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Petrological, Geochemical and Geochronological Studies of Precambrian Basement in Notheast Asia Region: 1. Age of the Metamorphism of Jirisan Area (동북아시아지역 선캠브리아 지괴에 대한 암석학, 지구화학 및 지구연대학적 연구 : 1. 지리산 지역 변성암의 변성연대)

  • 박계현;송용선;박맹언;이승구;류호정
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.29-39
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    • 2000
  • For the determination of metamorphic age of the metamorphic rocks distributed in the Ji-san area of Youngnam massif, Sm and Nd isotopic compositions were analyzed for the whole rock and garnet separates. As the result, we obtained 1799 + 11 Ma from the porphyroblastic gneiss, 1776 +30 Ma from the metapelite, 1714+35 Ma from the mafic granulite xenolith within the porphyroblastic gneiss, and 1776+30 Ma from the metapelite occurred as a xenolith within the quartzofeldspathic gneiss. There have been reports of geologic ages similar to such metamorphic ages of Jirisan area from the other portion of the Youngnam massif, which reveals that very intense metamorphism took place over the vast area of Youngnam massif during the period of 1.7-1.8 Ga ago. The granulite facies metomorphism of the Gyeonggi massif also shows the age similar to this period. Such resemblance in their metamorphic ages suggests that these massifs experienced similar tectonothermal events occurred at about the same Precambrian periods, which implies the possibility that the extension of the collision belt between the north and south China blocks does not extend through some places between the Youngnam and Gyeonggi massifs. On the other hand a quarzofeldspathic xenolith of porphyroblastic gneiss show 1928 +42 Ma which is older than above age of the metamorphism and is identical with the zircon U-Pb age of porphyroblastic gneiss indicating the formation age of the protolith of the porphyroblastic gneiss.

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Improvement Method of Sand Ground Using an Environmental Friendly Bio-grouting Material (친환경 바이오그라우팅을 이용한 모래지반 개량 공법)

  • Kim, Dae-Hyeon;Sagong, Myung;Park, Kyung-Ho
    • Journal of the Korean Society for Railway
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    • v.16 no.6
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    • pp.473-481
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    • 2013
  • The purpose of this research is to evaluate the improvements in the strength and injection range of loose ground after injecting $CaCO_3$(created by microorganism reaction). For this purpose, three cases of single-layer (Sand, SP, SW) specimens were made in a 150mm D ${\times}$ 200mm H space and two cases of multi-layer specimens (SW/SP, SP/SW) were made in a 150mm D ${\times}$ 300mm H space. The specimens were made with a relative density of 30% of soft ground and an injection was given over a time of one day. The uniaxial compression strength was measured with a cone penetrometer and the injection range was observed by checking the bulb formation around the injection nozzle. Also, the compositions of the specimens were assessed through XRD analyses. Based on the test results, a compressive strength of 500kPa and 15cm thick cementation were noted due to the cementation of the soil. This implies that there are significant effects of the pore condition and size on bio-grouting technology.

Flame Retardancy and Foaming Properties of the Waste-Polyethylene(W-PE)/Waste-Ethylene vinyl acetate copolymer(W-EVA) Blend Foams (폐폴리에틸린/폐에틸렌 비닐아세테이트공중합체 블렌드 발포체의 난연 및 발포 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.316-325
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    • 2003
  • The blends of waste-polyethylene (W-PE)/waste-ethylene vinyl acetate copolymer (W-EVA) with inorganic and phosphorous flame retardants (i.e., aluminium hydroxide, magnesium hydroxide, and so on) were prepared by melt mixing techniques at different compositions and foamed. The flame retardancy and foaming properties of the blends, limiting oxygen index (LOI), heat release rate (HRR), carbon monoxide yield (COY), total heat release (THR), effective heat of combustion (EHC), expandability and cell structure were investigated using cone calorimeter, SEM, LOI tester and polarizing microscope. When the composition ratios of the W-PE/W-EVA blends were 50/50 (w/w), and the ranges of the flame retardants contents were $175{\sim}220 phr$, we could obtain foams with the uniform and closed cell, high expandability (1900 % or more), high LOI, and low HRR values. These results depend on crosslinking and loaming conditions, a char formation and smoke suppressing effect. Aluminium hydroxide had more effect in the increase of LOI than magnesium hydroxide, while magnesium hydroxide considerably affected the decrease of HRR and COY.

Chemical Characteristics of Gochujang with Different Amount of Sweet Persimmon Powder (단감 분말의 첨가비율을 달리하여 제조한 고추장의 화학적 특성)

  • Kim, Jeong-Yeon;Hwang, Su-Jung;Eun, Jong-Bang
    • Food Science and Preservation
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    • v.18 no.5
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    • pp.706-713
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    • 2011
  • This study was conducted to investigate the chemical characteristics of Gochujang with different amounts of sweet persimmon powder added during fermentation at $20^{\circ}C$ for 90 days, in an effort to improve its taste and organoleptic quality. The moisture content was shown to be inclined to increase in all the treatments throughout the fermentation. There was no significant difference between the paste with sweet persimmon powder and the control. The pH showed a tendency to decrease with increased fermentation time in all the samples during fermentation, keeping a pH range of 4.64-4.67 after 60 days of fermentation. On the contrary, the titratable acidity increased during fermentation, showing a level of 0.147-0.156 mg% in the paste with sweet persimmon powder on the 90th day of fermentation. The sugar content was shown to be $33.67-39.67^{\circ}Brix$ in the early stage of fermentation, revealing a tendency to in crease with an increase in the amount of sweet persimmon powder added. The amino-type nitrogen content was at the 241.27-245.47 mg% level in the early stage of fermentation, and appeared to be significantly high (p<0.05) in the treatments with 3 and 4% sweet persimmon powder added, respectively, after 60 days of fermentation. The content was within the range of 357.47-371.53 mg% on the 90 th day of fermentation in the final stage, showing an increase trend throughout the fermentation. The alcohol content gradually increased with an increase in fermentation time, showing a range of 0.94-0.10% on the 90th day of the final stage of fermentation. Moreover, the content was highest (0.96-0.108%) on the 70th day of fermentation, demonstrating a trend to slightly decline in all the treatments thereafter.

Analysis of Fatty Acid Compositions and Biodiesel Properties of Seeds of Woody Oil Plants in Korea (국내 목본 유지식물 종자의 지방산 조성 및 바이오디젤 특성 분석)

  • Kim, Kwang Soo;Lee, Yong Hwa;Jang, Young Seok;Choi, In Hu
    • Korean Journal of Plant Resources
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    • v.26 no.5
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    • pp.628-635
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    • 2013
  • In order to evaluate their potential as sources of biodiesel, oil content and fatty acid composition of seeds and fatty acid methyl ester (FAME) properties from seven woody oil plants in Korea were analysed. The oil content of seed of all woody plant species ranged from 15.1 (Ligustrum lucidum) to 70.3% (Camellia japonica) by dry weight. Fatty acid composition consisted mainly of oleic acid, linoleic acid, linolenic acid, palmitic acid and stearic acid, with oleic acid being the most abundant. The content of unsaturated fatty acids of all species was higher than saturated fatty acids. Oxidation stability of seed oils of all woody plants ranged from 2.25 to 8.62 hours/$110^{\circ}C$. Fatty acid methyl ester of Styrax japonica has been found to have the highest iodine value, indicating that unsaturated fatty acid content is higher than other seed oils. Cold filter plug point(CFPP) was varied over a wide range from $0^{\circ}C$ to $-13^{\circ}C$. The cold fluidity of FAME of Chionanthus retusa were excellent.

In Vitro and In Vivo Studies of Different Liposomes Containing Topotecan

  • Hao, Yan-Li;Deng, Ying-Jie;Chen, Yan;Wang, Xiu-Min;Zhong, Hai-Jun;Suo, Xu-Bin
    • Archives of Pharmacal Research
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    • v.28 no.5
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    • pp.626-635
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    • 2005
  • Liposome as a carrier of topotecan (TPT), a promising anticancer drug, has been reported in attempt to improve the stability and antitumor activity of TPT. However, the biodistr ibution pattern of TPT liposome in vivo and PEG-modified liposome containing TPT have not been studied systemically. In this paper, the in vitro stability and in vivo biodistribution behavior of several liposomes containing TPT with different lipid compositions and PEG-modification were studied. Compared with the 'fluid' liposome (S-Lip) composed of soybean phosphatidylcholine (SPC), the 'solid' liposome (H-Lip) composed of hydrogenated soybean phosphatidylcholine HSPC decreased the leaking efficiency of TPT from liposome and enhanced the stability of liposome in fetal bovine serum (FBS) or human blood plasma (HBP). The results of biodistribution studies in S$_{180}$ tumor-bearing mice showed that liposomal encapsulation increased the concentrations of total TPT and the ratio of lactone form in plasma. Compared with free TPT, S-Lip and H-Lip resulted in 5- and 19- fold increase in the area under the curve (AUC$_{0\rightarrow\propto}$), respectively. PEG- modified H-Lip (H-PEG) showed 3.7-fold increase in AUC$_{0\rightarrow\propto}$ compared with H-Lip, but there was no significant increase in t$_{1/2}$ and AUC$_{0\rightarrow\propto}$ for PEG-modified S-Lip (S-PEG) compared with S-Lip. Moreover, the liposomal encapsulation changed the biodistribution behavior, and H-Lip and H-PEG dramatically increased the accumulation of TPT in tumor, and the relative tumor uptake ratios were 3.4 and 4.3 compared with free drug, respectively. There was also a marked increase in the distribution of TPT in lung when the drug was encapsulated into H-Lip and H-PEG. Moreover, H-PEG decreased the accumulation of TPT in bore marrow compared with unmodified H-Lip. All these results indicated that the membrane fluidity of liposome has an important effect on in vitro stability and in vivo biodistribution pattern of liposomes containing TPT, and PEG-modified 'solid' liposome may be an efficient carrier of TPT.

Differences in Breeding Bird Communities by Post-fire Restoration Methods (산불 후 복원방법의 차이가 번식기 조류 군집에 미치는 영향)

  • Kim, Jin-Yong;Lee, Eun-Jae;Choi, Chang-Yong;Lee, Woo-Shin;Lim, Joo-Hoon
    • Korean Journal of Environment and Ecology
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    • v.29 no.4
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    • pp.508-515
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    • 2015
  • Post-fire restoration can affect breeding bird communities and species compositions over a long-term period by determining pot-fire succession, and a long-term monitoring is therefore required to understand its impacts on forest birds. This study aimed to document the effects of post-fire restoration methods on breeding bird communities in three areas: unburned and two burned (nonintervention and intervention with clear-cut logging and planting) stands 13 years after the stand-replacing Samcheok forest fire at Mt. Geombong in Samcheok, South Korea. According to 108 point counts during the breeding season from April to June 2013, we found that the number of individuals, observed bird species, and species diversity index in intervention stands with clear-cut logging and planting were lower than that in nonintervention and unburned control stands. Foraging and nesting guild analysis also showed a lower abundance of foliage searchers, timber drillers, primary cavity nesters and secondary cavity nesters in intervention stands than in the other stands, while no significant difference was detected between the nonintervention and unburned stands. These results imply that an interventional restoration method may deter the recovery of avian breeding communities after forest fires, and also suggest that non-interventional restoration methods may be an effective way to benefit the species diversity and density of breeding bird communities.

Ground Beetle (Coleoptera: Carabidae) Assemblage Structure in Taeanhaean National Park : A Comparison between Coastal Dune and Windbreak Forest (태안해안국립공원 내 지표성 딱정벌레류(딱정벌레목 : 딱정벌레과) 군집 구조 : 사구와 방풍림 간의 비교)

  • Jung, Jong-Kook;Hong, EuiJeong;Kim, Tae Geun;Jeong, Jong-Chul
    • Korean Journal of Environment and Ecology
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    • v.32 no.2
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    • pp.147-153
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    • 2018
  • There are few available studies for insect diversity in relation to coastal dune despite the unique landscape features and high conservation value. Therefore, this study compared ground beetle assemblages inhabiting between windbreak forests and sand dunes in the Taeanhaean National Park. It investigated five windbreak forests and three coastal dunes using pitfall traps from middle of June to middle of October in 2014. A total of 2,335 ground beetles belonging to 30 species of 15 genera were collected. Synuchus arcuarticollis (158 individuals) and Dolichus halensis halensis (153 individuals) were dominant of 25 specifies collected from sand dunes while Synuchus arcuarticollis (1,630 individuals), Synuchus nitidus (130 individuals), and Synuchus cycloderus (42 individuals) were dominant of 14 species collected from windbreak forests. The similarity of ground beetles compositions in sand dunes and windbreak forests was significantly low at 27.4%. The results of this study showed that sand dune geographical features found in the Taeanhaean National Park had different insect assemblages from windbreak forests. It will be the useful information for conservation of insects in the future.

The Late Cretaceous Emplacement Age of Masan Hornblende-Biotite Granite (마산 각섬석-흑운모 화강암의 연령: 후기 백악기 정치연령)

  • Lee, Tae-Ho;Park, Kye-Hun;Kim, Jeongmin;Kim, Myoung Jung
    • The Journal of the Petrological Society of Korea
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    • v.26 no.1
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    • pp.1-11
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    • 2017
  • We have dated the K-Ar, Ar-Ar and U-Pb ages of the Masan hornblende-biotite granite in the southern Cretaceous Gyeongsang basin to constrain its emplacement age. The ~108 Ma hornblende K-Ar age obtained in the study is similar to the previously reported Rb-Sr age. However, the single grain total fusion $^{40}Ar/^{39}Ar$ dating on hornblende failed to yield statistically meaningful ages because the isotopic system was open during its alteration. Thus the hornblende K-Ar age in the study is also unlikely to be reliable. The single grain total fusion $^{40}Ar/^{39}Ar$ dating on biotite yielded an average age of $75.8{\pm}3.0Ma$. Apart from scattered data in the range of ~45-75 Ma, the average age increased to ~80 Ma. The SHRIMP and LA-MC-ICPMS U-Pb isotopic compositions of zircon from the Masan hornblende-biotite granite yielded its emplacement age as $87.6{\pm}2.7Ma$ and $86.8{\pm}0.4Ma$, respectively. It is thus likely that the ~80 Ma $^{40}Ar/^{39}Ar$ age of biotite might reflect the cooling age of Masan hornblende-biotite granite or the thermal influences from later intense igneous activities in the Gyeongsang basin.

The Component and Compositional Analysis of Trace Materials in LPG (LPG 잔류물질의 성분 및 조성 분석)

  • Kim, Yeong-Gu
    • Journal of the Korean Chemical Society
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    • v.46 no.4
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    • pp.317-323
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    • 2002
  • The composition of trace materials in domestic circulated LPG are determined. The sampling points are two cylinders of LPG cylinder re-inspection center, six vaporizer of LPG-supplying group facilities, and the compressed oil from one LPG station. In the trace materials from cylinder of LPG cylinder-reinspection center, alkene and diene derivative (No. of carbon ${\leq}9),$ aromatic compounds, and tarry chemicals(No. of carbon ${\geq}10)$ are 1.5~39.9%, 0.7%, 57.8~96.0%, respectively. While in the trace materials from LPG-supplying group facilities and in the oil from LPG station, tarry chemicals(No. of carbon>10) exceed 96.6%. Nine samples are classified into three clusters. One cluster is the sample of SE company cylinder-reinspection center(Euclidian distance between S company LPG cylinder-reinspection center and SE company cylinder-reinspection center=2.11), the other is the sample of SE company LPG cylinder-reinspection center(Euclidian distance between from samples of LPG-supplying group facilities including compressed oil from LPG station=0.110) the third is the samples of LPG-supplying group facilities(Euclidian distances among them<0.075). The compositions of samples from LPG-supplying group facilities are similar to those of oil from LPG station. Furthermore densities of samples from LPG-supplying group facilities and compressed oil in LPG station are 0.873, 0.873 [0.00798 (99% confidence limits) respectively. It was presumed that tarry chemicals had been leached from the compressed oil of LPG supplying facilities.