• Title/Summary/Keyword: complex mixture analysis

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Incineration of Waste Water Sludge and Coal In a Circulating Fluidized Bed Combustor (순환유동층에서 폐수슬러지와 석탄의 혼소 특성)

  • Bae, Dal-Hee;Shun, Do-Won;Park, Jae-Hyeon;Ryu, Ho-Jung;Park, Do-Hyun
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.165-172
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    • 2004
  • Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as $SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge.

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An Intelligent Automatic Early Detection System of Forest Fire Smoke Signatures using Gaussian Mixture Model

  • Yoon, Seok-Hwan;Min, Joonyoung
    • Journal of Information Processing Systems
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    • v.9 no.4
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    • pp.621-632
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    • 2013
  • The most important things for a forest fire detection system are the exact extraction of the smoke from image and being able to clearly distinguish the smoke from those with similar qualities, such as clouds and fog. This research presents an intelligent forest fire detection algorithm via image processing by using the Gaussian Mixture model (GMM), which can be applied to detect smoke at the earliest time possible in a forest. GMMs are usually addressed by making the model adaptive so that its parameters can track changing illuminations and by making the model more complex so that it can represent multimodal backgrounds more accurately for smoke plume segmentation in the forest. Also, in this paper, we suggest a way to classify the smoke plumes via a feature extraction using HSL(Hue, Saturation and Lightness or Luminanace) color space analysis.

Application of Clustering Methods for Interpretation of Petroleum Spectra from Negative-Mode ESI FT-ICR MS

  • Yeo, In-Joon;Lee, Jae-Won;Kim, Sung-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3151-3155
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    • 2010
  • This study was performed to develop analytical methods to better understand the properties and reactivity of petroleum, which is a highly complex organic mixture, using high-resolution mass spectrometry and statistical analysis. Ten crude oil samples were analyzed using negative-mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Clustering methods, including principle component analysis (PCA), hierarchical clustering analysis (HCA), and k-means clustering, were used to comparatively interpret the spectra. All the methods were consistent and showed that oxygen and sulfur-containing heteroatom species played important roles in clustering samples or peaks. The oxygen-containing samples had higher acidity than the other samples, and the clustering results were linked to properties of the crude oils. This study demonstrated that clustering methods provide a simple and effective way to interpret complex petroleomic data.

Form Follows Function - The Composite Construction and Mixed Structures in Modern Tall Buildings

  • Peng, Liu
    • International Journal of High-Rise Buildings
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    • v.3 no.3
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    • pp.191-198
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    • 2014
  • The tall building and super tall building has been a common building type in China, with multiple functions and complex geometry. Composite construction is broadly used in tall building structures and constitutes the mixed structure together with concrete and steel constructions. The mixture of the constructions is purposely designed for specific area based on the analysis results to achieve the best cost-effectiveness. New types of composite construction are conceived of by engineers for columns and walls. Material distribution is more flexible and innovative in the structural level and member level. However the reliability of computer model analysis should be verified carefully. Further researches in the design and build of composite construction are necessary to ensure the success of its application. Composite or Mixture Index is suggested to be used as a performance benchmark.

Error Analysis of Linear Mixture Model using Laboratory Spectral Measurements (실내 분광 측정자료를 이용한 선형혼합모델의 오차 분석)

  • Kim, Sun-Hwa;Shin, Jung-Il;Shin, Sang-Min;Lee, Kyu-Sung
    • Korean Journal of Remote Sensing
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    • v.23 no.6
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    • pp.537-546
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    • 2007
  • In hyperspectral remote sensing, linear spectral mixture model is a common procedure decomposing into the components of a mixed pixel and estimating the fraction of each end-member. Although linear spectral mixture model is frequently used in geology and mineral mapping because this model is simple and easy to apply, this model is not always valid in forest and urban area having rather complex structure. This study aims to analyze possible error for applying linear spectral mixture model. For the study, we measured laboratory spectra of mixture sample, having various materials, fractions, distributions. The accuracy of linear mixture model is low with the mixture sample having similar fraction because the multi-scattering between components is maximum. Additionally, this multi-scattering is related to the types, fraction, and distribution of components. Further analysis is necessary to quantify errors from linear spectral mixture model.

Oxidative Addition Reaction of Mono(aryl)cyanoplatinum(Ⅱ) Complex with Two Amino Ligands with the Dihalogens

  • Ko Jaejung;Kim Moonsik;Kim Seho;Shin Yookil
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.135-139
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    • 1992
  • The mono(aryl)cyanoplatinum(II) complex $[Pt(CN)(C_6H_3{CH_2NMe_2}_2-26)]$, reacts with the dihalogens to yield the mono(aryl)cyanoplatinum complexes $[PtX_2(CN)(C_6H_3{CH_2NMe_2}_2-26)]$, (X = Cl, Br, I). The structural configuration of the two halogen atoms for a square planar platinum complex was studied by 1H-NMR spectroscopy and led to a mixture of trans and cis orientation. The trans orientation was found to be more stable in energy (1.33 kcal/mol) than the cis orientation by means of Extended H ckel calculations. On the base of a combination of the analysis of $^1H-NMR$, $^{13}C-NMR spectra and computational calculations it is assumed that the intermediate consists of an initial attack in the linear transition state, leading to the $S_{N}2$ type mechanism.

Characteristics of debris resulting from simulated molten fuel coolant interactions in SFRS

  • E. Hemanth Rao;Prabhat Kumar Shukla;D. Ponraju;B. Venkatraman
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.283-291
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    • 2024
  • Sodium cooled Fast Reactors (SFR) are built with several engineered safety features and hence a severe accident such as a core melt accident is hypothetical with a probability of <10-6/ry. However, in case of such accidents, the mixture of the molten fuel and structural materials interacts with sodium. This phenomenon is known as Molten Fuel Coolant Interaction (MFCI) and results in fragmentation of the melt due to various instabilities. The fragmented particles settle as a debris bed on the core catcher at the bottom of the reactor vessel, and continue to generate decay heat. Characteristics of the debris particles play a vital role in heat transfer from the bed and need thorough investigation. The size, shape, and physical state of the debris depend on the associated fragmentation mechanism, superheating of the melt, and sodium temperature. Experiments have been conducted by releasing simulated corium, a molten mixture of alumina and iron generated by the aluminothermy process at ~2400 ℃ into liquid sodium, to study the fragmentation phenomena. After the experiment, the fragmented debris was retrieved and the particle size distribution was determined by sieve analysis. The debris was subjected to microscopic investigation for obtaining morphological characteristics. Based on the characteristics of debris, an attempt has been made to assess of fragmentation mechanism of simulated corium in sodium.

Synthesis of Silica using Silk Sericin without Hydrolysis of Tetraethyl Orthosilicate

  • Lee, Ji Young;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • v.27 no.2
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    • pp.298-302
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    • 2013
  • In this study, the effect of sericin on synthesis of the silica was investigated. Using the mixture of sericin solution and tetraethyl orthosilicate (TEOS), it was confirmed that silica could be synthesized in the presence of sericin, which was verified by thermal gravimetric analysis (TGA), Fourier-transformed infrared spectrometer (FT-IR) and nuclear magnetic resonance spectrometer (NMR) analysis. The TGA and FT-IR data revealed that silica-sericin complex was formed as a final product. Based on the TGA result, the content of silica and sericin in the complex would be 87 and 13%, respectively. The degree of silica condensation was higher than the natural biosilica. It could be concluded that sericin can induce the synthesis of silica directly from TEOS, which is similar to silicatein from marine sponges.

Rapid Analysis of Boric Acid in Nickel Plating Solutions (니켈도금액중의 붕산 신속정량법)

  • 염희택
    • Journal of the Korean institute of surface engineering
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    • v.3 no.1
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    • pp.7-12
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    • 1970
  • Only mannitol or glycerine is generally used for the determination of boric acid in a nickel plating solution in order to make its acidic property so strong that it can be titrated with NaOH. However, these solutions give very amgiguous color change of indicator due to the precipitation of nickel salts . Therefore, only experienced dchemistsorwell trained workimen can accurately confirm the actual end point of the titratiion. For eliminating such interference of nickel salts and easily confirming the end point by any persons , the author attempted to find out a solution which produces no precipitates during the titration in these experiments, and also he tried to funish the reason for ambiguousness in titration. The following results were obtained after many experiments. (1) In any titrations which produce nickel salts such nI(oh)$_2$, the salt is formed umption very approximate to the end point, which shows some error by the consumption of titrant(NaOH) . Then, the pink color of phenolphthalein is absorbed by Ni(OH)$_2$ and the pH jumping at the end pint is also diminished to as little as less than 15% of the total phenophthalein ph range. (2) Known methods by complex salts of citrate,w hich do not produce precipitates of Ni(OH)$_2$, are also not very satisfactory, because, the pH jumping at the end point is only about 35% and the color change of phenolphthalein is form blue-green to purple-blue. (3) New method by complex salts of oxalate were attempted in these experiments. They also did not produce precipitates of Ni(OH)$_2$ and were very satisfactory in color change at the end of point was about 65% and the color change was from blue-green to purpled. In this methods, analytica cost was minimized by the use of less amounts of cheaper chemicals than the conventional citrates complex methods. The mixture of chemicals used was composed methods. The mixture of chemical used was composed of 37g/ι of sodium oxalate(Na$_2$C$_2$O$_4$$.$5H$_2$O), 2g/ι of phenolphthalein, and 400ml /ι of glycerin. The accuracy of analysis was within the error of 0.5%. (4) The procedure of analysis was as follows. One ml of nickel plating solution was taken out and to it were added 20ml of water and 20 ml of the above mixture for the indicator. The solution was titrated with 0.1N NaOH. The quantity of boric acid was calculated by the following equation. Boric acid (g/ι) = 6.184${\times}$F${\times}$ml .

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Data Detection Algorithm Based on GMM in the Acoustic Data Transmission System (음향 데이터 전송 시스템의 강인한 데이터 검출 성능을 위한 Gaussian Mixture Model 기반 연구)

  • Song, Ji-Hyun;Chang, Joon-Hyuk;Kim, Moon-Kee;Kim, Dong-Keon
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.48 no.4
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    • pp.136-141
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    • 2011
  • In this paper, we propose an approach to improve the data detection performance of the acoustic data transmission system based on the modulated complex lapped transform (MCLT). We first present an effective analysis of the features and the detection method of data in the acoustic data transmission system. And then feature vectors which are applied to the Gaussian mixture model (GMM) are selected from relevant parameters of the previous system for the efficient data detection. For the purpose of evaluating the performance of the proposed algorithm, Bit error rate (BER) of the received data was measured at different environments (music genres (rock, pop, classic, jazz) and different distances (1m∼5m) from the loudspeaker to the microphone in a office room) and yields better results compared with the conventional scheme of the acoustic data transmission system based on the MCLT.