• Title/Summary/Keyword: conductive composite

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Mechanical Properties Evaluation of Composites for Electromagnetic Waves Absorption (전자기파 흡수용 복합재료의 기계적 강도평가)

  • 오정훈;김천곤;홍창선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.105-108
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    • 2002
  • Materials, matrices mixed with various kinds of conductive or magnetic powder, such as ferrite, have been used as the electromagnetic wave absorbing ones, so called RAM(radar absorbing material). The structure that does not only have electromagnetic waves absorbing property like RAM but also supports loads is called RAS(radar absorbing structure). One of the existing manufacturing process of RAS is to compound with conductive powders the glass fiber-reinforced composite with good permeability and the ability to support loads. The process, however, causes a number of problems, such as the degradation in the mechanical properties of the composite, especially, interlamina shear strength. In this study, mechanical properties of glass fabric/epoxy composite containing 7wt% carbon black powders were measured and compared with pure glass fabric/epoxy composites.

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Preparation and Properties of Electrically Conductive Clothing materials (전기전도성 의류소재의 제조 및 물성에 관한 연구)

  • 홍경희;오경화
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.4
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    • pp.584-592
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    • 1999
  • Highly conductive polyaniline(PAn)-nylon 6 composite fabric was prepared by immersing the nylon 6 fabric in 0.5M aniline+0.35M HCl aqueous solution at 4$0^{\circ}C$ for 2hours, Polymerization was then followed by mixing the prepared oxidant and dopant solution(0.5M(NH4)2S2O+0.35M HCl) to the diffusion bath at 5$^{\circ}C$ for 30 minutes. The conductivity of prepared PAn-nylon 6 composite fabrics reached as high as 0.5$\times$10-1S/cm. Their conductivity were significantly affected by the aniline and oxidant concentration. As compared to those of nylon 6 fabric heat of fusion melting point the degree of crystallinity and tensile strength of PAn-nylon 6 did not significantly changed by inclusion of PAn. In the aspect of serviceability wheras the fabric conductivity was significantly decreased after multiple washion no significant changes in the fabric conductivity were observed after abrading the composite fabric over 50 cycles. However we found that the fabric conductivity could be recovered by acid re-doping with HCl.

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Thermal Characteristics of Heating Films Including Conductive Graphite (전도성 흑연을 포함하는 발열 필름의 열적 특성)

  • Choi, Gyuyeon;Oh, Weontae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.6
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    • pp.500-504
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    • 2020
  • Heating films were prepared with composites of poly (methyl methacrylate) and conductive graphite. The as-prepared composite was deposited on a PET film and then fabricated using a bar coater to produce a film with uniform thickness. Copper electrodes were attached to both ends of the as-prepared film, and the heating characteristics of the film were analyzed while applying a DC voltage. The electrical conductivity and heating temperature of the heating films depended on the size, structure, content, and the dispersion characteristics of the graphite in the composite. The thermal energy was adjusted by controlling the electrical energy, based on the Joule heating theory. The electrical resistance of the film was altered in proportion to Ohm's law, and the heating temperature was changed according to the structure of the film (interelectrode spacing or electrode length) and the conductive graphite content. When the content of conductive graphite in the film increases, the electrical resistance decreases, and the heating temperature increases; however, there is no significant change above a certain content (50%).

Electrical Properties of Carbon Fiber/Aluminum Composite (Carbon Fiber/ Aluminum 복합재료의 전기적 특성연구)

  • Han, Se-Won;Kim, Bong-Seo;Woo, Byung-Chu;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.259-262
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    • 1991
  • Carbon fiber/Aluminum composites were fabricated vacuum hot press method with condition of $10^{-3}$ torr, 100MPa, $600^{\circ}C$, 30min. Microstructure, mechanical properties, electrical properties and thermal properties of CF/Al composites were studied.

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Modification of C/C Composite Bipolar Plate by Addition of Electro-Conductive Carbon Black

  • Ryu, Seung-Kon;Hwang, Taek-Sung;Lee, Seung-Goo;Lee, Sun-A;Kim, Chang-Soo
    • Carbon letters
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    • v.2 no.3_4
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    • pp.165-169
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    • 2001
  • Modification of C/C composite bipolar plate for improving electrical conductivity was carried out by addition of electroconductive carbon black (EC-CB). Carbon black was carefully mixed to methanol-containing phenolic resin, impregnated into 2D-carbon fabrics, hot pressed and then carbonized to obtain composite plate. Inclusion of electro-conductive carbon black enhanced the electrical conductivity of the C/C composites by increasing the conduction path. Addition of 10 vol% carbon black increased the electrical conductivity from 5.5/${\Omega}cm$ to 32/${\Omega}cm$ and reduced the crack formation by filling effect, resulting in the increase of flexural properties of composite plate. However, at carbon black content over 10 vol%, flexural properties decreased by delaminating role of excess carbon black at the interface in C/C composites.

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Feasibility Study of the Damage Monitoring for Composite Materials by the Piezoelectric Method (압전기법을 이용한 복합재료 손상모니터링의 가능성에 관한 연구)

  • Hwang, Hui-Yun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.11
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    • pp.918-923
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    • 2008
  • Since crack detection for laminated composites in-service is effective to improve the structural reliability of laminated composites, it have been tried to detect cracks of laminated composites by various nondestructive methods. An electric potential method is one of the widely used approaches for detection of cracks for carbon fiber composites, since the electric potential method adopts the electric conductive carbon fibers as reinforcements and sensors and the adoption of carbon fibers as sensors does not bring strength reduction induced by embedding sensors into the structures such as optical fibers. However, the application of the electric method is limited only to electrically conductive composite materials. Recently, a piezoelectric method using piezoelectric characteristics of epoxy adhesives has been successfully developed for the adhesive joints because it can monitor continuously the damage of adhesively bonded structures without producing any defects. Polymeric materials for the matrix of composite materials have piezoelectric characteristics similarly to adhesive materials, and the fracture of composite materials should lead to the fracture of polymeric matrix. Therefore, it seems to be valid that the piezoelectric method can be applied to monitoring the damage of composite materials. In this research, therefore, the feasibility study of the damage monitoring for composite materials by piezoelectric method was conducted. Using carbon fiber epoxy composite and glass fiber composite, charge output signals were measured and analyzed during the static and fatigue tests, and the effect of fiber materials on the damage monitoring of composite materials by the piezoelectric method was investigated.

Analysis of conductive mechanism on self-diagnosis FRP (자기진단 FRP의 도전기구 해석)

  • 임현주;이학용;신순기;이준희
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.27-30
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    • 2003
  • In order to apply fracture detection we fabricated the CP-FRP using carbon-powder and analyzed conductive mechanism of it. The composites showed lower initial resistance as the carbon powder and amount of glass fiber(TEX) was used much more. When those are compared with each other that before and after bending test, the more cracks observed in matrix after bending test. We become to know that the conductivity of the composites depends on percolation structure of carbon powder.

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Poly(phenanthrenequinone)-Poly(acrylic acid) Composite as a Conductive Polymer Binder for Submicrometer-Sized Silicon Negative Electrodes (서브마이크로미터 크기의 실리콘 음극용 폴리페난트렌퀴논-폴리아크릴산 전도성 고분자 복합 바인더)

  • Kim, Sang-Mo;Lee, Byeongil;Lee, Jae Gil;Lee, Jeong Beom;Ryu, Ji Heon;Kim, Hyung-Tae;Kim, Young Gyu;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.87-94
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    • 2016
  • In order to improve performances of submicrometer-sized Si negative electrode which shows larger volumetric change than nano-sized Si, composite binders are introduced by blending between poly(phenanthrenequinone) (PPQ) conductive polymer binder and poly(acrylic acid) (PAA) having good adhesion strength due to its carboxyl functional group. Blending between PPQ and PAA shows an effect that the adhesion strength of the Si electrode with the composite conductive binder is greatly improved after blending and this makes its better stable cycle performance. Blending ratios between PPQ and PAA in this work are 2:1, 1:1, 1:2 (by weight) and the best capacity retention at 50th cycle is observed in the electrode with the blending ratio 2:1 (named QA21). This is because that PPQ plays a role of conductive carbon among the Si particles or between Si particles and Cu current collector and PAA binds effectively the particles and the current collector. According to this synergetic effect, the internal resistance of the Si electrode with the blending ratio 2:1 is the smallest value. In addition, the Si electrode with PPQ-PAA composite binder shows the better stable cycle performance than the electrode with conventional super-P conductive carbon (20 wt.%).

The Electrical Characteristic of Composite Film for Lithium Secondary Battery by adding DMSO (DMSO 첨가에 따른 리튬이차전지용 복합필름의 전기적 특성)

  • 박수길;김종진;이창진;김상욱;김현후;임기조;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.269-272
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    • 1997
  • The Lithium ion secondary battery has been developed for high energy density of portable electrical device and electronics. Among the many conductive polymer materials, the positive active film for Li polymer battery system was synthesized successfully from polyphenylene diamine(PPD) by chemical polymerization in our lab. And PPD-DMcT(2, 5-dimercapto-1, 3, 4-thi-adiazole) composite flim conductive material, at high temperature was also prerared with the addition of dimethylsulfoxide(DMSO). The surface morphology and thermal stability of prepared composite flim was carried out by using SEM and TGA, respectively. Electrochemical and electrical conductivity of composite flim were also discussed by cyclic voltammetry and four-probe method in dry box(<27pm). And the electrode reaction mechanism was detected and analyzed from the half cell unit battery system.

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