• Title/Summary/Keyword: conductivity effective mass

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Heat transfer enhancement of metal hydride $(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$ for hydrogen storage (수소저장용 금속수소화물$(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$의 전열촉진)

  • Bae Sang-Chul;Yang Yang;Masanori Monde
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.75-80
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    • 2006
  • The effective thermal conductivities of $Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2}$ [TL-492] with hydrogen and helium have been examined. Experiment results show that pressure has great influence on effective thermal conductivity in low pressure range [below 0.5 MPa]. And that influence decreases rapidly with increase of gas pressure. The reason is at low pressure, the mean free path of gas becomes greater than effective thickness of gas film which is important to the heat transfer mechanism in this research. And, carbon fibers have been used to try to enhance the poor thermal conductivity of TL-492. Three types of carbon fibers and three mass fractions have been examined and compared. Naturally, the highest effective thermal conductivity has been reached with carbon fiber which has highest thermal conductivity, and highest mass fraction. This method has acquired 4.33 times higher thermal conductivity than pure metal hydrides with quite low quantity of additives, only 0.99 wt% of carbon fiber. This is a good result comparing to other method which can reach higher effective thermal conductivity but needs much higher mass fraction of additives too.

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Effect of Density-of-States Effective Mass on Transport Properties of Two Converging Valence Bands

  • Kim, Hyun-Sik
    • Journal of the Korean Ceramic Society
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    • v.56 no.3
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    • pp.325-330
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    • 2019
  • Band convergence is known to be effective in improving thermoelectric performance by increasing the Seebeck coefficient without significantly reducing electrical conductivity. Decoupling of the Seebeck coefficient and electrical conductivity in converged bands is the key requirement. Yet, the degree of decoupling depends on the band parameters of the converging bands. Herein, we report theoretical transport properties of two valence bands as their energy difference changes from 0.25 eV to 0 eV. In order to demonstrate the effect of band parameters in transport, we first conducted calculations for the case where the two bands have the same parameters. Then, we conducted the same calculation by doubling the density-of-states effective mass of one valence band. Given that there are two bands, each band's effective mass was doubled one at a time while the other band's effective mass remained constant. We found that the decoupling was strongest when the bands participating in convergence had the same band parameters.

Heat transfer enhancement of metal hydride $(Mm\;(La_{0.6-0.8})\;Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$ for hydrogen storage (수소저장용 금속수소화물$(Mm\;(La_{0.6-0.8})\;Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$의 전열촉진)

  • Bae, Sang-Chul;Yang, Yang;Masanori, Monde
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.33-36
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    • 2006
  • The effective thermal conductivities of $Mm\;(La_{0.6-0.8})\;Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2}$ (TL-492) with hydrogen and helium have been examined. Experiment results show that pressure has great influence on effective thermal conductivity in Low pressure range (below 0.5 MPa). And that influence decreases rapidly with increase of gas pressure. The reason is at low pressure, the mean free path of gas becomes greater than effective thickness of gas film which is important to the heat transfer mechanism in this research. And, carbon fibers have been used to try to enhance the poor thermal conductivity of TL-492. Three types of carbon fibers and three mass fractions have been examined and compared. Naturally, the highest effective thermal conductivity has been reached with carbon fiber which has highest thermal conductivity, and highest mass fraction. This method has acquired 4.33 times higher thermal conductivity than pure metal hydrides with quite low quantity of additives, only 0.99wt% of carbon fiber. This is a good result comparing to other method which can reach higher effect ive thermal conductivity but needs much higher mass fraction of additives too.

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Adaptive Estimation of Hairy Root Mass Using Conductometry

  • Kim, Ji-Hyeon;Yoo, Young-Je
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.641-646
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    • 2003
  • An accurate and efficient method for measuring the mass of hairy roots using conductometry is established. A conductivity equation expressed in terms of the concentration of the ion species in the medium is suggested. By using this equation, the effect of the individual ions on the total conductivity can be quantitatively analyzed. An equation for the in situ estimation of the cell growth coefficient for determining the mass of hairy roots is established based on measurements of the nitrogen concentration and conductivity during cultivation. The proposed equation does not require preliminary experiments to determine the cell growth coefficient. Instead, the physiological characteristics of the plant species are reflected by introducing the cellular nitrogen content. Since the cell growth coefficient is determined by measuring the major ionic nutrient concentrations, it is more effective to express the dynamics of an actual culture system. This improved method for determining the mass of hairy roots was successfully utilized in a fed-batch culture system.

The effects of particle shape on the effective thermal conductivity enhancement of nanofluids (나노유체 입자상 모양의 유효 열전도도에의 영향)

  • Koo, June-Mo;Kang, Yong-Tae
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2106-2109
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    • 2008
  • Nanofluids have been studied as possible alternatives for heat transfer fluids to improve the efficiency of heat exchangers. There are deviations of measured effective thermal conductivities between research-groups, and the mechanisms of the effective thermal conductivity enhancement of nanofluids are not confirmed yet. In this study, the effects of particle shape on the effective thermal conductivity enhancement are discussed and presented as a possible explanation of the deviations. The particle motion effect is found to be negligible for nanofluids of high aspect ratio cylindrical particles, which is believed to be important for nanofluids of spherical particles, while the percolation network formation and contact resistance play dominant roles in determining the effective thermal conductivity.

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Experimental und Numerical Sensitivity Analyses on Push Pull Tracer Tests

  • Hwang, Hyeon-Tae;Lee, Gang-Geun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.312-316
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    • 2004
  • Single-well tracer tests, especially push pull tracer tests, are more effective to estimate hydraulic parameters and microbial metabolic activities in terms of duration and cost compared to multi-well tracer tests. However, there are some drawbacks in accuracy, complicated data analysis and uniqueness. These shortages are thought to be derived from the applied conditions which affect mass recovery curve and breakthrough curve. Factors such as extraction rate, resting period, hydraulic conductivity and hydraulic gradient are considered as the major factors determining the mass recovery rate and shape of the breakthrough curve. The results of the sensitivity analysis are summarized as follows: 1) the significant change in concentration of breakthrough curve is obtained when the extraction rate increases. This effect would also be much higher if the hydraulic conductivity is lower; 2) the mass recovery rate decreases with the increase of resting time, and the difference of mass recovery rates for different resting times is inversely proportional to the hydraulic conductivity; 3) the sensitivity values decrease with time. The hydraulic conductivity affects not only the early period, but the later period of the breakthrough curves; 4) The influence of the hydraulic gradient on the breakthrough curves is greater at earlier stage than at later stage. The mass recovery rate is inversely proportional to the hydraulic gradient.

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The density-of-states effective mass and conductivity effective mass of electrons and holes in relaxed or strained Ge and ${Ge_{0.8}}{Sn_{0.2}}$ (완화된 또는 응력변형을 겪는 Ge과 ${Ge_{0.8}}{Sn_{0.2}}$에서 전자와 정공의 상태밀도 유효질량과 전도도 유효질량)

  • 박일수;전상국
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.8
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    • pp.643-650
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    • 2000
  • Density-of-states effective mass(m*$_{d}$) and conductivity mass(m*$_{c}$)for Ge and Ge$_{0.8}$/Sn$_{0.2}$ are obtained by using 8$\times$8 k.p and strain Hamiltonians. It is shown that m*$_{d}$ and m*$_{c}$ for electrons in Ge/Ge$_{0.8}$/Sn$_{0.2}$(001) and Ge$_{0.8}$/Sn$_{0.2}$/Ge(001) are much smaller than those for electrons in relaxed Ge mainly due to the increase of interaction caused by the strain between the conduction band and valence bands at the $\Gamma$ point. The lift of degeneracy in Ge/Ge$_{0.8}$/Sn$_{0.2}$(001) and Ge/Ge$_{0.8}$/Sn$_{0.2}$(001) makes m*$_{d}$ and m*$_{c}$ for holes smaller than those in relaxed Ge and results in the decrease of the interband scattering as well as interband scattering. The decrease of the interband scattering is more obvious in Ge/Ge$_{0.8}$/Sn$_{0.2}$(001) because of its large splitting energy between the heavy hole and light hole band. Therefore, Ge/Ge$_{0.8}$/Sn$_{0.2}$(001) is expected to be good candidate for the development of ultra high-speed CMOS device.CMOS device.eed CMOS device.CMOS device.

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Estimation of the Effective Hydraulic Conductivity in the Granite Area as an Equivalent Continuum Medium (등연속체매질로서의 화강암지역의 유효수리전도도 산출)

  • 김경수;김천수;배대석
    • The Journal of Engineering Geology
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    • v.12 no.3
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    • pp.319-332
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    • 2002
  • This study is focused on the characterization of an effective hydraulic conductivity in each hydrogeologic unit assumed as an equivalent continuum medium in the granitic area. Four boreholes of 3" diameter were installed and a Multi-packer system was facilitated in the selected borehole. Various in-situ tests including the fracture logging, constant injection and fall-off tests, slug and pulse tests were carried out. A hydrogeologic unit was defined into the upper and lower zones based on the variation of fracture properties and hydraulic conductivities. The difference of the result obtained by the various hydraulic tests and the effective characterization techniques on rock mass permeability are also discussed. The effective hydraulic conductivity of the upper unit was measured by two times(5.27E-10 m/s~7.57E-10 m/s) that of the lower unit(2.45E-10 m/s~6.81E-10 m/s)through the constant injection and fall-off tests.

An Experimental Study of Frost Formation on the Horizontal Cylinder (수평 실린더 표면의 착상에 대한 실험적 연구)

  • Paik, Sang-Jin;Lee, Yoon-Been;Ro, Sung-Tack
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.240-245
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    • 2000
  • In this study, thickness, density and effective thermal conductivity of frost forming on the horizontal cylinder were measured with various air temperature and humidity. Reynolds number and temperature of cooling surface are controlled 17300 and $-l5^{\circ}C$ respectively. In each case of air temperature $5^{\circ}C,\;10^{\circ}C,\;15^{\circ}C,$ varying absolute humidity, experiments were executed. In measuring frost surface temperature and thickness of frost layer, infrared thermocouples and CCD camera were used. Frost was gathered from cylinder to measure mass of frost layer. Experimental data showed that the thickness and effective thermal conductivity of the frost layer increase with respect to time. Thickness of frost layer increase with humidity increasing, and density of frost layer increase with air temperature rising. Frost growth with air temperature and density of frost layer with humidity are affected by whether dew point is below or above freezing point.

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A Simple Condensation Model on the Vapor Jets in Subcooled Water (과냉각수로 방출되는 증기제트의 응축모델)

  • Kim, Hwan-Yeol;Ha, Kwang-Soon;Bae, Yoon-Yeong;Park, Jong-Kyun;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.240-245
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    • 2001
  • Phenomena of direct contact condensation (DCC) heat transfer between steam and water are characterized by the transport of heat and mass through a moving steam/water interface. Application of the phenomena of DCC heat transfer to the engineering industries provides some advantageous features in the viewpoint of enhanced heat transfer. This study proposes a simple condensation model on the steam jets discharging into subcooled water from a single horizontal pipe for the prediction of the steam jet shapes. The analysis model was derived from the mass, momentum and energy equations as well as a thermal balance equation with condensing characteristics at the steam/water interface for the axi-symmetric coordinates. The extremely large heat transfer rate at the steam/water interface was reflected in the effective thermal conductivity estimated from the previous experimental results. The analysis results were compared with the experimental ones. The analysis model predicted that the steam jet shape (i. e. radius and length) was increasing as the steam mass flux and the pool temperature were increasing, which was similar in trend to that observed in the experiment.

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