• Title/Summary/Keyword: conducting property

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Effect of Cathode Porosity on the Cathodic Polarization Behavior of Mixed Conducting LSCF(La0.6Sr0.4Co0.2Fe0.8O3) (혼합전도체 LSCF(La0.6Sr0.4Co0.2Fe0.8O3) 양극의 기공률에 따른 양극분극 특성)

  • Yun, Joong-Cheul;Lee, Jong-Ho;Kim, Joosun;Lee, Hae-Weon;Kim, Byong-Ho
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.251-259
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    • 2005
  • In order to characterize the influence of the reaction-site density on the cathodic polarization property of LSCF, we chose the porosity of LSCF as a main controlling variable, which is supposed to be closely related with active sites for the cathode reaction. To control the porosity of cathodes, we changed the mixing ratio of fine and coarse LSCF powders. The porosity and pore perimeter of cathodes were quantitatively analyzed by image analysis. The electrochemical half cell test for the cathodic polarization was performed via 3-probe AC-impedance spectroscopy. According to the investigation, the reduction of oxygen at LSCF cathode was mainly controlled by following two rate determining steps; i) surface diffusion and/or ionic conduction of ionized oxygen through bulk LSCF phase, ii) charge transfer of oxygen ion at cathode/electrolyte interface. Moreover, the overall cathode polarization was diminished as the cathode porosity increased due to the increase of the active reaction sites in cathode layer.

DEVELOPMENT OF SN BASED MULTI COMPONENT SOLDER BALLS WITH CD CORE FOR BGA PACKAGE

  • Sakatani, Shigeaki;Kohara, Yasuhiro;Uenishi, Keisuke;Kobayashi, Kojiro F.;Yamamoto, Masaharu
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.450-455
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    • 2002
  • Cu-cored Sn-Ag solder balls were fabricated by coating pure Sn and Ag on Cu balls. The melting behavior and the solderability of the BGA joint with the Ni/Au coated Cu pad were investigated and were compared with those of the commercial Sn-Ag and Sn-Ag-Cu balls. DSC analyses clarified the melting of Cu-cored solders to start at a rather low temperature, the eutectic temperature of Sn-Ag-Cu. It was ascribed to the diffusion of Cu and Ag into Sn plating during the heating process. After reflow soldering the microstructures of the solder and of the interfacial layer between the solder and the Cu pad were analyzed with SEM and EPMA. By EDX analysis, formation of a eutectic microstructure composing of $\beta$-Sn, Ag$_3$Sn, ad Cu$_{6}$Sn$_{5}$ phases was confirmed in the solder, and the η'-(Au, Co, Cu, Ni)$_{6}$Sn$_{5}$ reaction layer was found to form at the interface between the solder and the Cu pad. By conducting shear tests, it was found that the BGA joint using Cu-cored solder ball could prevent the degradation of joint strength during aging at 423K because of the slower growth me of η'-(Au, Co, Cu, Ni)$_{6}$Sn$_{5}$ reaction layer formed at the solder, pad interface. Furthermore, Cu-cored multi-component Sn-Ag-Bi balls were fabricated by sequentially coating the binary Sn-Ag and Sn-Bi solders on Cu balls. The reflow property of these solder balls was investigated. Melting of these solder balls was clarified to start at the almost same temperature as that of Sn-2Ag-0.75Cu-3Bi solder. A microstructure composing of (Sn), Ag$_3$Sn, Bi and Cu$_{6}$Sn$_{5}$ phases was found to form in the solder ball, and a reaction layer containing primarily η'-(Au, Co, Cu, Ni)$_{6}$Sn$_{5}$ was found at the interface with Ni/Au coated Cu pad after reflow soldering. By conducting shear test, it was found that the BGA joints using this Cu-core solder balls hardly degraded their joint shear strength during aging at 423K due to the slower growth rate of the η'-(Au, Cu, Ni)$_{6}$Sn$_{5}$ reaction layer at the solder/pad interface.he solder/pad interface.

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Transport and optical properties of transparent conducting oxide In2O3:Zn (비정질 투명전도막 In2O3:Zn의 전기적 광학적 특성)

  • 노경헌;최문구;박승한;주홍렬;정창오;정규하;박장우
    • Korean Journal of Optics and Photonics
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    • v.13 no.5
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    • pp.455-459
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    • 2002
  • The transport and optical properties of $In_2O_3$:Zn(IZO) thin films grown by DC magnetron sputtering deposition have been studied. The deposition temperatures ($T_s$) were varied from room temperature to $400^{\circ}C$ in $50^{\circ}C$ steps. The IZO films are an amorphous phase for $T_s$<$300^{\circ}C$ and polycrystalline phase for $350^{\circ}C$$T_s$. In contrast to ordinary films, amorphous IZO films have lower resistivity and higher optical transmittance than polycrystalline IZO films. The resistivity of amorphous IZO was in the range of 0.29~0.4 m$\Omega$cm and that of polycrystalline IZO was in the range of 1~4 m$\Omega$cm. The carrier type for IZO film was found to be n-type, and the carrier density, was $3~5{\times}10^{20}/cm^3$. The Hall mobility, $({\mu}_H)$, was 20~$50\textrm{cm}^2$/V.sec. The predominant scattering mechanisms in both amorphous and polycrystalline IZO films were believed to be ionized impurity scattering and lattice scattering. The visible transmittance of the IZO films, which decreases with an increase of TS, was above 80%.

Research on Evaluation of Properties of PA6/PA66/GF Composite according to Injection Pressure and Simulation of Damping Performance (엔진마운트 브라켓용 PA66/GF 복합재료의 특성 평가 및 진동감쇠 성능 시뮬레이션에 대한 연구)

  • Seong-Hun Yu;Hyun-Sung Yun;Dong-Hyun Yeo;Jun-Hee Lee;Jong-Su Park;Jee-hyun Sim
    • Composites Research
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    • v.37 no.2
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    • pp.59-67
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    • 2024
  • Research was conducted on a PA material-based composite material manufacturing method for application to engine mount brackets. Engine mount brackets must have heat resistance, impact resistance, and damping performance. PA66 resin was used as the base material for the composite material. The glass fiber was used as the reinforcement material. The composite material was manufactured using the injection molding method. The thermal, mechanical, and morphological characteristics were analyzed depending on the content of glass fiber. 3D model was created using the property evaluation database of composite materials(input data). The damping performance of the generated 3D model was extracted as out-put data. The reason for evaluating the characteristics of PA-based composite materials and conducting simulations on the damping performance of 3D models of engine brackets is because product performance can be predicted without manufacturing actual automobile parts and conducting damping performance tests. As a result of the damping simulation, damping performance tended to increase proportionally as the mass fraction of the reinforcement increased. But above a certain level, it no longer increased and slightly decreased. As a result of comparing the actual experimental values a nd the simulated values, the approximate value was within ±5%.

Experimental Study for the Development of the Mixing Ratio as a Compaction Pile (다짐말뚝 재료로서 쇄석과 저회의 적정 혼합비 도출을 위한 실험적 연구)

  • Leem, Hansoo;Kim, Sunkon;Lee, Jooho;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.9
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    • pp.5-16
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    • 2012
  • In the case of using the soil materials created by cutting in-situ ground directly without adjusting particle size, it is recommendable to seek the compaction property or material constant required for filling design or density control through indoor test, and many studies on this subject have been carried out during that time. The researches conducted during that time, however, were focused on the mixed materials with different diameters that exist in a natural condition. There has been no study conducted using coal fly ash that is by-product of the thermal power plant that is actively considered as the building materials. Therefore, this study was aimed at implementing compaction test and examining the basic engineering property in order to explore the influence of crushing the particles through compacting the admixture of crushed stone and coal fly ash produced from thermal power plant on its engineering property, and then the impact of the admixture volume of each material on compaction property and material property by conducting the One-Dimensional Compression Test. As result of compaction test, the optimum moisture ratio of coal fly ash was shown to be approx. 23%. As result of compaction test in accordance with the mixed ratio of coal fly ash and crushed stone under the same compaction energy and moisture ratio, dry unit weight tended to drop when the mixed ratio of coal fly ash exceeded 30%, while it reached approx. $1.81gf/cm^3$ when the mixed ratio was 30%. As result of One-Dimensional Compression Test in accordance with the mixed ratio of crushed stone and coal fly ash, the change in void ratio by particle crushing was at the highest level in the case of coal fly ash 100%, while the lowest level in the case of crushed stone 100%. In the case of mixed materials of crushed stone and coal fly ash, compression index was at the lowest level in case of coal fly ash 30%, and therefore this ratio of mixed material was judged to be the most stable from an engineering aspect.

Fire Occurrence Pattern Analysis and Fire Risk Calculation of Jinju City (진주시 화재발생 패턴분석과 위험등급 산출)

  • Bae, Gyu Han;Yoo, Hwan Hee
    • Journal of Korean Society for Geospatial Information Science
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    • v.22 no.4
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    • pp.151-157
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    • 2014
  • Diverse and complex facilities have been on the increase in urban areas in accordance with rapid urbanization. Along the lines of the increase in facilities, the risk of fire has increased. In particular, fire accidents as well as traffic accidents accounted for the highest rate in artificial disasters. Therefore, the National Fire Information Systems managed by the National Emergency Management Agency (NEMA) appeared for the effective fire management. The NEMA has provided the public with the Internet services regarding information about fire outbreak since 2007. This study acquired data from both NEMA and the Jinju City Fire Department. It constructed the fire data of Jinju City and calculated the change in spatial density targeting fire, occurred in Jinju city with a view to examining the fire risk of facilities by conducting a time series analysis on the trends of fire outbreak over a span of periods between 2007 and 2013. It also conducted an analysis of Moran's I, Getis-Ord Gi. Therefore, it came to select higher hot spots in terms of fire location and fire density. In addition, it attempted to calculate the levels of fire hazard by drawing up the matrix of personal injury and property damage, depending on facilities to present the methods, which can predict the risk of fire occurrence in urban areas.

A Study on Synthetic Techniques Utilizing Map of 3D Animation - A Case of Occlusion Properties (오클루전 맵(Occlusion Map)을 활용한 3D애니메이션 합성 기법 연구)

  • Park, Sung-Won
    • Cartoon and Animation Studies
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    • s.40
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    • pp.157-176
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    • 2015
  • This research describes render pass synthetic techniques required to use for the effectiveness of them in 3D animation synthetic technology. As the render pass is divided by property and synthesized after rendering, elaborate, rapid synthesis can be achieved. In particular, occlusion pass creates a screen as if it had a soft, light shading, expressing a sense of depth and boundary softness. It is converted into 2D image through a process of pass rendering of animation projects created in 3D space, then completed in synthetic software. Namely, 3D animation realizes the completeness of work originally planned through compositing, a synthetic process in the last half. To complete in-depth image, a scene manufactured in 3D software can be sent as a synthetic program by rendering the scene by layer and property. As recently the occlusion pass can express depth notwithstanding conducting GI rendering of 3D graphic outputs, it is an important synthetic map not omitted in the post-production process. Nonetheless, for the importance of it, currently the occlusion pass leaves much to be desired for research support and books summarizing and analyzing the characteristics of properties, and the principles and usages of them. Hence, this research was aimed to summarize the principles and usages of occlusion map, and analyze differences in the results of synthesis. Furthermore, it also summarized a process designating renderers and the map utilizing the properties, and synthetic software usages. For the future, it is hoped that effective and diverse latter expression techniques will be studied beyond the limitation of graphic expression based on trends diversifying technique development.

Anion Effects on Changes in Viscoelasticity of Polypyrrole during Electrochemical Growth in Neutral Aqueous Solutions (중성 수용액에서 폴리피롤의 전기화학적 성장시 발생하는 점탄성 변화에 미치는 음이온 효과)

  • Bae Sang-Eun;Lee Seung-Yong;Paek Se-Hwan;Kim Young-Sang;Lee Chi-Woo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.66-69
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    • 1999
  • A large number of works have been Performed to understand the electrochemical growth of Polypynole on conducting substrates in aqueous as well as in nonaqueous solutions. Recently most researches with Polypyrrole have tended to be directed toward technological applications, but many fundamental physical and chemical properties of Polypyrrole remain unknown. In Particular, microrheological Property of polypyrrole has been largely neglected until the advanced electrochemical quartz crystal microbalance technique was introduced recently. To study anion effects on microrheolosical Property of Polypyrrole, we investigated changes in viscoelasticity of Polypyrrole during electrochemical growth in neutral aqueous solutions by means of in siか electrochemical quartz crystal oscillator method. The results showed that the films of Polypyrrole synthesized in $KPF_6\;and\;KCIO_4$ were more viscoelastic than the ones in $KCI,\;KNO_3,\;KBr,\;KBF_4,\;K_2SO_4$, sodium tosylate (NaOTs), and sodium dodecyl sulfate (SDS). The growth rate of Polypyrrole in SDS was faster than that in the others utilized. Polypyrroles synthesized in buffered neutral solutions were more elastic than those in unbuffered neutral solutions.

Mobile Cloud Context-Awareness System based on Jess Inference and Semantic Web RL for Inference Cost Decline (추론 비용 감소를 위한 Jess 추론과 시멘틱 웹 RL기반의 모바일 클라우드 상황인식 시스템)

  • Jung, Se-Hoon;Sim, Chun-Bo
    • KIPS Transactions on Software and Data Engineering
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    • v.1 no.1
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    • pp.19-30
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    • 2012
  • The context aware service is the service to provide useful information to the users by recognizing surroundings around people who receive the service via computer based on computing and communication, and by conducting self-decision. But CAS(Context Awareness System) shows the weak point of small-scale context awareness processing capacity due to restricted mobile function under the current mobile environment, memory space, and inference cost increment. In this paper, we propose a mobile cloud context system with using Google App Engine based on PaaS(Platform as a Service) in order to get context service in various mobile devices without any subordination to any specific platform. Inference design method of the proposed system makes use of knowledge-based framework with semantic inference that is presented by SWRL rule and OWL ontology and Jess with rule-based inference engine. As well as, it is intended to shorten the context service reasoning time with mapping the regular reasoning of SWRL to Jess reasoning engine by connecting the values such as Class, Property and Individual which are regular information in the form of SWRL to Jess reasoning engine via JessTab plug-in in order to overcome the demerit of queries reasoning method of SparQL in semantic search which is a previous reasoning method.

The Status of Damage and Monitoring of Subterranean Termite (Reticulitermes spp.) (Blattodea: Rhinotermitidae) for Wooden Cultural Heritage in Korea (국내 목조문화재에 대한 지중 흰개미 피해 및 모니터링 현황)

  • Im, Ik-Gyun;Cha, Hyun-Seok;Kang, Won-Chul;Lee, Sang-Bin;Han, Gyu-Seong
    • Journal of Conservation Science
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    • v.37 no.3
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    • pp.191-208
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    • 2021
  • In this study, the status of damage by subterranean termites and their management according to the region and type of domestic wooden cultural properties were identified. This was based on the survey reports of agencies conducting regular nationwide and regional monitoring of subterranean termites. In addition, using geographical information system (GIS) based on the survey contents, a map was constructed of termite infestation and its progress on 2,805 wooden cultural properties that were surveyed nationwide. Based on the map produced, a total of 486 cases of termite infestation were confirmed in wooden cultural properties during 2018-2019, of which 143 cases (approximately 29.4%) were confirmed to be owing to the invasion of termites in the ground and infestation of wood materials. A web platform and an application using a mapping application program interface were created to increase accessibility to the investigated damage status data. The methods employed by each institution for investigating and monitoring the invasion of termites in the ground included the use of detection dogs, visual observation, installation of wood specimens made of pine, and microwave equipment. However, it was confirmed that monitoring and survey methods were not applied to determine the territorial range of the subterranean termite colonies. Accordingly, the use of dyeing and mark-release-recapture methods were deemed necessary to understand the current status, such as calculating the scope of the target wooden cultural property, when monitoring subterranean termite colonies.