• Title/Summary/Keyword: conductivity/resistivity

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Electrical Characteristics of Li(Mn$_{1-}$$\delta$Nb$\delta$)$_2$O$_4$ Cathode Materials for Li-Ion Secondary Batteries (리튬 이온 이차전지 Cathode용 Li(Mn$_{1-}$$\delta$Nb$\delta$)$_2$O$_4$의 전기적 특성)

  • 오용주;유광수
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.995-1001
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    • 1998
  • As a basic study for cathode materials of {{{{ { {LiMn }_{2 }O }_{4 } }}-based lithium-ion secondary batteries Li({{{{ { { { {Mn }_{1-$\delta$ }Nb }_{$\delta$} )}_{2 }O }_{4 } }} ($\delta$=0.05, 0.1, 0.2) materials which Nb is substituted for Mn were synthesized by the solid state reaction at 80$0^{\circ}C$ and 110$0^{\circ}C$ respectively. The second phase {{{{ { LiNbO}_{3 } }} appeared above $\delta$=0.1 As the result of im-pedance analysis as the amount of substituted Nb increased the resistivity of grain boundary increased greatly. Compared to undoped-{{{{ { {LiMn }_{2 }O }_{4 } }} the electrical conductivity of Li({{{{ { { { {Mn }_{1-$\delta$ }Nb }_{$\delta$} )}_{2 }O }_{4 } }} decreased slightly but is charging capacity and potential plateau increased.

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Field Emission Property of ZnO Nanowire with Nanocone Shape (나노뿔 형태로 제작된 ZnO 나노선의 전계방출 특성)

  • No, Im-Jun;Shin, Paik-Kyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.4
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    • pp.590-594
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    • 2012
  • ZnO nanowires were fabricated by hydrothermal synthesis technique for field emission device application. Al-doped zinc oxide (AZO) thin films were prepared as seed layer of catalyst for the ZnO nanowire synthesis, for which conductivity of the seed layer was tried to be improved for enhancing the field emission property of the ZnO nanowire. The AZO seed layer revealed specific resistivity of $ 7.466{\times}10^{-4}[{\Omega}{\cdot}cm]$ and carrier mobility of 18.6[$cm^2$/Vs]. Additionally, upper tip of the prepared ZnO nanowires was treated by hydrochloric acid (HCl) to form a nanocone shape of ZnO nanowire, which was aimed for enhanced focusing of electric field on that and resultingly to improve field emission property of the ZnO nanowires. The ZnO nanowire with nanocone shape revealed decreased threshold electric field and increased current density than those of the simple ZnO nanowires.

Nanocrystalline Materials-an Overview

  • Suryanarayana, C.
    • Journal of Powder Materials
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    • v.3 no.4
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    • pp.233-245
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    • 1996
  • Nanocrystalline materials, with a grain size of typically <100 nm, are a new class of materials with properties vastly different from and often superior to those of the conventional coarse-grained materials. These materials can be synthesized by a number of different techniques and the grain size, morphology, and composition can be controlled by controlling the process parameters. In comparison to the coarse-grained materials, nanocrystalline materials show higher strength and hardness, enhanced diffusivity, improved ductility/toughness, reduced, density, reduced elastic modulus, higher electrical resistivity, increased specific heat, higher coefficient of thermal expansion, lower thermal conductivity, and superior soft and hard magnetic properties. Limited quantities of these materials are presently produced and marketed in the US, Canada, and elsewhere. Applications for these materials are being actively explored. The present article discusses the synthesis, structure, thermal stability, properties, and potential application of nanocrystalline materials.

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A Development of Coatable Conductive Polymer (코팅가능한 전도성 고분자 개발)

  • 김종은;심재훈;서광석;윤호규;구자윤;박영인
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.223-226
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    • 1998
  • Organic conducting N-methyl phenazinium TCNQ (7,7,8,8-tetracyanoquinonedimethane) ion radical salt was synthesized and characterized by FTIR, EA. After blending this material with PMMA using NMP/DMF, the solution was bar-coated on a PET film and dried at 40$^{\circ}C$. The optical micrograph showed the fibril crystals. The surface resistivity was 10$\^$5/ $\Omega$/$\square$. The conductivity decreased considerably at temperatures above 80$^{\circ}C$, although it decreased slightly at RT and 4$^{\circ}C$.

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The composition control of ITO/PET by plasma emission monitor (PEM을 이용한 ITO/PET film의 조성 제어)

  • 한세진;김용환;김영환;이택동
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.438-444
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    • 1999
  • The characterization of the reactively sputtered ITO layer on the PET film has been studied. The PEM device has been used to determine the optimum stoichimetry through control of the amount of oxygen incorporated into the alloy target and the optimum operation conditions to produce films with the highest electrical conductivity and visible transparency. The PEP film was pre-treated under the plasma discharge condition to remove the adsorbed gases and to modify the surface morphology. The results revealed that by adjusting the flow rate of oxygen with the spectral intensity of indium target, the composition of plasma gas can be kept constant during the entire deposition period. The resistivity of ITO film obtained was fond to be about 37$\Omega\Box$, and the transmittance of visual range was about 86%.

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A Poling Study on a Piezoceramic/Polymer 0-3 Composites for Hydrophone Applications (Hydrophone 응용을 위한 Piezoceramic/Polymer 0-3 Composite의 분극 개선)

  • Lee, S.H.;Cho, H.C.;SaGong, G.;Seul, S.D.;Koo, H.B.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.349-352
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    • 1989
  • Poling piezoelectric ceramic-polymer composites with 0-3connectivity is difficult because of the high dielectric constant of most of the ferroelectric filler materials, and the high resistivity of the polymer matrix. To aid in poling this type of composite, conductivity of the polymer phase can be controlled by adding small amount of a semiconductor phase such as germanium, carbon or silicon. In this study, flexible piezoelectric composites of $PbTiO_3$ powder and Eccogel polymer were developed using small amounts of a semiconducting phase. These composites were poled rapidly at low voltages, resulting in properties superior to composites prepared without a conductive phase. The effect of addition of various conductive phase with different volume percentage on the dielectric and piezoelectric properties of the composite are discussed here.

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The degradation of insulation oil in power transformers by the evolution of gases, Tan $\delta$, moisture and total acid number (가스량, Tan $\delta$, 수분량, 전산가에 의한 유침 전력 변압기의 열화현상에 관한 연구)

  • Choi, Jong-Kab;Han, Min-Koo;Kwon, Tae-Won;Yun, Yong-Bum
    • Proceedings of the KIEE Conference
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    • 1989.11a
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    • pp.159-163
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    • 1989
  • The various degradation phenomena, such as the evolution of gases, tan $\delta$, moisture content and total acid number in power transformer insulation oil, have been measured and analyzed. Mineral oil has been degraded at laboratory by the forced thermal stress of $60^{\circ}C$ and $90^{\circ}C$ respectively. Thermal aging oil has been degraded about 17, 34, 72 days. Also, we extracted insulation oil from working transformers. We measured gases dissolved in samples, tan $\delta$, moisture content, total acid number. Activation energy and resistivity is calculated from them. It is found that gases and tan $\delta$ increases as partial discharge and total acid number increases and that conductivity of the sample increases as activation energy increases.

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Electrical properties of sintered $HoSi_2$ ($HoSi_2$ 소결체의 전기적 특성 연구)

  • Lee, Woo-Sun;Oh, Guem-Kon;Kim, Hyung-Gon
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1396-1398
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    • 2001
  • The $HoSi_2$ compounds prepared by codeposition of Si and Ho, and $HoSi_2$ by sintering method were investigated electrical and Hall effect. The crystal structure of samples showed a orthorhombic structure, and lattices constant is a=9.8545 $\AA$, b=7.7935 $\AA$, c=7.8071 $\AA$. Hall effect shows a n-type conductivity in the sintered $HoSi_2$. The electrical resistivity values was 1.608${\Omega}cm^{-1}$ and carrier mobility was $6.9{\times}10^1cm^2/V{\cdot}sec$ at low room temperature.

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Optical and electrical properties of ${\beta}-FeSi_2$ single crystals (${\beta}-FeSi_2$ 단결정의 전기적 광학적인 특성)

  • Kim, Nam-Oh;Kim, Hyung-Gon;Lee, Woo-Sun;Son, Kyung-Chun
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1500-1502
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    • 2001
  • Plate-type ${\beta}-FeSi_2$ single crystals were grown using $FeSi_2$, Fe, and Si as starting materials by the chemical transport reaction method. The ${\beta}-FeSi_2$ single crystal was an orthorhombic structure. The direct optical energy gap was found to be 0.87eV at 300K. Hall effect shows a n-type conductivity in the ${\beta}-FeSi_2$ single crystal. The electrical resistivity values was 1.608$\Omega$cm and electron mobility was $3{\times}10^{-1}cm^2/V{\cdot}sec$ at room temperature.

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The Hall Effect in Binary Compound Silver telluride Single Crystal (2원화화물 $Ag_2Te$ 단결정의 Hall 효과 특성)

  • Kim, N.O.;Kim, H.G.;Jang, S.N.;Lee, K.S.;Bang, T.W.;Hyun, S.C.
    • Proceedings of the KIEE Conference
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    • 2004.07e
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    • pp.134-136
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    • 2004
  • The results of investigations of $Ag_2Te$ crystal is presented. $Ag_2Te$ crystal was grown by the Bridgman method. The $Ag_2Te$ crystal was an monoclinic structure with lattice constance a = 8.1686 A, b = 9.0425 ${{\AA}}$, c = 8.0065 ${{\AA}}$. Hall effect shows a n-type conductivity in the $Ag_2Te$ crystal. The electrical resistivity values was $1.080e^{-3}{\Omega}cm$ and electron mobility was $-5.48{\times}10^3cm^2/V{\cdot}sec$ at room temperature(RT).

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