• Advances in nano research
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• v.1 no.2
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• pp.71-82
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• 2013

A simple chemical precipitation technique is reported for the synthesis of a hybrid nanostructure of single-wall carbon nanotubes (SWCNT) and titania ($TiO_2$) nanocrystals of average size 5 nm, which may be useful as a prominent photocatalytic material with improved functionality. The synthesized hybrid structure has been characterized by transmission electron microscopy (HRTEM), energy-dispersive X-ray analysis (EDAX), powder X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. It is clearly revealed that nearly monodispersed titania nanocrystals (anatase phase) of average size 5 nm decorate the surfaces of SWCNT bundles. The UV-vis absorption study shows a blue shift of 16 nm in the absorbance peak position of the composite material compared to the unmodified SWCNTs. The photoluminescence study shows a violet-blue emission in the range of 325-500 nm with a peak emission at 400 nm. The low temperature electrical transport property of the synthesized nanomaterial has been studied between 77-300 K. The DC conductivity shows semiconductor-like characteristics with conductivity increasing sharply with temperature in the range of 175-300 K. Such nanocomposites may find wide applications as improved photocatalyst due to transfer of photo-ejected electrons from $TiO_2$ to SWCNT, thus reducing recombination, with the SWCNT scaffold providing a firm and better positioning of the catalytic material.

• Steel and Composite Structures
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• v.34 no.3
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• pp.377-391
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• 2020

A concrete filled steel tube (CFT) column with stiffeners has preferable behavior subjected to axial loading condition due to delay local buckling of the steel wall than traditional CFT columns without stiffeners. Welding lines in welded built-up steel box columns is expected to behave as longitudinal stiffeners. This study has presented a numerical investigation into the behavior of built-up concrete filled steel tube columns under axial pressure. At first stage, a finite element model (FE) has been built to simulate the behavior of built-up CFT columns. Comparing the results of FE and test has shown that numerical model passes the desired conditions and could accurately predict the axial performance of CFT column. Also, by the raise of steel tube thickness, the load bearing capacity of columns has been increased due to higher confinement effect. Also, the raise of concrete strength with greater cross section is led to a higher load bearing capacity compared to the steel tube thickness increment. In CFT columns with greater cross section, concrete strength has a higher influence on load bearing capacity which is noticeable in columns with more welding lines.

• Journal of the Korean Society of Safety
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• v.30 no.1
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• pp.8-13
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• 2015

The experimental design methodology was applied in the drop tube furnace (DTF) to predict the various combustion properties according to the operating conditions and to assess the coal plant safety. Response surface method (RSM) was introduced as a design of experiment, and the database for RSM was set with the numerical simulation of DTF. The dependent variables such as burnout ratios (BOR) of coal and $CO/CO_2$ ratios were mathematically described as a function of three independent variables (coal particle size, carrier gas flow rate, wall temperature) being modeled by the use of the central composite design (CCD), and evaluated using a second-order polynomial multiple regression model. The prediction of BOR showed a high coefficient of determination (R2) value, thus ensuring a satisfactory adjustment of the second-order polynomial multiple regression model with the simulation data. However, $CO/CO_2$ ratio had a big difference between calculated values and predicted values using conventional RSM, which might be mainly due to the dependent variable increses or decrease very steeply, and hence the second order polynomial cannot follow the rates. To relax the increasing rate of dependent variable, $CO/CO_2$ ratio was taken as common logarithms and worked again with RSM. The application of logarithms in the transformation of dependent variables showed that the accuracy was highly enhanced and predicted the simulation data well.

• Steel and Composite Structures
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• v.18 no.4
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• pp.833-852
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• 2015

Self-compacting Concrete Filled steel Tubes (SCFT), which combines the advantages of steel and concrete materials, can be applied to strengthen the RC columns. In order to investigate the eccentric loading behavior of the strengthened columns, this paper presents an experimental and numerical investigation on them. The experimental results showed that the use of SCFT is interesting since the ductility and the bearing capacity of the RC columns are greatly improved. And the performance of strengthened columns is significantly affected by four parameters: column section type (circular and square), wall thickness of the steel tube, designed strength grade of strengthening concrete and initial eccentricity. In the numerical program, a generic fiber element model which takes in account the effect of confinement is developed to predict the behavior of the strengthened columns subjected to eccentric loading. After the fiber element analysis was verified against experimental results, a simple design formula based on the model is proposed to calculate the ultimate eccentric strength. Calibration of the calculated results against the test results shows that the design formula closely estimates the ultimate capacities of the eccentrically compressed strengthened columns by 5%.

• Journal of Advanced Research in Ocean Engineering
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• v.1 no.1
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• pp.44-54
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• 2015

Breakwaters are the coastal structures constructed either perpendicular (shore connected) or parallel (detached) to the coast. The main function of breakwater is to create a tranquil medium on its leeside by reflecting the waves and also dissipating the wave energy arriving from seaside, resulting in ease of manoeuvrability to boats or ships to their berthing places. Different types of breakwaters are being used at present, such as rubble mound breakwater, vertical wall type breakwater and composite breakwater. The objective of this paper is to investigate reflection coefficients (Kr) and dissipation (loss) coefficients (Kl) for physical models of Quarter circle caisson breakwater of three different radii of 0.550 m, 0.575 m and 0.600 m with S/D ratio of 2.5 (S=spacing between perforations, D=diameter of perforations). The models were tested in the monochromatic wave flume of the department, for different incident wave heights (Hi), Wave periods (T) and water depths (d). It was observed that reflection coefficient increased with increase in the wave steepness (Hi/gT2) and decreased with increase in depth parameter (d/gT2) and hs/d (Height of structure including rubble base/depth of water). The loss coefficient decreased with increase in the wave steepness and increased with increase in depth parameter and hs/d.

• Journal of Powder Materials
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• v.21 no.1
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• pp.34-38
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• 2014

Cu-Ni alloys with unidirectionally aligned pores were prepared by freeze-drying process of CuO-NiO/camphene slurry. Camphene slurries with dispersion stability by the addition of oligomeric polyester were frozen at $-25^{\circ}C$, and pores in the frozen specimens were generated by sublimation of the camphene during drying in air. The green bodies were hydrogen-reduced at $300^{\circ}C$ and sintered at $850^{\circ}C$ for 1 h. X-ray diffraction analysis revealed that CuO-NiO composite powders were completely converted to Cu-Ni alloy without any reaction phases by hydrogen reduction. The sintered samples showed large and aligned parallel pores to the camphene growth direction, and small pores in the internal wall of large pores. The pore size and porosity decreased with increase in CuO-NiO content from 5 to 10 vol%. The change of pore characteristics was explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

• Steel and Composite Structures
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• v.17 no.4
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• pp.431-452
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• 2014

The present study focuses on the mechanical behaviour of concrete filled double skin steel tubular (CFDST) stub columns confined by fiber reinforced polymer (FRP). A series of axial compression tests have been conducted on two CFDST stub columns, eight CFDST stub columns confined by FRP and a concrete-filled steel tubular (CFST) stub column confined by FRP, respectively. The influences of hollow section ratio, FRP wall thickness and fibre longitudinal-circumferential proportion on the load-strain curve and the concrete stress-strain curve for stub columns with annular section were discussed. The test results displayed that the FRP jacket can obviously enhance the carrying capacity of stub columns. Based on the test results, a new model which includes the effects of confinement factor, hollow section ratio and lateral confining pressure of the outer steel tube was proposed to calculate the compressive strength of confined concrete. Using the present concrete strength model, the formula to predict the carrying capacity of CFDST stub columns confined by FRP was derived. The theoretically predicted results agree well with those obtained from the experiments and FE analysis. The present method is also adapted to calculate the carrying capacity of CFST stub columns confined by FRP.

• Steel and Composite Structures
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• v.24 no.3
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• pp.323-337
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• 2017

This paper presents the results of a comprehensive experimental investigation on the compressive behaviour of steel tube-confined concrete (STCC) stub columns with active and passive confinement. To create active confinement in STCC columns, an innovative technique is used in which steel tube is laterally pre-tensioned while the concrete core is simultaneously pre-compressed by applying pressure on fresh concrete. A total of 135 STCC specimens with active and passive confinement are tested under axial compression load and their compressive strength, ultimate strain capacity, axial and lateral stress-strain curves and failure mode are evaluated. The test variables include concrete compressive strength, outer diameter to wall thickness ratio of steel tube and prestressing level. It is shown that applying active confinement on STCC specimens can considerably improve their mechanical properties. However, applying higher prestressing levels and keeping the applied pressure for a long time do not considerably affect the mechanical properties of actively confined specimens. Based on the results of this study, new empirical equations are proposed to estimate the axial strength and ultimate strain capacity of STCC stub columns with active and passive confinement.

• Korean Journal of Materials Research
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• v.20 no.9
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• pp.478-482
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• 2010

A series of molecular dynamic (MD), finite element (FE) and ab initio simulations are carried out to establish suitable modeling schemes for the continuum-based analysis of aluminum matrix nanocomposites reinforced with carbon nanotubes (CNTs). From a comparison of the MD with FE models and inferences based on bond structures and electron distributions, we propose that the effective thickness of a CNT wall for its continuum representation should be related to the graphitic inter-planar spacing of 3.4${\AA}$. We also show that shell element representation of a CNT structure in the FE models properly simulated the carbon-carbon covalent bonding and long-range interactions in terms of the load-displacement behaviors. Estimation of the effective interfacial elastic properties by ab initio simulations showed that the in-plane interfacial bond strength is negligibly weaker than the normal counterpart due to the nature of the weak secondary bonding at the CNT-Al interface. Therefore, we suggest that a third-phase solid element representation of the CNT-Al interface in nanocomposites is not physically meaningful and that spring or bar element representation of the weak interfacial bonding would be more appropriate as in the cases of polymer matrix counterparts. The possibility of treating the interface as a simply contacted phase boundary is also discussed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.11a
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• pp.215-218
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• 2007

Internal Ballistic modeling and performance prediction for solid propellant micro thruster was performed with heat loss to the chamber wall as an important factor of miniaturization. Simple l-D end-burner type thruster and general HTPB-AP type composite propellant were selected for computation model. The results showed that the performance loss with the heat loss to the surroundings becomes larger as the surface-to-volume ratio is increased. In this case, the total impulse was reduced about 3% of the case in adiabatic condition.