• Title/Summary/Keyword: concentration rate

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Evaluation of Contribution Rate of PM Concentrations for Regional Emission Inventories in Korean Peninsula Using Brute-force Sensitivity Analysis (Brute-force 방법을 이용한 한반도 미세먼지 농도에 대한 배출원의 기여도 산출 연구)

  • Lee, Soon-Hwan;Lee, Kang-Yeol
    • Journal of Environmental Science International
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    • v.24 no.11
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    • pp.1525-1540
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    • 2015
  • In order to clarify the contribution rate of PM concentration due to regional emission distribution, Brute force analysis were carried out using numerical estimated PM data from WRF-CMAQ. The emission from Kyeongki region including Seoul metropolitan is the largest contribution of PM concentration than that from other regions except for emission of trans-country and source itself. Contribution rate of self emission is also the largest at Kyeongki region and its rate reach on over 95 %. And the rate at Gangwon region also higher than any region due to synoptic wind pattern. Due to synoptic wind direction at high PM episode, pollutants at downwind area along from west to east and from north to south tends to mix intensively and its composition is also complicated. Although the uncertainty of initial concentration of PM, the contribution of regional PM concentration tend to depend on the meteorological condition including intensity of synoptic and mesoscale wind and PM emission pattern over upwind region.

Study on the 2,4,6-Trinitrotoluene reduction rate by mediation of extracellular material of mixed culture (혼합배양 미생물의 세포외 물질이 2,4,6-Trinitrotoluene 변환에 미치는 영향에 관한 연구)

  • 한기봉
    • Journal of environmental and Sanitary engineering
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    • v.11 no.2
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    • pp.27-31
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    • 1996
  • 2,4,6-Trinitrotoluene(TNT) was reduced into intermediate products by mixed culture incubated in anaerobic condition. To test the effects of extracellular material to electron transfer between sulfide and TNT, filtered medium of mixed culture was loaded in the test tubes with TNT and sulfide. The transformation rate was measured under four different conditions. The rate under microbial activity was the fastest among under different conditions. With sulfide or filtrate alone and TNT, the reactions were measured as the slowest reactions or no reactions occured, respectively. The reaction rate coefficient were calculated by linear regression and the first order kinetic was fitted best. Also, the plot of rate coefficients (K$_{f}$) showed linear relationships when at time zero TNT and sulfide concentration were 20 mg/1 and 6.0 mM, respectively. By extrapolation, reaction rate coefficient of 100% filtrate could be calculated as 0.0054/minute. However, reaction rate was affected by different concentration of sulfide, so it is a dependent of sulfide concentration. The results of this test showed TNT reduction rate can be limited more by microbial reaction than by mediation of filtrate or sulfide and filtrate alone.

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Behavior of Soluble Microbial Products by the Internal Recycle Rate in MBR Process (MBR공정에서 내부 반송비에 따른 생물대사성분의 거동)

  • Lee, Won-Bae;Cha, Gi-Cheol;Jeong, Tae-Young;Kim, Dong-Jin;Yoo, Ik-Keun
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.602-608
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    • 2005
  • A laboratory-scale experiment was conducted to investigate control of soluble microbial products (SMP) by the internal recycle rate in the submerged membrane separation activated sludge process. The internal recycle rate of the reactor RUN 1 and RUN 2 were 100 % and 200 %, respectively. SMP concentration was rapidly accumulated in the reactor (RUN 1). The variation of accumulated SMP concentration was related to the denitrification rate at the beginning experiment however SMP concentration decreased without correlatively to the denitrification rate during long operation time. The microbial kinetic model was rapidly presented in the both microbial growth and extinction in the reactor (RUN 1). In the SMP kinetic model, Internal recycle rate is the lower, value of UAP and BAP which SMP matter were presented low. The study about development of kinetic model is relatively well adjusted to the experiment exception SMP. In the future, SMP formation equation must be thought that continually research is necessary.

Improvement of Organics and Nitrogen Removal by HRT and Recycling Rate in Air Lift Reactors (공기부상반응조에서 체류시간과 반송율에 의한 유기물질 및 질소제거 향상에 관한 연구)

  • Kim, Jin-Ki;Yu, Sung-Whan;Lim, Bong-Su
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.45-50
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    • 2006
  • This study was performed to evaluate the air lift reactors (ALR) by variations of HRT and recycling rate. Air lift reactor was composed of bioreactor and clarifier above it. To remove organic matters and nitrogen through the formation of microbic film and filtration, bio-filter reactors were filled with clay, glass, bead, waste plastic, respectively. Influent wastewater was fed to biofilter reactor, and effluent wastewater from bio-filter reactor was injected ALR again, instead of adding external carbon source. Effluent BOD concentration was satisfied with lower than 10 mg/L in recycling rate 100% regardless of the variation of HRT and the kinds of media materials. In HRT 4 hr, recycling rate 100%, BOD removal efficiency rate was from about 85 to 90%, COD removal efficiency rate was higher than 90%. Effluent TN concentration was satisfied with less than 20 mg/L, if HRT was maintained by over than 6 hr regardless of recycling rate and media materials. Over than HRT was 4 hr, microbes concentration in air lift reactor was maintained over than 2,500 mg/L constantly, not sensitive to environmental condition, and organic removal was effective as it was higher.

Determination of Short-term Bioconcentration Factor on Carbofuran in Carassius auratus (goldfish) (Carassius auratus(goldfish)를 이용한 Carbofuran의 단기간 생물농축계수의 측정)

  • 민경진;배영규;차춘근;박천만;강회양
    • Journal of Environmental Health Sciences
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    • v.22 no.4
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    • pp.25-32
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    • 1996
  • The Bioconcentration factor(BCF) is used as an important criterion in the risk assessment of environmental contaminants. Also it can be used as indicator of biomagnification of environmentally hazardous chemicals through food-chain as well as a tool for ranking the bioconcentration potential of the chemicals in the environment. This paper reports the measured BCF value on carbofuran in Carassius auratus(goldfish), under steady state, and examined corelation between the BCF value and the depuration rate constant. Carassius auratus(goldfish) was chosen as test organism and test periods were 1-day, 3-day and 5-day. Experimental concentrations were 0.05, 0.10 and 0.50 ppm. Carbofuran in fish tissue and in test water was extracted with n-hexane and acetonitril. GC-ECD was used to detect and quantitate carbofuran. The depuration rate of carbofuran from the whole body of goldfish is determined over the 24-h period after treatment. The obtained results were as follows: 1. It was possible to determine short term BCFs of carbofuran through relatively simple procedure in environmental concentrations. 2. $BCF_1$ of carbofuran in concentration of 0.05, 0.10 and 0.50 ppm were 1.66, 1.64 0.61, $BCF_3$ were 2.08, 2.14, 0.66 and $BCF_5$ were 2.21, 2.57, 0.86, respectively. 3. Carbofuran concentration in fish extract was increased as increasing test concentration and prolonging test period, but $BCF_s$ in concentration of 0.50 ppm was greately decreased. 4. Determined deputation rate constants of carbofuran in concentration of 0.05, 0.10, 0.50 ppm were 0.076, 0.082 and 0.089, respectively. 5. It is considered that great decrease of $BCF_s$ in concentration of 0.50 ppm is due to high water solubility and stability of carbofuran in testwater. 6. It is suggested that low BCF of carbofuran is due to its relatively high water solubility and depuration rate, compared to BPMC, carbaryl and chlorothalonil.

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Experiments on a Regenerator with Thermosyphon for Absorption Heat Pumps (기포 펌프를 적용한 흡수식 열펌프용 고온 재생기의 작동 특성 실험)

  • Park, C.W.;Jurng, J.;Nam, P.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.463-472
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    • 1996
  • Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.

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Characteristics of Advanced Wastewater Treatment Process Using High MLSS in Anoxic Tank (무산소조에서 고농도 미생물을 이용한 하수고도처리공정의 처리특성)

  • Son, Dong-Hun;Lim, Bong-Su;Park, Hye-Sook
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.42-47
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    • 2004
  • This study was accomplished to develope an advanced wastewater treatment process using high MLSS in anoxic tank aimed to improve nutrient removal and to reduce wasting sludge. It was operated with 4 Modes with varing solid concentration and internal recycle ratios. Mode I, II, III was operated 1.0~1.5% MLSS concentration at anoxic tank with 50% sludge recycle rate, however, each internal recycle rate were 100%, 200%, 300% and Mode IV was operated 1.5~2.0% MLSS concentration at anoxic tank with 50% sludge recycle rate and 100% internal recycle rate. The COD removal efficiency didn't show any big difference from Mode I to IV. The average COD removal rate was over than 90%. The T-N removal rate was 73%, the highest rate in all mode. The 36% of SCOD is used for the denitrification and phosphorus release in the anoxic tank. Specific denitrification rate was 3.5mg $NO_3{^-}-N/g$ Mv/hr and denitrification time was 0.7hr. As MLSS concentration is higher in anoxic tank as denitrification time would be shorter. The T-P removal rate was average 70%. The phosphorus release accomplished from the anoxic tank because the anaerobic condition was prevalent in the anoxic due to the prompt completion of denitrification. Sludge production was 0.28 kgVSS/kg $BOD_{removed}$ under the 1.5% MLSS and 17 day SRT. It is prominent result which has 40% sludge reduce comparing with traditional activate sludge system.

Effect of General Ventilation Rate on Concentrations of Gaseous Pollutants Emitted from Enclosed Pig Building (밀폐형 돈사 작업장의 전체 환기율이 가스상 오염물질 노출 농도 변화에 미치는 영향)

  • Kim, Ki Youn;Seo, Sung Chul;Choi, Jeong-Hak
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.1
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    • pp.46-51
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    • 2014
  • Objectives: The principal aim of this study was to compare the concentrations of gaseous pollutants emitted in enclosed pig buildings between different rates of general ventilation and determine the variations in the patterns of gaseous pollutants as affected by ventilation rate. Materials and Methods: The experiment was performed in the growing/finishing room($20.0m{\times}12.0m{\times}3.0m$) of a pig confinement building located on the experimental farm of Seoul National University. The conditions of the general ventilation rate for three treatments were 30%($4.12m^3s^{-1}$), 50%($6.87m^3s^{-1}$) and 70%($9.61m^3s^{-1}$). The data presented in the study were collected overa total of 45 days, 15 days for each of the three treatments from March to May 2011. A total of six air samplings were taken at 1.5m above the floor of the pig building. The environmental agents measured in the pig building were ammonia, hydrogen sulfide and odor concentration index for gaseous pollutants with temperature and hydrogen sulfide for thermal factors. Results: There were significant differences in the ammonia and odor concentration index in the pig building among the three general ventilation rate conditions(p<0.05), whereas hydrogen sulfide did not show a significant difference among three conditions of general ventilation rate(p>0.05). As the general ventilation rate applied to the pig building increases, it appears that all the indoor environmental agents measured in this study simultaneously decrease. Conclusions: The gaseous pollutants significantly affected by the general ventilation rate in pig building were ammonia and odor concentration index(p<0.05). However, it was found that hydrogen sulfide and thermal factors, temperature and relative humidity were not influenced significantly by variation in the general ventilation rate.

Depositing Rate of Electroless Nickel Plating Bath Contained Triethanolamine as a Complexing Agent (트리에탄올아민을 錯化劑로 사용한 無電解니켈鍍金浴의 析出速度에 관한 硏究)

  • Yeo, Woon-Kwan
    • Journal of Surface Science and Engineering
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    • v.18 no.4
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    • pp.153-163
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    • 1985
  • In the electroless nickel plating bath which contained nickel sulfate, sodium hypophosphite, boric acid and triethanolamine, effect of their concentration on the rate of deposition was tested by gravimetric method and polarization method. The polarization method that polarize small range of voltage anodicaly and cathodicaly at the mixed potential in the electroless plating bath can calculate mixed current (depositing rate) from $i_{mp}=\frac {i}{\eta}\;\frac{RT}{nF}\;or\;i_{mp}=\frac{i}{\eta}\;\frac{1}{2.3}(\frac{b_a\;\;b_c}{b_c+b_a})$ Where $i_{mp}$ is the depositing current, i is the polarized current, ${\eta}$ is the polarized voltage, $b_a\;and\;b_c$ are the Tafel slop of anodic and cathodic polarization curves respectively. The calculated mixed current ($i_{mp}$) is proportional to the depositing rate obtained by gravimetric method and corresponded mostly to the real depositing rate by multifying supplementary constant. The polarization method can be used for founding inclination of reaction on various concentration of each composition. Decreasing or increasing concentration of triethanolaminc as a complexing agent , the depositing rate is decreased and when the bath contained 25-50mL/L of triethanoloamine, the depositing rate is increased. The depositing rate is increased with increasing the concentration of boric acid, and when the bath contained 0.5M of boric acid, the depositing rate is increased abruptly. The optimum composition of the electroless nickel bath was estimated 0.1M of nickel sulfate, 0.25M of sodium hypophosphite, 0.5M of boric acid, and 25-50mL/L of triethanalamine.

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Measurement of Efficiency and Flue Gas Concentration of 90 kW Woodchip Boiler (90kW급 우드칩 온수 보일러 특성 및 성능 시험)

  • Kang, Sae-Byul;Kim, Jong-Jin;Choi, Kyu-Sung;Lee, Woong-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.194-197
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    • 2008
  • We measured the efficiency and flue gas concentration of a 90kW woodchip boiler which is for heating water of lodging. At nominal operating condition, the fuel, woodchip is fed into the boiler at a rate of 22.6 kg/h. In order to determine the efficiency of the boiler, we measured the water flow rate, woodchip flow rate, heating value and water content of woodchip, temperature of inlet and outlet of heating water. The results of test show that the power output of the woodchip boiler is 90.0 kW(77,400 kcal/h) and the thermal efficiency of the boiler is 88.5%. By using a gas analyser, flue gas concentrations are measured. The results show that O2 in the flue gas is 10.2%, CO concentration is 393 ppm and NOx concentration is 74 ppm.

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