median lethal concentration(LC$_{50}$) was estimated 52,694 ppm (confidence limit 95%; 49,494~55,447 ppm) in acute inhalation. Abnormal clinical signs related to the 1-Hexene were not observed with the acute inhalation dose. Cross findings of necropsy revealed on evidence of specific toxicity related to the 1-hexene. II. By repeated inhalation exposure the body weight of male were more or less reduced by the dose of 2,500 ppm and 5,000 ppm compared with control group. However there were no significant variation hematology and blood biochemistry for the exposed rats compared with the control rats. Abnormal clinical signs and gross findings of necropsy related to the 1-hexene were not shown. In conclusion when we exposed 1-hexene to SD rats for 4 weeks, 5 days per week, 6 hours per day, the Lowest observed effect level (LOEL) was over 2,500 ppm and Non observed effect level (NOEL) was below 500 ppm.

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Uncertainty Quantification of RELAP5/MOD3/KAERI on Reflood Peak Cladding Temperature (재관수 첨두 피복재 온도에 대한 RELAP5/MOD3/KAERI의 불확실성 정량화)

  • Park, Chan-Eok;Chung, Bub-Dong;Lee, Young-Jin;Lee, Guy-Hyung;Lee, Sang-Yong
    • Nuclear Engineering and Technology
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    • v.26 no.3
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    • pp.389-400
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    • 1994
  • The predictability of KAERI version of RELAP5/MOD3 on reflood peak cladding temperature during large break loss-of-coolant accident is assessed against 18 test runs in FLECHT SEASET test data. The associated uncertainty is statistically quantified. The selected test runs include a gravity feed test and several forced feed tests with wide range of the parameters such as flooding rate, system pressure, initial clad temperature, rod bundle power. The results show that the code under-predicts the peak cladding temperature by 7.56 K on average. The upper limit of the associated uncertainty at 95% confidence level is evaluated to be about 99 K, It including the bias due to the under-prediction.

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Quality Evaluation and Shelf-life of Dried Squid (마른 오징어의 품질평가 및 보존기간)

  • YOU Byeong-Jin;LEE Kang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.3
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    • pp.169-176
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    • 1988
  • In order to obtain the objective indices which can assess the quality and the shelf-life of dried squid, nonenzymatic browning, carbonyl value, trimethyl amine (TMA) and trimethyl amine oxide (TMAO) decrease and panel test were determined in dried squid at various water activity levels. When the data of nonenzymatic browning fit a zero order equation, $r^2$ value were more than 0.92 except aw 0.52 for 0.8241. Through variance analysis for the data of browning extent and TMAO decrease, the confidence limits of regression equation were $99\%$ and their limit values of shelf-life were shown 0.45390 O. D./g. solid and 190.322 g/g respectively. In case of TMAO, $r^2$ value was calculated more than 0.95. Linear regression equation for the correlation between browning data and average panel score was Y=0.6138-0.053X and its $r^2$ value was 0.9285. Also in TMAO decrease, the equation was InY=2.0314+0.08269x and $r^2$ value was 0.7854. The shelf-life, evaluated by nonenzymatic browning, TMAO decrease and panel test, was 110-170 days at aw 0.45-0.76 except aw 0.15.

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