• 제목/요약/키워드: compositional change

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초피 정유의 저장 중 향기성분 변화 (Compositional Changes in Essential Oil of Zanthoxylum piperitum A.P. DC. During Storage)

  • 정미숙
    • 한국식생활문화학회지
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    • 제21권4호
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    • pp.433-438
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    • 2006
  • Compositional changes In essential oil of Zanthoxylum piperitum A.P. DC. were investigated under six different storage conditions for 3 months. Essential oil from Zanthoxylum piperitum was collected by steam distillation method and analyzed by gas chromatography-mass selective detector (GC-MSD). Forty-one volatile compounds, consisting of 12 hydrocarbons, 11 alcohols, 8 aldehydes, 3 oxides, 3 esters, 3 ketones and 1 acid were identified from the fresh essential oil of Zanthoxylum piperitum. In essential oils, compositional changes occurred in particularly monoterpene hydrocarbons. Total levels of ketones, esters, oxides and alcohols increased during storage. Moreover, aerobic condition caused decrease in a few constituents duringstorage even at low temperature.

Microbiome Study of Initial Gut Microbiota from Newborn Infants to Children Reveals that Diet Determines Its Compositional Development

  • Ku, Hye-Jin;Kim, You-Tae;Lee, Ju-Hoon
    • Journal of Microbiology and Biotechnology
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    • 제30권7호
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    • pp.1067-1071
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    • 2020
  • To understand the formation of initial gut microbiota, three initial fecal samples were collected from two groups of two breast milk-fed (BM1) and seven formula milk-fed (FM1) infants, and the compositional changes in gut microbiota were determined using metagenomics. Compositional change analysis during week one showed that Bifidobacterium increased from the first to the third fecal samples in the BM1 group (1.3% to 35.1%), while Klebsiella and Serratia were detected in the third fecal sample of the FM1 group (4.4% and 34.2%, respectively), suggesting the beneficial effect of breast milk intake. To further understand the compositional changes during progression from infancy to childhood (i.e., from three weeks to five years of age), additional fecal samples were collected from four groups of two breast milk-fed infants (BM2), one formula milk-fed toddler (FM2), three weaning food-fed toddlers (WF), and three solid food-fed children (SF). Subsequent compositional change analysis and principal coordinates analysis (PCoA) revealed that the composition of the gut microbiota changed from an infant-like composition to an adult-like one in conjunction with dietary changes. Interestingly, overall gut microbiota composition analyses during the period of progression from infancy to childhood suggested increasing complexity of gut microbiota as well as emergence of a new species of bacteria capable of digesting complex carbohydrates in WF and SF groups, substantiating that diet type is a key factor in determining the composition of gut microbiota. Consequently, this study may be useful as a guide to understanding the development of initial gut microbiota based on diet.

영주저반의 부석심성암체 내에서 공간적 조성변화와 그 성인 (Spatial Compositional Variations and their Origins in the Buseok Pluton, Yeongju Batholith)

  • 황상구
    • 자원환경지질
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    • 제33권2호
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    • pp.147-163
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    • 2000
  • The Buseok pluton in the Yeongju Batholith is a comagmatic plutonic rocks which haveconcentrically compositional zoning. The lithofacies of the Buseok pluton comprise hornblende biotite tonalite in the southern part of the pluton, porphyritic and equigranular biotite granodiorite in the northern part and biotite granite in the north-central part. The compositional variations change gradually with continuity both within and between the lithofacies. The concentrically zoned pattern is relatively mafic rocks composed of high-temperature mineral assemblages in margin of the southern part, passing inward and northward gradually to more felsic rock in core of the north-central part. Changes in the textures and microstructures, as well as in the mineral content, take place between rock types of the plutons. Darker colored, generally coarse-grained, well foliated tonalite pass inward to light colored, coarse-grained, poorly foliated granodiorite, and finally give way to lighter colored, medium-grained, nearly nonfoliated granite. The foliation are best developed in the marginal part of the tonalite. Here, the regional myolitic foliation in the tonalite is steep northward and parallels to its southeastern contact with the country rock, but the magmatic foliation from disc-shaped mafic microgranitoid enclaves is subvertical and parallels the contacts with the country rock. As the tonalite approaches biotite granite in composition, the foliation is indistinct. Modal and chemical data for the pluton show quantitative compositional variation from the margin of the southern part to the core of the north-central part. Quartz and K-feldspar increase toward the core of the pluton, whereas hornblende, biotite and color index decrease. /Abundances of $SiO_2$and $K_2O$$_2$O increase toward the core according to the variation in quartz and K-feldspar, whereas those of MnO, CaO, $TiO_2$, $Fe_2O_3$, MgO and $P_2O_5$ decrease corresponding to the variation in mafic and accessaries. The compositional zonation resulted from fractional crystallization involving downward settling of earlier crystals, accompanied by upward movement of melt and volatiles, and followed by accessary marginal accretion of crystalline material in the magma to the marginal part. Although a little crustal contamination by the wall rock is recognized from the isotope data, the contamination is not only dominated over but also appropriate for forming the compositional variation in the pluton.

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P2O5-ZnO-SiO2-R2O Glass Frit Materials for Hermetic Sealing of Dye-Sensitized Solar Cells

  • Lee, Hansol;Lee, Choon Yeob;Hwang, Jae Kwun;Chung, Woon Jin
    • 한국세라믹학회지
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    • 제54권5호
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    • pp.400-405
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    • 2017
  • $P_2O_5-ZnO-SiO_2-R_2O$ glasses were synthesized as a sealing material for large scale dye-sensitized solar cells (DSSC). Compositional effects of $P_2O_5$ and ZnO were examined by varying their contents. Their viscosity and glass stability at sintering temperatures of less than $550^{\circ}C$ were examined by flow button test. Glass transition temperature and structural change upon compositional change were investigated. Chemical stability against electrolyte was also examined by immersing the glasses in the electrolyte for 72 h at $85^{\circ}C$.

류금두공의 양식적 형성과정 연구 (A Study on the Style Emergence of Liujin Dougong)

  • 백소훈
    • 건축역사연구
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    • 제26권3호
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    • pp.19-30
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    • 2017
  • This paper studies the style emergence of Liujin Dougong in the ancient Chinese architecture. Dougong is the bracket set of the ancient Chinese wood structural architecture, and Liujin Dougong is one of the late styles of Chinese Dougong. It emerged in the period of the Ming Dynasty and has been installed in imperial palaces and imperial temples till the late period of the Qing Dynasty. Through the long term field survey and documental investigation, this research found out the some prototypes of Liujin Dougong among the earlier Xia-ang style Dougongs in the Song and Yuan Dynasty architectures. The symptom of style change appeared in the bracket composition. In the beginning, because Shuatou, the horizontal member just on Xia-ang was needed to be fixed to the inner main structure system, it was changed to the diagonal member and replaced Xia-ang. It brought continuous changes, the other horizontal members of Dougong also began to change to the diagonal form. And in accordance with these compositional changes of Dougong members, the decoration of inner parts also began to change. This paper analyzed every step of the compositional and decorative changes from Xia-ang Dougong style to Liujin Dougong style. In the addition, it also proposed the typical model of Qing style Liujin Dougong of which tail end is not placed on the beam and is just placed under the purlin, based on the its own research and analysis.

제조업 고용구조변화의 특징 분석 (Structural Change and Employment in Manufacturing Sector -Polarization by Firm Size-)

  • 고상원
    • 기술혁신연구
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    • 제7권1호
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    • pp.14-35
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    • 1999
  • This paper presents the relationship between the pace of structural change and the magnitude of employment growth in the manufacturing sector in OECD countries. To measure the pace of structural change, the compositional change index in value-added in manufacturing sector is introduced. For mid to long-term there seems to be a positive relationship between the pace of structural change and the magnitude of employment growth. In those countries with higher value of the compositional index, the employment growth in manufacturing sector was generally higher. To analyse the characteristics of structural change in manufacturing sector, this paper classifies manufacturing industries into groups: one based on technology, one on orientation, one on wages and one on skills. The international comparison of manufacturing sector's employment patterns based on above four classifications are presented. International comparison suggests that Korean manufacturing sector move into jobs with more skills and knowledge The structural change of SMEs and large firms are compared based on above four classification methods. It is shown that SMEs' employment in low value sectors, that is low-technology, labor-intensive, tow-wage, and unskilled sectors, have risen faster than SMEs' employment in high-technology, science-based, high-wage and skilled sectors. Large firms' employment have been mainly increased in high value sectors. However, the employment growth of both large and small firms have been concentrated on production worker-intensively-using sectors, i.e. unskilled sectors. This widened the wage differential of production workers by firm sizes and concurrently led to severe shortage of production workers for SMEs, which has little ability to pay high wage to production workers because they usually belong to low-wage sectors. Korea need to push SMEs forward to high value sectors. The premise of that is, however, to pull large firms out of production worker-intensively-using sectors.

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금속-도재관용 Ni-Cr합금의 조성변화와 소성단계에 따른 전단결합강도 (Observation of Shear Bonding Strength by Compositional Change and Firing Steps of the Ni-Cr Alloy for Porcelain Fused Metal Crown)

  • 조용완;홍민호;김원영;최성민;정인성
    • 대한치과기공학회지
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    • 제35권4호
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    • pp.353-358
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    • 2013
  • Purpose: This study was observation shear bonding strength by compositional change and firing step of a Ni-Cr alloy for porcelain fused metal crown. The aim of study was to suggest the material for firing step of Ni71-Cr14 alloy to development of alloy for porcelain fused to metal crown. Methods: The test was on the two kinds of Ni-Cr alloy specimens. The surfaces of two alloys were analyzed by EDX in order to observe oxide characteristic. And the shear test was performed by MTS. Results: The surface property and oxide characteristic analysis of oxide layer, weight percentage of Element O within $Ni_{71}Cr_{14}$ alloy measured 23.32wt%, and $Ni_{59}Cr_{24}$ alloy was measured 23.03wt%. And the maximum shear bonding strength was measured 58.02MPa between $Ni_{59}Cr_{24}$ alloy and vintage halo(H4 group). Conclusion: The surface property and oxide characteristic three kind of Ni-Cr alloy was similar. and shear bonding strength showed the highest bonding strength in H4 specimens.

Thermodynamics for Formation of Each Stable Single Phase in BSCCO Thin Films

  • Yang, Sung-Ho;Park, Yong-Pil;Kim, Gwi-Yeol
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2000년도 추계학술대회논문집
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    • pp.104-105
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    • 2000
  • High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, T$_{sub}$, and ozone gas pressures, PO$_3$. The correlation diagrams of the BSCCO phases appeared against T$_{sub}$ and PO$_3$are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 phases as well as Bi2212 one come out as stable phases depending on T$_{sub}$ and PO$_3$. From these results, the thermodynamic evaluations of ΔH and ΔS which are related with Gibbs'free energy change for single Bi2212 or Bi2223 phase are performed.ormed.i2212 or Bi2223 phase are performed.

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표면분석용 인증표준물질의 개발 I : 표면조성분석용 합금박막 표준물질 (Development of certified reference material (CRM)s for surface analysis I : alloy thin film for surface compositional analysis)

  • 김경중;박용섭;문대원
    • 한국진공학회지
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    • 제8권3B호
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    • pp.276-282
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    • 1999
  • For the quantitative surface analysis of multicomponent materials, algorithms for the compensation of the matrix effect and surface compositional change by ion beam sputtering must be established and reference materials having certified compositions are necessary. These certified reference material (CRM)s are needed for the improvement of instrument performance, inter-laboratory comparison and quantitative surface analysis. Surface analysis group of KRISS developed alloy thin film CRMs by and ion beam sputter deposition system and in-situ surface analysis system to control the composition of alloy thin films The real compositions of the CRMs were certified by inductively coupled plasma-atomic emission spectroscopy (ICP-AES).

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