• 제목/요약/키워드: concentration influence

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방식도막에 있어서 물의 침투에 대한 전해질 용액의 영향 (Effect of Electrolyte Concentration on Water Permeation in Protective Coatings)

  • 박진환
    • 한국안전학회지
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    • 제13권4호
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    • pp.206-212
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    • 1998
  • The water permeation in protective coatings, which may greatly influence the corrosion protective property of these coatings, was studied using the electrochemical impedance spectroscopy technique. During the absorption of water in protective coatings immersed in electrolyte solution, the change of coating capacitance with concentration of electrolyte was determined from impedance measurements. When water absorption or desorption of coatings occured by exposing the coatings to electrolyte solutions of different concentration, increase in impedance caused by desorption of water was found to be higher in the case of thicker film. The amount of water absorbed in coatings changed with concentration of electrolyte. The water taken up in coatings from the solution of lower electrolyte concentration was deserted by contact with the solution of higher concentration. The uptake of water in protective coatings varied depending on the type of coating ingredient especially binder.

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이산화탄소 농도에 따른 콘크리트 구조물의 탄산화 해석 (Carbonation Analysis of Concrete Structures with Carbon Dioxide Concentration)

  • 양주경
    • 한국컴퓨터산업학회논문지
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    • 제9권4호
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    • pp.143-148
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    • 2008
  • 콘크리트의 탄산화를 진행시키는 가장 주요한 영향인자는 대기 중의 농도이다. 본 연구에서는 대기 중의 이산화탄소 농도에 따른 탄산화 진행 정도를 개발한 프로그램을 통하여 해석적으로 접근하였다. 또한 해석 프로그램을 통하여 이산화탄소 농도에 따른 내구수명을 산정하였다. 이산화탄소 표면농도가 0.1%인 경우도 탄산화 깊이가 50mm 정도로 나타났다. 콘크리트의 피복두께를 40mm를 유지한다면 이산화탄소 표면농도가 0.1%일 때 콘크리트의 내구수명은 67년으로 검토되었다.

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모래다짐말뚝지반의 응력분담비에 영향을 미치는 인자에 대한 해석적 연구 (A Numerical Analysis for the Influential Factors on the Stress Concentration Ratio)

  • 최효원;신현영;유한규;김수삼
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.966-973
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    • 2005
  • The stress concentration ratio in accordance with area replacement ratios were considered as core elements of design. However, the stress concentration ratio will be vary depends on progress of consolidation in clay ground. And, since it is not sure to know the affecting factors accurately, the value is decided based on field experiences. To use SCP method more effective and correspond to soil improvement, the decision on proper area replacement ratio through the exact stress concentration ratio is very important. Accordingly, a numerical analysis on influence of various factors that needed to make rational designing guide for decision of proper area replacement ratio to stress concentration ratio was executed in this study.

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염분 농도에 따른 콘크리트 구조물의 염분침투 해석 (Chloride Penetration Analysis of Concrete Structures with Chloride Concentration)

  • 양주경
    • 한국컴퓨터산업학회논문지
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    • 제9권3호
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    • pp.137-142
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    • 2008
  • 염소이온 침투로 인해 철근 부식에 가장 큰 영향을 끼치는 인자는 염소이온 표면농도이다. 본 연구에서는 염소이온 표면농도에 따른 염해 진행 정도를 개발한 프로그램을 통하여 해석적으로 접근하였다. 또한 해석 프로그램을 통하여 염소이온 표면농도에 따른 내구수명을 산정하였다. 염소이온 표면농도가 600ppm인 경우도 염소이온 침투 깊이가 32.3mm 정도로 나타났다. 콘크리트의 피복두께를 40mm를 유지한다면 염소이온 표면농도가 600ppm일 때 콘크리트의 내구수명은 167년으로 검토되었다.

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미셀용액에서 Cyanocobalt(II) 착물의 리간드치환 반응에 대한 속도론적 연구 (Kinetic Studies on the Ligand Substitution Reactions of Cyanocobalt(II) Complexes in Micellar Solutions)

  • 안범수
    • 한국응용과학기술학회지
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    • 제26권3호
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    • pp.370-378
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    • 2009
  • Kinetic studies on the ligand substitution reactions of cyanocomplexes were performed in several micellar solutions. It showed the observed rate constants was found to be independent of the entering ligand concentration at high concentration of cyanopyridine and pyrazinecarboxylate. We could see also that in nonionic and anionic micellar solutions no influence of changes in the surfactant concentration on the observed rate constants was found. Taking into account the hydrophilic nature of the cobalt complex, the cobalt complex molecule was expected to be located in the aqueous phase of the micellar systems, where the reaction would take place. In cationic micellar solutions, a small increase in the observed rate constant was found when the cationic surfactant concentration increased. After reaching a maximum, the rate constant decreased on increasing surfactant concentration and subsequently it reached a plateau, where the observed rate constant was independent of changes in the surfactant concentration.

기상인자가 미세먼지 농도에 미치는 영향 (The Influence of Meteorological Factors on PM10 Concentration in Incheon)

  • 신문기;이충대;하현섭;최춘석;김용희
    • 한국대기환경학회지
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    • 제23권3호
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    • pp.322-331
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    • 2007
  • In this study, we have analyzed $PM_{10}$ concentration measured at Incheon Regional Air Monitoring Network (10 stations) and meteorological data at Incheon Weather Station to investigate factors (i.e. wind direction, wind speed, relative humidity, major meteorological phenomenon, and sea-land breezes existence) influencing $PM_{10}$ concentration in Incheon during 2005. Statistical differences among meteorological factors were assessed by Kruskal-Wallis test or Mann-Whitney U test. The main conditions causing high $PM_{10}$ concentration are summarized below; 1. When westerly wind prevailed (however, $PM_{10}$ decreased when winds were blowing from the east or north). 2. When the winds were calm, owing to accumulation of nearby emissions under stagnant conditions, or when the wind speed is in excess of 6 m/s, which shows the effect of fugitive dust produced by wind erosion. 3. Under the condition of high relative humidity and poor diffusion based on meteorological phenomenon such as fog, mist, and haze. 4. When the Sea-Land breezes existed, which occurred 70 days in Incheon during 2005 and contributed significantly to high $PM_{10}$ concentration in the coastal urban area. In conclusion, we have found that the meteorological factors have influence on $PM_{10}$ concentration in Incheon.

점착성 퇴적물의 침전 특성 분석 (Analysis of Characteristics of Cohesive Sediment Settling)

  • 김종우;윤세의;이종태
    • 한국수자원학회논문집
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    • 제38권2호
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    • pp.133-142
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    • 2005
  • 미세하게 부유된 입자(alumina(Al$_2$O$_3$), quartz(SiO$_2$))의 침전 농도를 물리-화학적(초기농도, pH, NaCl)인 영향을 고려하면서 연구하였다. 침강실험은 입자사이의 끌어당기는 힘 때문에 Flocculation(플록 형성)이 일으키는 초기농도와 NaCl의 증가가 중요한 영향을 미치며, 더욱이 미립자(alumina(Al$_2$O$_3$))의 농도-시간 곡선에 pH의 영향이 매우 큼을 보였다. 또한 정지수면 조건하에서 미립자의 침전 거동예측을 위한 수치 모델은 부정류 1차원 이송방정식에 의해 분석되었으며 양해법, 음해법, Crank-Nicolson 기법 및 유한차분법을 이용하였다. 수치모델은 평형을 이룬 농도변화까지 예측하였으며, 실험치의 비교분석을 통해 중앙차분법을 통한 Implicit 모형의 계산이 대체로 일치하였다.

외기 중 미세먼지의 공동주택 실내 유입에 관한 연구 (Analysis of Infiltration of Outdoor Particulate Matter into Apartment Buildings)

  • 방종일;조성민;성민기
    • 대한건축학회논문집:구조계
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    • 제34권1호
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    • pp.61-68
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    • 2018
  • Recently, concentration of fine and ultra-fine particulate matter(PM) has been increased in KOREA. The increase of PM in KOREA is due to increase of domestic industries and yellow dust from china. PM is known to cause diseases such as dyspnoea, asthma, arrhythmia. Since PM is harmful to human, KOREA Ministry of Environment(ME) warns people to stay indoors when the outdoor PM concentration is high. However, prior studies has shown that indoor PM concentration can be relatively high when outdoor PM concentration is high due to infiltration of PM into buildings though leakage areas. In this study, airtightness, indoor and outdoor pressure difference and PM 2.5 & 10 concentration were measured in an apartment complex to observe PM infiltrating into building. Field measurement was conducted in newly-built apartment buildings to avoid the influence of indoor PM which can be generated by residents. The airtightness test was conducted to identify the leakage areas of the apartment, such as electric outlets and supply/exhaust diffusers. The airtightness test result showed that the air leakage area of the building was dominant in buildings envelop. According to indoor and outdoor pressure difference measurement result and PM concentration measurement result, it can be concluded that outdoor PM can infiltrate into indoor by leakage areas when wind is blown toward the apartment. As a result, pressure difference formed by the external weather condition and architectural characteristics such as the airtightness in building can influence PM to infiltrate into buildings. In further studies, I/O ratio, stack-effect, infiltration and penetration factor will be considered.

대구 안심연료단지 환경오염물질 노출 평가(II) - TSP, PM10, PM2.5 및 중금속 농도분포 및 노출특성 - (Exposure Assessments of Environmental Contaminants in Ansim Briquette Fuel Complex, Daegu(II) - Concentration distribution and exposure characteristics of TSP, PM10, PM2.5, and heavy metals -)

  • 정종현;피영규;이준정;오인보;손병현;이형돈;윤미라;김근배;유승도;민영선;이관;임현술
    • 한국산업보건학회지
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    • 제25권3호
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    • pp.380-391
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    • 2015
  • Objectives: The objective of this study is to assess airborne particulate matter pollution and its effect on health of residents living near Ansim Briquette Fuel Complex and its vicinities. Also, this study measured and analyzed the concentration of TSP, $PM_{10}$, $PM_{2.5}$, and heavy metals which influences on the environmental and respiratory disease in Ansim Briquette Fuel Complex, Daegu, Korea. Methods: In this study, we analyzed various environmental pollutants such as particulate matter and heavy metals from Ansim Briquette Fuel Complex that adversely affected local residents's health. In particular, we verified the concentration distribution and characteristics of exposure for TSP, $PM_{10}$, and $PM_{2.5}$ among particulate matters, and heavy metals(Cd, Cr, Cu, Mn, Ni, Pb, Fe, Zn, and Mg). In that regard, the official test method on air pollution in Korea for analysis of particulate matter and heavy metal in atmosphere were conducted. The large capacity air sampling method by the official test method on air pollution in Korea were applied for sampling of heavy metals in atmosphere. In addition, we evaluated the concentration of seasonal environmental pollutants for each point of residence in Ansim Briquette Fuel Complex and surrounding area. The sampling measured periods for air pollutants were from August 11, 2013 to February 21, 2014. Furthermore, we measured and analyzed the seasonal concentrations(summer, autumn and winter). Results: The average concentration for TSP, $PM_{10}$, and $PM_{2.5}$ by direct influence area at Ansim Briquette Fuel Complex were 1.7, 1.4 and 1.9 times higher than reference region. In analysis results of seasonal concentrations for particulate matter in four direct influence and reference area, concentration levels for winter were generally somewhat higher than concentrations for summer and autumn. The average concentrations for Cd, Cr, Mn, Ni, Pb, Fe, and Zn in direct influence area at Ansim Briquette Fuel Complex were $0.0008{\pm}0.0004{\mu}g/Sm^3$, $0.0141{\pm}0.0163{\mu}g/Sm^3$, $0.0248{\pm}0.0059{\mu}g/Sm^3$, $0.0026{\pm}0.0011{\mu}g/Sm^3$, $0.0272{\pm}0.0084{\mu}g/Sm^3$, $0.4855{\pm}0.1862{\mu}g/Sm^3$, and $0.3068{\pm}0.0631{\mu}g/Sm^3$, respectively. In particularly, the average concentrations for Cd, Cr, Mn, Ni, Pb, Fe, and Zn in direct influence area at Ansim Briquette Fuel Complex were 1.9, 3.6, 2.1, 1.9, 1.4, 2.6, and 1.2 times higher than reference area, respectively. The continuous monitoring and management were required for some heavy metals such as Cr and Ni. Moreover, the average concentration in winter for particulate matter in direct influence area at Ansim Briquette Fuel Complex were generally higher than concentrations in summer and autumn. Also, average concentrations for TSP, $PM_{10}$, and $PM_{2.5}$ were from 1.5 to 2.0 times, 1.2 to 1.8 times, and 1.1 to 2.3 times higher than reference area, respectively. In results for seasonal atmospheric environment, TSP, $PM_{10}$, $PM_{2.5}$, and heavy metal concentrations in direct influence area were higher than reference area. Especially, the concentrations in C station were a high level in comparison with other area. Conclusions: In the results, some particulate matters and heavy metals were relatively high concentration, in order to understand the environmental pollution level and health effect in surrounding area at Ansim Briquette Fuel Complex. The concentration of some heavy metals emitted from direct influence area at Ansim Briquette Fuel Complex were relatively higher than reference area. In particular, average concentration for heavy metals in this study were higher than average concentrations in air quality monitoring station for heavy metal for 7 years in Deagu metropolitan region. Especially, the residents near Ansim Briquette Fuel Complex may be exposed to the pollutants(TSP, $PM_{10}$, $PM_{2.5}$, and heavy metals, etc) emitted from the factories in Ansim Briquette Fuel Complex.

낙동강 하류의 하상구조와 오염물질과의 상관관계 연구 (A Study on the Relation between Riverbed Structure and Pollutant Concentration in Downstream of Nakdong River)

  • 황선출;정성욱
    • 한국환경과학회지
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    • 제5권4호
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    • pp.481-494
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    • 1996
  • This study was performed to investigate the relationship between concentrations of heavy metals in sediment and the depths of 27 sampling sites along the West Nakdong river in downstream of Nakdong River. The deepest site was Kangdong bridge nearby 20ft. From here, the depth was shallowed to Chidong gradually. In each site the smaller mesh was, the liger concentration of heavy metal becomed. Concentration of Zn, Cd, Cr and Cu at inflow point of Shinoe stream was 576.016 ppm, 262.307 ppm, 68.674 ppm and 61.634 ppm, respectively, the concentration was the higest at this point. From here, it was lowered gradually. The concentration of heavy metal at inflow point of Joman river was 155.328 ppm, 56.485 ppm, 25.200 ppm and 31.172 ppm, respectively, those concentrations were liger than other points with the exception of Shinoe stream. Therefore, woman river and Shinoe stream were the major source of pollution in West Nakdong river. Among two sources Shinoe stream was more important source of pollution. West Nakdong river has become lake by Noksan floodgate because it's pollution has had influence on Bonglim.

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