• Composites Research
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• 제35권1호
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• pp.47-51
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• 2022

전자기기 발열을 효율적으로 제어하기 위해 열전도성 복합재료에 대한 많은 연구가 진행되고 있다. 본 연구에서는 solvent 별 분산에 따른 carbon fiber의 배열성 관계를 알아보기 위해 Milled Carbon Fiber를 4가지 Solvent에 분산하고 Vacuum filtration 방법을 통해 탄소섬유강화 복합재료(CFRP)를 제작하였다. CFRP의 배열성을 알아보기 위해 광학현미경 관측과 섬광법을 통한 열전도도를 측정하였다. NMP와 Ethanol을 Solvent로 사용하여 성형한 CFRP의 평면두께방향 열전도도가 각각 10.79 W/mK, 10.57 W/mK 값을 보였고 이는 평면내부방향 열전도도에 비해 218%, 209% 향상된 결과를 보였다. Solvent의 상대적으로 높은 점도 값은 solvent 유체의 높은 전단력에 영향을 주어 성형 시 필러의 배열성을 결정하는데 영향을 주는 것으로 판단된다.

• 한국전기전자재료학회논문지
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• 제36권4호
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• pp.303-325
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• 2023

Flexible fiber- or yarn-based one-dimensional (1-D) energy storage devices are essential for developing wearable electronics and have thus attracted considerable attention in various fields including ubiquitous healthcare (U-healthcare) systems and textile platforms. 1-D supercapacitors (SCs), in particular, are recognized as one of the most promising candidates to power wearable electronics due to their unique energy storage and high adaptability for the human body. They can be woven into textiles or effectively designed into diverse architectures for practical use in day-to-day life. This review summarizes recent important development and advances in fiber-based supercapacitors, concerning the active materials, fiber configuration, and applications. Active materials intended to enhance energy storage capability including carbon nanomaterials, metal oxides, and conductive polymers, are first discussed. With their loading methods for fiber electrodes, a summary of the four main types of fiber SCs (e.g., coil, supercoil, buckle, and hybrid structures) is then provided, followed by demonstrations of some practical applications including wearability and power supplies. Finally, the current challenges and perspectives in this field are made for future works.

• 설비공학논문집
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• 제25권11호
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• pp.595-599
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• 2013

The pipes used in buildings are generally categorized into metallic or plastic materials. Metal pipes, such as copper and stainless steel pipes, are mainly used for water and hot water supply, and for the heating system. However, plastic pipes made of polyethylene and cross-linked polyethylene are used for floor heating, water drainage, and air vent systems. Usually, plastic pipes have thermal demerits, such as high linear expansion coefficients and bending phenomenon by hot water, although the pipes have several merits of light weight, low price, low thermal conductivity, and the comparatively high workability of metal pipes. Therefore, if those kind of demerits are overcome, plastic pipes can be easily accepted for hot water systems. This research is aimed to evaluate the applicability for vertical heating pipes of a plastic pipe system consisting of electric fusion fitting of a conductive carbon compound and propylene random glass fiber pipe, through measurement of the expansion rate and leakage in summer and winter seasons, in the apartment construction field.

• 한국건설순환자원학회논문집
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• 제11권1호
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• pp.48-54
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• 2023

본 연구에서는 금속성분을 다량 함유한 전기로산화슬래그(EOS)를 골재로 활용한 콘크리트에 도전성이 높은 카본계 재료를 혼입하여 현장적용이 가능한 EMP 차폐 콘크리트의 최적배합을 도출하고자 기초적인 물성과 두께별 EMP 차폐성능을 평가하였다. 평가결과 슬럼프는 카본섬유(CF)의 혼입량이 증가할수록 저하, 밀드카본(MCF) 혼입시 증가하는 것을 확인할 수 있었다. 압축강도는 EOS가 NA에 비해 강도를 증진시키는 것을 확인할 수 있었으며, CF 및 MCF 혼입시 강도가 저하되는 것을 확인할 수 있었다. EMP 차폐 측정결과 두께가 증가할수록 차폐율이 증가하였으며, 도전성 재료의 첨가량보다 도전성 재료의 종류 및 시험체의 두께가 차폐율 증가에 영향력이 더 큰 것을 확인할 수 있었다. 종합적으로 비교평가를 진행한 결과 EMP 차폐 콘크리트 배합으로 EOS CF 0.2가 적합한 것으로 사료된다.

• 전기전자학회논문지
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• 제13권2호
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• pp.216-219
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• 2009

$V_2O_5$ 나노선/폴리비닐 알코올(PVA) 고분자 복합체를 나일론 제조법을 응용하여 제작하였고 전기적 특성을 연구하였다. PVA가 아세톤, 에탄올, 메탄올 등의 벤젠기와 반응하여 얇은 막을 형성하는 것을 이용하여 나일론 섬유 제작방법과 유사하게 실타래를 감아올려 나노선 섬유가 섞인 폴리머 섬유를 만들었다. 폴리머-나노선 복합체는 내부에서 전도성이 있는 $V_2O_5$나노선 다발이 네트워크를 형성하기 때문에 전자기장을 차폐할 수 있는 고분자 섬유 등에 적용할 수 있다.

• 한국응용과학기술학회지
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• 제32권3호
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• pp.405-411
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• 2015

Carbon composites for flexible fiber heating element were examined to improve the electrical conductivity in this study. Carbon composites using carbon black, denka black, super-c, super-p with/without CNF or dispersant such as BCS03 and Sikament-nn were prepared. Carbon composite slurry was coated on plane film and yarns(cotton, polyester) and the performances of prepared heating materials were investigated by checking electrical surface resistance, adhesion strength. The plane heating element using carbon black under natural drying condition($25^{\circ}C$) had better physical properties such as surface resistance(185.3 Ohm/sq) and adhesion strength(above 90%) than those of other carbon composite heating elements. From these results, polyester heating element coated by carbon black showed better electrical line resistance(33.2 kOhm/cm) than cotton heating element. Then, it was found that polyester heating element coated by carbon black with CNF(3 wt%) and BCS03(1 wt%) appeared best properties(0.604 kOhm/cm).

• Advanced Composite Materials
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• 제16권1호
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• pp.1-10
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• 2007

Composite materials consisting of crushed carbon fiber reinforced plastics (CFRP) pieces and acrylonitrile-butadiene-styrene (ABS) resin were prepared by an injection mold method to solve the problem of recycling of CFRP. The electrical properties, such as electrical resistivity, alternating current impedance and electromagnetic interference (EMI) shielding effect, were measured for the composites. The electrical resistivity of the composites showed a percolation type of conduction behavior and no difference between parallel and perpendicular to the injection direction was observed for CFRP content higher than the critical value. Measurement of alternating current impedance revealed that the conduction mechanism is attributed to the direct conductive paths generated by distributed carbon fibers; however, strong frequency dependence of the impedance was observed for the CFRP content near the critical one. The frequency dependence of the impedance is caused by the inter-fiber connection and can be expressed as a simple equivalent circuit. The absorption component of shielding effect (SE) was smaller than the expected value estimated from its resistivity. The decline of SE is thought to be caused by the decrease in effective thickness due to fiber orientation.

• Composites Research
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• 제27권3호
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• pp.83-89
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• 2014

본 연구는 엔지니어링 플라스틱인 Polybutylene terephthalate(PBT)에 첨가물을 넣어 강도와 열전도성, 열충격내구성을 개선시키는 것을 목적으로 한다. 그에 따라 PBT에 유리섬유(Glass Fiber)와 Boron nitride(BN)을 복합적으로 첨가하여, 각각의 조성비에 따른 기계적 특성과 열전도 특성변화를 실험적으로 분석하였다. 시험 결과 BN의 함유량이 증가함에 따라 열전도도는 증가하였고, 기계적 강도는 작아졌다. 열충격싸이클을 가한 결과, 비충전 PBT는 파단 신장률이 작아졌으나 충전 PBT는 강도와 열전도율이 별다른 성질변화가 거의 없었다. BN의 첨가에 따라 PBT 복합재의 열전도도도는 크게 향상되었다.

• Fibers and Polymers
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• 제7권2호
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• pp.89-94
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• 2006

Ionic conductivity and mechanical properties of a mixed polymer matrix consisting of poly(ethylene glycol) (PEG) and cyanoresin type M (CRM) with various lithium salts and plasticizer were examined. The CRM used was a copolymer of cyanoethyl pullulan and cyanoethyl poly(vinyl alcohol) with a molar ratio of 1:1, mixed plasticizer was ethylene carbonate (EC) and propylene carbonate (PC) at a volume ratio of 1:1. The conductive behavior of polymer electrolytes in the temperature range of $298{\sim}338\;K$ was investigated. The $PEG/LiClO_4$ complexes exhibited the highest ionic conductivity of ${\sim}10^{-5}S/cm$ at $25^{\circ}C$ with the salt concentration of 1.5 M. In addition, the plasticized $PEG/LiClO_4$ complexes exhibited improvement of ionic conductivity. However, their complexes showed decreased mechanical properties. The improvement of ionic conductivity and mechanical properties could be obtained from the polymer electrolytes by using CRM. The highest ionic conductivity of PEG/CRM/$LiClO_4$/(EC-PC) was $5.33{\time}10^{-4}S/cm$ at $25^{\circ}C$.

• Journal of Electrochemical Science and Technology
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• 제1권2호
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• pp.117-120
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• 2010

Materials used as fuel cell electrode should be light, high conductive, high surface area for reaction, catalytic surface and uniformity of porous structure. Nickel is widely used in electrode materials because it itself has catalytic properties. When used as electrode materials, nickel of only a few im on the surface may be sufficient to conduct the catalytic role. To manufacture the nickel with porous structure, Electroless nickel plating on carbon fiber be conducted. Because electroless nickel plating is possible to do uniform coating on the surface of substrate with complex shape. Acidic bath and alkaline bathe were used in electroless nickel plating bath, and pH and temperature of bath were controlled. The rate of electroless plating in alkaline bath was faster than that in acidic bath. As increasing pH and temperature, the rate of electrolee plating was increased. The content of phosphorous in nickel deposit was higher in acidic bath than that in alkaline bath. As a result, the uniform nickel deposit on porous carbon fiber was conducted.