• Title/Summary/Keyword: conductivity measurement

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Effects of Capillary Force on Salt Cementation Phenomenon (소금의 고결화 현상에서 모세관 효과)

  • Truong, Q. Hung;Byun, Yong-Hoon;Eom, Yong-Hun;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.26 no.4
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    • pp.37-45
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    • 2010
  • Salt cementation, a typical naturally-cemented phenomenon, may occur due to water evaporation under the change of climate. Capillary force may influence the distribution of cement in granular soils. This study addresses the effect of capillary force on salt cementation using five different techniques: cone penetration test, electrical conductivity measurement, photographic imaging technique, nondestructive imaging technique, and process monitoring by elastic wave. Glass beads modeling a particulate media was mixed with salt water and then dried in an oven to create the cementation condition. Experimental results show that salt cementation highly concentrates at the top of the small particle size specimens and at the middle or the bottom of the large particle specimens. The predicted capillary heights are similar to the locations of high salt concentration in the cemented specimens. Five suggested methods show that the behavior of salt-cemented granular media heavily depends on the capillary force.

Study on the numerical model of complex permittivity of composites based on the percolation theory (퍼콜레이션 이론에 기초한 복합재료의 복소 유전율 모델에 대한 연구)

  • Kim, Jin-Bong;Lee, Sang-Kwan;Kim, Chun-Gon
    • Composites Research
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    • v.22 no.3
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    • pp.44-54
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    • 2009
  • In this paper, we proposed a numerical model the complex permittivity for the E-glass fabric/epoxy composite laminate containing electrical conductive carbon black. The model is based on the percolation theory and for the composites over than the percolation threshold and in higher frequency band in that the AC conductivity is fully proportional to the frequency. The measurement for the complex permittivity wasperformed at the frequency band of 0.5 GHz $\sim$ 18.0 GHz using a vector network analyzer with a 7 mm coaxial air line. The proposed model is composed of the numerical equations of the scaling law used in percolation theory and constants obtained from experiments to quantify the model itself. The model describes the complex permittivity as the function of frequency and filler concentration. The model was verified by being compared with the measurements.

Establishment of an Ice Core Processing Method and Analytical Procedures for Fundamental Proxies (빙하코어의 전처리 방법 및 기초 프록시 분석법 확립)

  • Jun, Seong Joon;Hong, Sang Bum;Hur, Soon Do;Lee, Jeonghoon;Kang, Jung-Ho;Hwang, Hee Jin;Chung, Ji Woong;Jung, Hye Jin;Han, Changhee;Hong, Sungmin
    • Ocean and Polar Research
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    • v.36 no.1
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    • pp.13-24
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    • 2014
  • We established the first complete ice core processing method and analytical procedures for fundamental proxies, using a 40.2 m long ice core drilled on the Mt. Tsambagarav glacier in the Mongolian Altai mountains in July 2008. The whole core was first divided into two sub ice core sections and the measurements of the visual stratigraphy and electrical conductivity were performed on the surface of these sub core sections. A continuous sequence of samples was then prepared for chemical analyses (stable isotope ratios of oxygen ($^{18}O/^{16}O$) and hydrogen ($^2H/^1H$), soluble ions and trace elements). A total of 29 insoluble dust layers were identified from the measurement of visual stratigraphy. The electrical conductivity measurement (ECM) shows 11 peaks with the current more than 0.8 ${\mu}A$ Comparing the profiles of $SO_4{^{2-}}$ and $Cl^-$ concentrations to correlate with known volcanic eruptions, the first two ECM peaks appear to be linked to the eruptions (January and June 2007) of Kliuchevskoi volcano on the Kamchatka Peninsula of Russia, which supports the reliability of our ECM data. Finally, the composition of stable isotopes (${\delta}^{18}O$ and ${\delta}D$) shows a well-defined seasonal variation, suggesting that various chemical proxies may have been well preserved in the successive ice layers of Tsambagarav ice core. Our ice core processing method and analytical procedures for fundamental proxies are expected to be used for paleoclimate and paleoenvironmental studies from polar and alpine ice cores.

An Experimental Study on Characteristics of Averaged Electromagnetic Properties considering Moisture Changes in Cement Mortar (시멘트 모르타르의 수분변화에 따른 평균화된 전자기 특성에 대한 실험적 연구)

  • Kwon, Seung-Jun;Maria, Q. Feng;Na, Ung-Jin
    • Journal of the Korea Concrete Institute
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    • v.21 no.2
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    • pp.199-207
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    • 2009
  • Many researches on electromagnetic (EM) properties like dielectric constant and conductivity are performed since they can be characterized in nonmetallic cement-based material such as mortar and concrete. However, they are much affected by the moisture so that the behaviors of EM properties are to be clearly understood. In this paper, measurements for saturation and EM properties are performed for cement mortar specimens with five different water to cement (W/C) ratios including basic tests like compressive strength and porosity measurement. Every saturated specimens are exposed to room condition and the changes in EM properties caused by decreasing saturation are analyzed. In the saturated condition, higher measurement of EM properties are evaluated in the specimens with higher porosity, however this relationship is adversely changed with drying process. Since the pores without filled water causes the decreases in EM properties, the measurements show stable and linear increment with the lower W/C ratios. Furthermore, the increasing ratios of EM measurements with W/C ratio are shown with saturation and the relationships between them are derived through regression analysis.

Nonstoichiometry and Magnetic Property of the $Nd_{-x}Sr_{x}CoO_{3-y}$ System ($Nd_{-x}Sr_{x}CoO_{3-y}$계의 비화학양론 및 자기적 특성)

  • Chul Hyun Yo;Kwon Sun Roh;Sung Joo Lee;Kyu Hong Kim;Eung Ju Oh
    • Journal of the Korean Chemical Society
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    • v.35 no.3
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    • pp.211-218
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    • 1991
  • A series of samples in the $Nd_{-x}Sr_{x}CoO_{3-y}$ system (x = 0.00, 0.25, 0.50, 0.75 and 1.00) have been produced by heating the reactants at 1200${\circ}$C under atmospheric pressure. The solid solutions were analysed by X-ray diffraction spectra, thermal analysis, and SEM micrographs. X-ray powder diffraction assigns the compositions of x = 0.00, 0.25, 0.50 and 0.75 to the cubic system and the composition of x = 1.00 to the orthorhombic system. The reduced lattice volume is increased with increasing x values in the system. The mole ratio of $Co^{4+}$ or ${\tau}$ values are determined by the Iodometric titration method and are maximum at the composition of x = 0.50. The magnetic measurement shows that a ferromagnetism is appeared in the compositions of x = 0.00, 0.25, 0.50 and 0.75 and then an antiferromagnetism in the composition of x = 1.00. The measurement of the electrical conductivity shows that the semiconductivity is appeared in the composition of x = 0.00, 0.25 and 1.00 and the metallic conductivity in the composition of x = 0.50 and 0.75. The magnetic and electrical properties of the samples are discussed with the nonstoichiometric chemical formulas.

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Synthesis and Characterization of Soluble Polypyrrole with High Conductivity (높은 전기 전도성을 갖는 가용성 폴리피롤 합성 및 특성)

  • Hong, Jang-Hoo;Jang, Kwan-Sik
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.234-238
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    • 2007
  • Highly conducting Polypyrroles soluble in organic solvents were synthesized using functional doping agents, such as mixed dopants [sodium di(2-ethylhexyl)sulfosuccinate (DEHSNa) Naphthalenesulfonic acid (NSA), DEHSNa Toluenesulfonic acid (TSA), DEHSNa Dodecylbenzensulfonic acid (DBSA)] and mixed oxidants [$(NH_4)_2S_2O_8{\cdot}FeCl_3$, $(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$]. Ppy-DEHS powder using an oxidant, such as $(NH_4)_2S_2O_8$ (10 wt%/vol.) showed higher solubility than the mixed dopant (DEHSNa NSA, 3 wt%/vol.) and mixed oxidant [$(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$, 4 wt%/vol.] in DMF solvent. But Ppy-DEHS free standing film using a mixed dopant, such as DEHSNa NSA (16 S/cm) and a mixed oxidant, such as $(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$ (13 S/cm) cast from DMF solvent showed higher electrical conductivity than $(NH_4)_2S_2O_8$ (2 S/cm). For the Ppy-DEHS films using various condition cast from DMF solvent, three dimensional various range hopping model (3D VRH ; $\{{\sigma}_{dc}(T)={\sigma}_oexp[-(T_o/T)^{1/4}]\}$) provided fit to the results of temperature dependence of electrical conductivity measurement.

Far-infrared Emission Characteristics of ZrC Imbedded Heat Storage Knitted Fabrics for Emotional Garment (탄화지르코늄 함유 감성의류용 축열/발열 편물의 원적외선 방출특성)

  • Kim, Hyun-Ah
    • Science of Emotion and Sensibility
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    • v.18 no.1
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    • pp.49-58
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    • 2015
  • This paper investigated far-infrared emission characteristics of ZrC imbedded heat storage knitted fabrics for emotional garment. For this purpose, ZrC imbedded heat storage PET was spun with high viscosity PET imbedded ZrC powder on the core part and low viscosity PET on the sheath part by conjugated spinning method. Ingredient analysis and far-infrared emission characteristics assessment of spun filament were carried out by EDS and FT-IR spectrometer. Two kinds of knitted fabrics were made using texturized ZrC imbedded PET for measuring thermal characteristics of ZrC imbedded heat storage PET. Zr peak was certified by EDS measurement and it was confirmed that content of Zr was 19.29%. Far-infrared analysis revealed that emission power at the range of wavelength, $5{\sim}20{\mu}m$ was $3.65{\times}10^2W/m^2$, and emissivity was 0.906. Heat storage analysis by KES-F7 system revealed that $Q_{max}$ of ZrC imbedded PET knitted fabric was lower than that of regular PET one and warmth keepability rate was higher than that of regular one, which means that ZrC imbedded PET knitted fabric has heat storage property. Thermal conductivity of ZrC imbedded PET knitted fabric was higher than that of regular PET one which was caused by high thermal conductivity of Zr itself. Hand property of ZrC imbedded knitted fabric was not inferior compared to regular PET knitted fabric, which preferably was found to be dependent on knit structure and surface property.

Calculation of Unsaturated Hydraulic Conductivity from Soil Moisture Changes in Pressure-Plate Extractor (Pressure-Plate Extractor 내(內) 토양수분함량(土壤水分含量) 변화(變化)로부터 불포화수리전도도(不飽和水理傳導度)의 계산(計算))

  • Ro, Hee-Myeong;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.1
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    • pp.7-11
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    • 1984
  • A study was carried out to develop a modified Gardner's method, which enabled us to obtain simultaneously both the unsaturated hydraulic conductivities and the moisture retention curves by the use of a soil moisture pressure-plate extractor. The unsaturated hydraulic conductivity was calculated from soil moisture changes under different tension ranges in the pressure- plate extractor by means of Gardner's pressure-plate outflow equation. From 30mbar-tension to 10bar-tension, the unsaturated hydraulic conductivities obtained on three soils (Bonryang sandy loam, Yesan silt loam, and Pogog clay loam) varied $3.09{\times}10^{-2}cm/day{\sim}4.06{\times}10^{-6}cm/day$, $1.34{\times}10^{-2}cm/day{\sim}7.30{\times}10^{-6}cm/day$, and $1.83{\times}10^{-2}cm/day{\sim}8.50{\times}10^{-6}cm/day$, respectively. In comparison with the outflow method, it is inconvenient to perform the periodic determinations of the soil moisture content that require release of the applied Pressure before readjusting the pressure desired for each measurement. Nevertheless, the main advantage of the modified method is that the unsaturated hydraulic conductivities of different soils can be calculated simultaneously with a small amount of each soil sample. It is concluded that the unsaturated hydraulic conductivity can be calculated from soil moisture changes in the soil moisture pressure-plate extractor.

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Study on the Sinterability and Pellet Properties of Dy2O3-TiO2 Oxides (Dy2O3-TiO2 산화물의 소결성 및 소결체 특성에 관한 연구)

  • Kim, Han-Soo;Joung, Chang-Yong;Kim, Si-Hyung;Lee, Byoung-Ho;Lee, Young-Woo;Sohn, Dong-Seong;Lee, Sang-Hyun
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1108-1112
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    • 2002
  • pellets were fabricated as a reactor control material by the powder process. Sinterability of $Dy_2O_3+TiO_2$ mixtures and phases of solid solutions were analyzed by using TMA and XRD, respectively. The thermal conductivity of pellet was determined from the measurement data of the specific heat and the thermal diffusivity of the pellet. The sinterability and the sintered density varied as a function of Dy content in $Dy_xTi_yO_z$. The pellet of $3\;g\;Dy/cm^3\;Dy_xTi_yO_z$ melted in the sintering temperature of $1580{\circ}C$. There were two phases of $Dy_2TiO_5+Dy_2Ti_2O_7$ and a single phase of $Dy_2TiO_5$ for the pellet that has the Dy content of and , respectively. The thermal conductivity of $Dy_xTi_yO_z$ was nearly constant in the temperature range of $25~600{\circ}$. It was 1.69~1.78 W/mK for the pellet sintered in and 1.49~1.55 W/mK for the pellet sintered in $1550{\circ}$.

The growth of GaN on the metallic compound graphite substrate by HVPE (HVPE 방법에 의한 금속 화합물 탄소체 기판 위의 GaN 성장)

  • Kim, Ji Young;Lee, Gang Seok;Park, Min Ah;Shin, Min Jeong;Yi, Sam Nyung;Yang, Min;Ahn, Hyung Soo;Yu, Young Moon;Kim, Suck-Whan;Lee, Hyo Suk;Kang, Hee Shin;Jeon, Hun Soo;Sawaki, Nobuhiko
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.5
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    • pp.213-217
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    • 2013
  • The GaN layer was typical III-V nitride semiconductor and was grown on the sapphire substrate which cheap and convenient. However, sapphire substrate is non-conductivity, low thermal conductivity and has large lattice mismatch with the GaN layer. In this paper, the poly GaN epilayer was grown by HVPE on the metallic compound graphite substrate with good heat dissipation, high thermal and electrical conductivity. We tried to observe the growth mechanism of the GaN epilayer grown on the amorphous metallic compound graphite substrate. The HCl and $NH_3$ gas were flowed to grow the GaN epilayer. The temperature of source zone and growth zone in the HVPE system was set at $850^{\circ}C$ and $1090^{\circ}C$, respectively. The GaN epilayer grown on the metallic compound graphite substrate was observed by SEM, EDS, XRD measurement.