• Title/Summary/Keyword: conductive polymer

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Commercialization & Process Optimization of Protective Film on Nano Silver Transparent Conductive Substrate by Means of Large Scale Roll-to-Roll Coating and Experimental Design (나노실버 투명전도소재 보호필름의 개발 및 공정 최적화와 실험 계획법을 이용한 검증)

  • Park, Kwang-Min;Lee, Ji-Hoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.813-820
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    • 2015
  • We have studied commercialization and process optimization of protective film on transparent conductive coated substrate, nano silver on flexible PET (poly ethylene terephthalate), by means of roll-to-roll micro-gravure coater. Nanosilver on flexible PET substrate is potential materials to replace ITO (indium tin oxide). Protective film is most important to maintain unique silver pattern on top of transparent PET. PSA pressure sensitive adhesives) was developed solely for nano silver on PET and protective film was successfully laminated. We have optimized all process conditions such as coating thickness, line speed and aging time & temperature via experimental design. Transparent conductive film and its protective film developed in this research are commercially available at this moment.

Preparation and Physical Properties of Conductive Poly(acrylonitrile) Fabrics Containing Polypyrrole (폴리피롤을 이용한 전도성 아크릴 직물의 제조 및 물성)

  • 이영관;조재춘
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.276-280
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    • 2000
  • A conductive poly(acrylonitrile)/polypyrrole composite fabric was prepared. A conductive composite was prepared by the impregnation of PAN fabric into a mixed solution of pyrrole and oxidant in order to induce the in-situ polymerization of a conducting polymer into the matrix fabric. In the composite formation, the reaction condition was optimized to achieve the best properties, and the effect of the externally-added arylsulfonate dopants on the physical properties was examined. As a result, the best properties of electrical conductivity, thermal stability, and fastness to washing, was observed in the composite containing an antraquinonesulfonate (AQSA) dopant.

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Chemical and Electrochemical Synthesis of Highly Conductive and Processable PolyProDOP-alkyl Derivatives

  • Cho, Youn-Kyung;Pyo, Myoung-Ho;Zong, Kyu-Kwan
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.57-62
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    • 2010
  • New monomers, possessing various alkyl substituents on propylene dioxypyrrole, were synthesized. The monomers could be easily polymerized to produce highly conductive and soluble polymers. The corresponding polymers showed excellent solubility, retaining electrochemical and optical properties of their parent polymer [poly(propylene dioxypyrrole)]. The conductivities of chemically prepared polymers were quite high in a range of 20 and $60\;Scm^{-1}$. Solubility of the polymer in a common organic solvent was as high as no polymer is deposited on an electrode. The redox potentials of the electrochemically prepared polymers revealed quite stable electro-activity during repeated redox switching up to 500 times. The optoelectrochemistry studies also showed distinct color changes of the polymers upon changing the doping state, indicating strong absorption peaks at 400~600 nm in reduced states and complete bleaching in fully oxidized states.

A Study of Polymer Heater Using Conducting Polymer (Polyaniline의 합성과 이를 이용한 고분자 발열체에 관한 연구)

  • 임동준;임석범;양준모;김은옥;김영호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.802-805
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    • 2001
  • Conductive polymer is insulator or semiconductor in initial state. Polyaniline(PANI) is a $\pi$-conjugated polymer that shows electric property changes, when it is contact with oxidant/reductor chemicals. Synthesis of polyaniline is used vacuum evaporation method, using by (NH$_4$)$_2$O$_{8}$과 NMP, NH$_2$NH$_2$, HCl, MH$_4$OH, etc. Doped PANI is used such a resistor, addition to graphite is increased conductivity. Applying contact voltage, samples show constant current and contact temperature.e.

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Study on Mechanical and Electrical Properties of Expanded Graphite/Carbon fiber hybrid Conductive Polymer Composites (팽창흑연/탄소섬유 혼합 보강 전도성 고분자 복합재료의 특성 평가)

  • Oh, Kyung-Seok;Heo, Seong-Il;Yun, Jin-Chul;Han, Kyung-Seop
    • Composites Research
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    • v.20 no.6
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    • pp.1-7
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    • 2007
  • Expanded graphite/carbon fiber hybrid conductive polymer composites were fabricated by the preform molding technique. The conductive fillers were mechanically mixed with a phenol resin to provide an electrical property to composites. The conductive filler loading was fixed at 60wt.% to accomplish a high electrical conductivity. Expanded graphites were excellent in forming a conductive networking by direct contacts between them while it was hard to get the high flexural strength over 40MPa with using only expanded graphite and phenol resin. In this study, carbon fibers were added in composites to compensate the weakened flexural strength. The effect of carbon fibers on the mechanical and electrical properties was examined according to the weight ratio of carbon fiber. As the carbon fiber ratio increased, the flexural strength increased until the carbon fiber ratio of 24wt.%, and then decreased afterward. The electrical conductivity gradually decreased as the increase of the carbon fiber ratio. This was attributed to the non-conducting regions generated among the carbon fibers and the reduction of the direct contact areas between expanded graphites.