Browse > Article
http://dx.doi.org/10.4191/kcers.2017.54.5.04

P2O5-ZnO-SiO2-R2O Glass Frit Materials for Hermetic Sealing of Dye-Sensitized Solar Cells  

Lee, Hansol (Division of Advanced Materials Engineering & Institute for Rare Metals, Kongju National University)
Lee, Choon Yeob (R&D Center, ORION Co., Ltd.)
Hwang, Jae Kwun (R&D Center, ORION Co., Ltd.)
Chung, Woon Jin (Division of Advanced Materials Engineering & Institute for Rare Metals, Kongju National University)
Publication Information
Journal of the Korean Ceramic Society / v.54, no.5, 2017 , pp. 400-405 More about this Journal
Abstract
$P_2O_5-ZnO-SiO_2-R_2O$ glasses were synthesized as a sealing material for large scale dye-sensitized solar cells (DSSC). Compositional effects of $P_2O_5$ and ZnO were examined by varying their contents. Their viscosity and glass stability at sintering temperatures of less than $550^{\circ}C$ were examined by flow button test. Glass transition temperature and structural change upon compositional change were investigated. Chemical stability against electrolyte was also examined by immersing the glasses in the electrolyte for 72 h at $85^{\circ}C$.
Keywords
Glass; Sealing; Frit; Phosphate; DSSC;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 D. Wei, "Dye Sensitized Solar Cells," Int. J. Mol. Sci., 11 [3] 1103-13 (2010).   DOI
2 M. Gratzel, "Dye-Sensitized Solar Cells," J. Photochem. Photobiol., C, 4 [2] 145-53 (2003).   DOI
3 S. R. Sim, J. H. Yoon, and U. C. Shin, "A Study on the Effect of DSSC BIPV Window System in Office Building Considering Cooling.Heating.Lighting Energy," J. Kor. Sol. Energy Soc., 31 [3] 67-72 (2011).   DOI
4 H. Tian, X., J. Zhang, W. Duan, F. Tian, and X. Yu, "The Influence of Environmental Factors on DSSCs for BIPV," Int. J. Electrochem. Sci., 7 4686-91 (2012).
5 H. Matsui, K. Okada, T. Kitamura, and N. Tanabe, "Thermal Stability of Dye-Sensitized Solar Cells with Current Collecting Grid," Sol. Energy Mater. Sol. Cells, 93 [6] 1110-15 (2009).   DOI
6 M. N. Amalina and M. Rusop, "The Performance of Solid-State Dye Sensitized Solar Cells with Mist-Atomized CuI as the Hole Conductors," pp. 49-55 in Recent Trends in Nanotechnology and Materials Science, Springer, 2013.
7 H. S. Lee, J. W. Cho, J. W. Hwang, and W. J. Chung, "$V_2O_5$-$P_2O_5$-ZnO-$Sb_2O_3$ Glass Frit Materials with BaO and $Al_2O_3$ for Large-sized Dye-sensitized Solar Cell Sealing," J. Korean Ceram. Soc., 52 [2] 114-18 (2015).   DOI
8 E. Stathatos and P. Lianos, "Dye-Sensitized Photoelectrochemical Solar Cells Based on Nanocomposite Organic- Inorganic Materials," J. Photochem. Photobiol., A, 169 [1] 57-61 (2005).   DOI
9 I. Lee, S. Hwang, and H. Kim, "Reaction between Oxide Sealant and Liquid Electrolyte in Dye-Sensitized Solar Cells," Sol. Energy Mater. Sol. Cells, 95 [1] 315-17 (2011).   DOI
10 S. J. Cho and K. H. Lee, "Laser Sealing of Dye-Sensitized Solar Cell Panels Using $V_2O_5$ and $TeO_2$ Contained Glass," J. Korean Ceram. Soc., 51 [3] 170-76 (2014).   DOI
11 R. Sastrawan, J. Beier, U. Belledin, S. Hemming, A. Hinsch, R. Kern, C. Vetter, F. M. Petrat, A. Prodi-Schwab, P. Lechner, and W. Hoffmann, "New Interdigital Design for Large Area Dye Solar Modules Using a Lead-free Glass Frit Sealing," Prog. Photovoltaics, 14 [8] 697-709 (2006).   DOI
12 J. J. Hudgens, R. K. Brow, D. R. Tallant, and S. W. Martin, "Raman Spectroscopy Study of the Structure of Lithium and Sodium Ultraphosphate Glasses," J. Non-Cryst. Solids, 223 [1] 21-31 (1998).   DOI
13 R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, "The Short-Range Structure of Zinc Polyphosphate Glass," J. Non-Cryst. Solids, 191 [1-2] 45-55 (1995).   DOI
14 R. K. Brow, C. A. Click, and T. M. Alam, "Modifier Coordination and Phosphate Glass Networks," J. Non-Cryst. Solids, 274 [1] 9-16 (2000).   DOI
15 J. M. Koo, B. S. Bae, and H. K. Na, "Raman Spectroscopy of Copper Phosphate Glasses," J. Non-Cryst. Solids, 212 [2-3] 173-79 (1997).   DOI
16 R. K. Brow, "Review: the Structure of Simple Phosphate Glasses," J. Non-Cryst. Solids, 263-264 [1] 1-28 (2000).   DOI