• 제목/요약/키워드: complex mixture analysis

검색결과 112건 처리시간 0.019초

Thiocyanato ammine계 chromium complex salts에 있어 thiocyanato기의 수가 Rf치에 미치는 영향 (The effect on the Rf value by the number of thiocyanate radical in various thiocyanate ammine chromium complex salts)

  • 최종인
    • 약학회지
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    • 제10권4호
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    • pp.1-6
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    • 1966
  • Various thiocyanatoammine chromium complex salts are prepared by the known methods and the Rf. value of these complex salts are determined by four developers. These four developers were used in the paper chromatographical work of cobalt complex salts by Yamamoto in 1954. It was also found that the developer A (Ch$_{3}$OH, acetone, NH$_{4}$OH) gave best results of these four developers and the decending development gave better results than ascending development in this experiment. In the case of decending development using developer A, it is found that the Rf. value is increased with the number of thiocyanate radical. The reason of this curious results can be explained that the thiocyanate radical in the complex ion is more active for the organic solvent than ammine radical. Shifting of electrons to the central metal and the charge of the complex ion can also effect ot the Rf. value but much questions are remained for the explanation of the above curious phenomenon. Separation of mixed sample is also studied for various mixture of the above complex salts. In the case of the mixture of hexammine and diammine complex salt, the clear separation is possible but in almost all other mixed sample, the results are not clear. Therefore it can be said that the results of this work can be used in the qualitative analysis of the individual complex salts, except the mixed sample of hexammine and diammine complex salts.

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L-아르기닌 복합체를 이용한 피록시캄의 용해도 및 생체이용률의 증가 (Improvement of Solubility and Bioavailability of Poorly Water Soluble Piroxicam with L-Arginine Complex)

  • 홍석천;유창훈;조동현;신현종;길영식
    • Journal of Pharmaceutical Investigation
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    • 제33권2호
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    • pp.85-89
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    • 2003
  • Piroxicam-arginine complex was prepared to improve the solubility and dissolution rate of poorly water-soluble piroxicam. Its formation was identified by infrared spectrophotometry, differential thermal analysis and dissolution rate. Piroxicam complex dispersible tablets, commercial $Feldene^{\circledR}$ dispersible tablets and piroxicam physical mixture hard capsules were prepared to compare dissolution rate in water. Dissolved amounts (%) after 15 mins of piroxicam complex dispersible tablets, commercial $Feldene^{\circledR}$ dispersible tablets and piroxicam physical mixture hard capsules were 98%, 48% and 10%, respectively. The solubility of complex in water was significantly higher than that of piroxicam itself. In vivo, pharmacokinetic parameters were obtained after oral administrations of piroxicam complex and physical mixture at a does of 2 mg to New Zealand White Rabbit. The $C_{max}$ of piroxicam complex was similar to that of piroxicam. However, there were much difference between the two formulations with regard to $T_{max}$ and AUC. The $T_{max}$ of piroxicam alone was 4 hours, but that of piroxicam complex was 0.8 hours. In addition, the AUC of piroxicam complex was 1.38 times greater than that of piroxicam alone.

Performance of Zoysia spp. and Axonopus compressus Turf on Turf-Paver Complex under Simulated Traffic

  • Chin, Siew-Wai;Ow, Lai-Fern
    • Weed & Turfgrass Science
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    • 제5권2호
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    • pp.88-94
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    • 2016
  • Vehicular traffic on turf results in loss of green cover due to direct tearing of shoots and indirect long-term soil compaction. Protection of turfgrass crowns from wear could increase the ability of turf to recover from heavy traffic. Plastic turfpavers have been installed in trafficked areas to reduce soil compaction and to protect turfgrass crowns from wear. The objectives of this study were to evaluate traffic performance of turfgrasses (Zoysia matrella and Axonopus compressus) and soil mixture (high, medium and low sand mix) combinations on turf-paver complex. The traffic performance of turf and recovery was evaluated based on percent green cover determined by digital image analysis and spectral reflectance responses by NDVI-meter. Bulk density cores indicated significant increase in soil compaction from medium and low sand mixtures compared to high sand mixture. Higher reduction of percent green cover was observed from A. compressus (30-40%) than Z. matrella (10-20%) across soil mixtures. Both turf species displayed higher wear tolerance when established on higher sand (>50% sand) than low sand mixture. Positive turf recovery was also supported by complementary spectral responses. Establishment of Zoysia matrella turf on turfpaver complex using high sand mixture will result in improved wear tolerance.

Identification of riparian vegetation using Spectral Mixture Analysis of multi-temporal Landsat Imagery

  • Kim, Sang-Wook;Park, Chong-Hwa
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.175-177
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    • 2003
  • To monitor riparian wetlands as one of complex natural ecosystems using remotely sensed data, we need to concurrently consider vegetation, soil and water which constitute complicated wetland ecosystems. To identify riparian distribution we adopted linear Spectral Mixture Analysis in order to improve identification accuracy of riparian areas. This study has indicated that linear SMA adopting tasseled cap endmember selection is an enhanced routine for Identification of riparian wetlands and phenologically autumn imagery is more appropriate to detect riparian vegetation in the Paldang water catchment area.

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Recovery of Cholesterol from the $\beta$-Cyclodexgtrin-Cholestrerol Complex Using Immobilized Cyclomaltodextrinas of Alkalophilic Bacillus sp. KJ 133

  • Kwon, Ho-Jeong;Jung, Hye-Jin;Kwak, Hae-Soo
    • Journal of Microbiology and Biotechnology
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    • 제11권4호
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    • pp.712-715
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    • 2001
  • A new combined method including the enzymatic hydrolysis of $\beta$-cyclodextrin ($\beta$-CD) and solvent extraction fo cholesterol from the hydrolyzed mixture was developed to recover cholesterol from a $\beta$-CD-cholesterol complex prepared from dairy products, such as cream, milk, and cheese. Cyclomaltodextrinase (cyclomatodextrin dextrin hydrolase, EC 3.2.1.54, DCase_ prepared form alkalophilic Bacillus sp. KJ 133 hydrolyzed the $\beta$-DC of the $\beta$-CD-cholesterol complex, and then, free cholesterol was efficiently extracted from the hydrolyzed mixture by a nonpolar solvent such as ethyl acetate. To increase the stability of free CDase, immobilized CDase was developed using sodium alginate as a carrier. The immobilized CDase showed a high recovery yield of cholesterol in a time-dependent manner compared to the free CDase. A gas chromatography analysis showed that more than 70% of cholesterol was recovered from the $\beta$-DC-cholesterol complex of cream by the immobilized CDase, whereas only 3% and 29% of cholesterol were recovered when the solvent extraction and free CDase treatment were used, respectively. The cholesterol recovered can be used as a raw material for steroid synthesis. Furthermore, this method can be an efficient way to recover cholesterol or other organic compounds that are bound in a $\beta$ -DC-cholesterol or -organic compound complex.

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Protective Effect of ACTIValoe N-931 Complex, a Mixture of Aloe vera and Silybum marianum, on Experimental Acute Liver Injury

  • Moon, Young-Joo;Cheon, Ho-Jun;Lee, Woo-Cheol;Kim, Hyo-Yeon;Oh, Sun-Tack;Shin, Eun-Ju;Shim, Kyu-Suk;Lee, Sun-Mee
    • Biomolecules & Therapeutics
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    • 제16권3호
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    • pp.203-209
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    • 2008
  • The aim of this study was to investigate the hepatoprotective effect of $ACTIValoe^{(R)}$ N-931 complex, a mixture of Aloe vera and Silybum marianum, against acute liver injuries. Acute liver damages were induced by intraperitoneal injection of galactosamine (GalN, 700 mg/kg), naphthylisothiocyanate (ANIT, 40 mg/kg) and ethionine (500 mg/kg). $ACTIValoe^{(R)}$ N-931 (85, 170 and 340) was administered orally 48 h, 24 h, 2 h before and 6 h after the injection of hepatotoxins. At 24 h after GalN treatment the levels of serum aminotransferases and hepatic lipid peroxidation were significantly elevated, whereas hepatic glutathione, serum triglyceride (TG) and total cholesterol were decreased. These changes were attenuated by $ACTIValoe^{(R)}$ N-931 complex. The serum aminotransferase activities and total bilirubin significantly increased at 48 h after ANIT treatment, but were attenuated by $ACTIValoe^{(R)}$ N-931 complex. The bile flow was lower after ANIT treatment, which was restored by $ACTIValoe^{(R)}$ N-931 complex. $ACTIValoe^{(R)}$ N-931 complex reduced the ethionine-induced elevated hepatic TG contents. Histopathological analysis revealed that signs of liver injury were prominent at 24 h as result of ethionine injection, demonstrated by extensive areas of fatty change and microvesicular steatosis were observed around cells. These changes were attenuated by $ACTIValoe^{(R)}$ N-931 complex. Our results suggest that the $ACTIValoe^{(R)}$ N-931 complex has a protective effect on acute liver injury.

LDA 혼합 모형을 이용한 얼굴 인식 (Face Recognition using LDA Mixture Model)

  • 김현철;김대진;방승양
    • 한국정보과학회논문지:소프트웨어및응용
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    • 제32권8호
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    • pp.789-794
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    • 2005
  • LDA는 데이타를 잘 구분하게 하는 변환을 제공하고, 얼굴 인식에서 우수한 성능를 보였다. 그러나, LDA는 전체 데이타에 대해 단 하나의 변환 행렬만을 주므로 사람 얼굴과 같은 많은 클래스로 구성되어 있는 복잡한 데이타를 구분하기에 충분하지 않다. 이런 약점을 극복하기 위해 우리는 LDA 혼합 모형이라는 새로운 얼굴 인식 방법을 제안한다. LDA 혼합 모형에서는 모든 클래스가 여러 개의 군집으로 분할되고 각 군집에 대해서 하나의 변환 행렬을 얻는다. 이렇게 더 세세히 표현하는 방법은 분류 성능을 크게 향상시킬 것이다 얼굴 인식 실험 결과, LDA 혼합 모형은 PCA, LDA, PCA 혼합 모형보다 더 우수한 분류 성능을 보여주었다.

2 - 아미노나프탈렌술폰산류의 자외선분광 광도법에 의한 분석 (Ultraviolet Spectrophotometric Analysis of 2-Aminonaphtalene Sulfonic Acids)

  • 손주환;김주원
    • 한국응용과학기술학회지
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    • 제3권2호
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    • pp.23-28
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    • 1986
  • The sulfuric acid sulfonation mixtures of 2-aminonaphthalene, contained 2-aminonaphthalene, Dahl's acid, Broenner's acid, amino-F-acid and Baden acid, can be determined quantitatively by multicomponent spectrophotometric analysis. The analysis was performed in diluted sodium hydroxide aqueous solution and based on the ultraviolet absorption of the sodium salts of each isomers. The determination of quantity of each isomers was performed by subjection the absorbances of the unknown mixture and of its constituents, gathered at a large number of wavelengths, to a least square treatment by an electronic personer computer. This method provided a rapid analysis of such complex mixture, and the standard deviation was ${\pm}1.65$ mole %.

PCA 혼합 모형과 클래스 기반 특징에 의한 LDA의 확장 (Extensions of LDA by PCA Mixture Model and Class-wise Features)

  • 김현철;김대진;방승양
    • 한국정보과학회논문지:소프트웨어및응용
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    • 제32권8호
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    • pp.781-788
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    • 2005
  • LDA는 클래스간 퍼진 정도와 클래스내 퍼진 정도의 비를 최대화하는 변환를 구하는 데이터 구분 기술이다. LDA는 여러 가지 응용에 성공적으로 응용되었지만 그 모델의 단순성과 관련된 두 가지 한계를 가지고 있다. 첫째는 각 클래스의 데이타가 가우시안 분포를 가진다고 가정되므로 복잡한 분포를 갖는 데이타를 구분하는데 실패한다는 것이다. 둘째는 LDA가 클래스의 전체 범위에 대해서 단지 하나의 변환만을 주므로 클래스 기반의 정보를 잃게 된다는 것이다. 본 논문은 위의 문제들을 극복하는 세가지 확장들을 제안한다. 첫 번째 확장은 더 복잡한 분포를 표현할 수 있는 PCA 혼합 모형을 이용하여 클래스내 퍼진 정도를 모델링함으로써 첫째 문제를 극복한다. 두번째 확장은 클래스 기반 특징들을 제공하기 위해서 각 클래스에 대해 다른 변환을 취함으로써 둘째 문제를 극복한다. 셋째 확장은 PCA 혼합 모형의 관점에서 각 클래스를 표현함으로써 앞의 두 확장을 결합하는 것이다. 숫자 인식과 알파벳 인식에 대한 실험에서 LDA의 모든 제안된 확장들이 LDA보다 더 좋은 분류 성능을 보여 주었다.

Multidimensional Gas Chromatography-A Powerful Tool for the Analysis of Multicomponent Mixtures

  • Kim, Kyoung-Su
    • Preventive Nutrition and Food Science
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    • 제1권1호
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    • pp.127-133
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    • 1996
  • The development of high resolution capillary columns and a large variety of different detectors led to a strong position of gas chromatography in instrumental analysis. Every effort has been made to solve sophisticated separation problems by column switching. Nowadays, several systems are commercially available for this purpose. The principle and the capabilities of multidimensional gas chromatography(MDGC) are illustrated by different applications in the field of modern flavor and essential oil research.

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